Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers
We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials wer...
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| Veröffentlicht in: | European polymer journal 2011-12, Vol.47 (12), p.2303-2310 |
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| creator | Cureton, LaShonda T. Richard Turner, S. |
| description | We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.
We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments. |
| doi_str_mv | 10.1016/j.eurpolymj.2011.09.006 |
| format | Article |
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b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.
We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2011.09.006</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>4,4′-Dihydroxyterphenyl ; Applied sciences ; Bisphenol A ; Block copolymers ; Copolymers ; Elongation ; Ethers ; Exact sciences and technology ; Inorganic and organomineral polymers ; Molecular weight ; Physicochemistry of polymers ; Poly(arylene ether sulfone) ; Polydimethylsiloxane block copolymers ; Preparation ; Segments ; Tensile properties ; Thermal properties</subject><ispartof>European polymer journal, 2011-12, Vol.47 (12), p.2303-2310</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-760229cf8a3770f28eca0b8fa22211c13f31f88c9c0247f219190bce56b90113</citedby><cites>FETCH-LOGICAL-c377t-760229cf8a3770f28eca0b8fa22211c13f31f88c9c0247f219190bce56b90113</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.eurpolymj.2011.09.006$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3552,27931,27932,46002</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25229008$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Cureton, LaShonda T.</creatorcontrib><creatorcontrib>Richard Turner, S.</creatorcontrib><title>Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers</title><title>European polymer journal</title><description>We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.
We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.</description><subject>4,4′-Dihydroxyterphenyl</subject><subject>Applied sciences</subject><subject>Bisphenol A</subject><subject>Block copolymers</subject><subject>Copolymers</subject><subject>Elongation</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Inorganic and organomineral polymers</subject><subject>Molecular weight</subject><subject>Physicochemistry of polymers</subject><subject>Poly(arylene ether sulfone)</subject><subject>Polydimethylsiloxane block copolymers</subject><subject>Preparation</subject><subject>Segments</subject><subject>Tensile properties</subject><subject>Thermal properties</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM2OFCEUhYnRxHb0GWRj1EWVF-j6YdmZ-JdM4sLZE4q6OLRUUXKrjb3TZ_ANfRJpuzNbV-TCdzj3HMaeC6gFiPbNvsZDXlI8TvtaghA16BqgfcA2ou9UJfS2ecg2AGJbKWi6x-wJ0R4AOtWqDfv1-Tivd0iBuJ1HvuS0YF4DEk-eD4GWO5xT5Ls_P3-vmC_Tye2VzceIM3Is8szpEH2a8XXhTq9jmMr9MVKI6YctFOGXCecVRz7E5L5yl_6tjJmeskfeRsJnl_OK3b57e3v9obr59P7j9e6mcqrr1qprQUrtfG_LCF726CwMvbdSSiGcUF4J3_dOO5DbzkuhhYbBYdMOurSirtjL87cl4rcD0mqmQA5jLNulAxndKi163TSF7M6ky4koozdLDlOJawSYU-Vmb-4rN6fKDWhTKi_KFxcPS85Gn-3sAt3LZVMSAPSF2505LHm_B8yGXMDZ4RgyutWMKfzX6y-waqGf</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Cureton, LaShonda T.</creator><creator>Richard Turner, S.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20111201</creationdate><title>Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers</title><author>Cureton, LaShonda T. ; Richard Turner, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-760229cf8a3770f28eca0b8fa22211c13f31f88c9c0247f219190bce56b90113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>4,4′-Dihydroxyterphenyl</topic><topic>Applied sciences</topic><topic>Bisphenol A</topic><topic>Block copolymers</topic><topic>Copolymers</topic><topic>Elongation</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Inorganic and organomineral polymers</topic><topic>Molecular weight</topic><topic>Physicochemistry of polymers</topic><topic>Poly(arylene ether sulfone)</topic><topic>Polydimethylsiloxane block copolymers</topic><topic>Preparation</topic><topic>Segments</topic><topic>Tensile properties</topic><topic>Thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cureton, LaShonda T.</creatorcontrib><creatorcontrib>Richard Turner, S.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cureton, LaShonda T.</au><au>Richard Turner, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers</atitle><jtitle>European polymer journal</jtitle><date>2011-12-01</date><risdate>2011</risdate><volume>47</volume><issue>12</issue><spage>2303</spage><epage>2310</epage><pages>2303-2310</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.
We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES-
b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800
MPa and a higher
T
g, 196
°C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2011.09.006</doi><tpages>8</tpages></addata></record> |
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| subjects | 4,4′-Dihydroxyterphenyl Applied sciences Bisphenol A Block copolymers Copolymers Elongation Ethers Exact sciences and technology Inorganic and organomineral polymers Molecular weight Physicochemistry of polymers Poly(arylene ether sulfone) Polydimethylsiloxane block copolymers Preparation Segments Tensile properties Thermal properties |
| title | Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers |
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