Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers

We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials wer...

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Veröffentlicht in:European polymer journal 2011-12, Vol.47 (12), p.2303-2310
Hauptverfasser: Cureton, LaShonda T., Richard Turner, S.
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Richard Turner, S.
description We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments. We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.
doi_str_mv 10.1016/j.eurpolymj.2011.09.006
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The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments. We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. 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The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments. We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.</description><subject>4,4′-Dihydroxyterphenyl</subject><subject>Applied sciences</subject><subject>Bisphenol A</subject><subject>Block copolymers</subject><subject>Copolymers</subject><subject>Elongation</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Inorganic and organomineral polymers</subject><subject>Molecular weight</subject><subject>Physicochemistry of polymers</subject><subject>Poly(arylene ether sulfone)</subject><subject>Polydimethylsiloxane block copolymers</subject><subject>Preparation</subject><subject>Segments</subject><subject>Tensile properties</subject><subject>Thermal properties</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM2OFCEUhYnRxHb0GWRj1EWVF-j6YdmZ-JdM4sLZE4q6OLRUUXKrjb3TZ_ANfRJpuzNbV-TCdzj3HMaeC6gFiPbNvsZDXlI8TvtaghA16BqgfcA2ou9UJfS2ecg2AGJbKWi6x-wJ0R4AOtWqDfv1-Tivd0iBuJ1HvuS0YF4DEk-eD4GWO5xT5Ls_P3-vmC_Tye2VzceIM3Is8szpEH2a8XXhTq9jmMr9MVKI6YctFOGXCecVRz7E5L5yl_6tjJmeskfeRsJnl_OK3b57e3v9obr59P7j9e6mcqrr1qprQUrtfG_LCF726CwMvbdSSiGcUF4J3_dOO5DbzkuhhYbBYdMOurSirtjL87cl4rcD0mqmQA5jLNulAxndKi163TSF7M6ky4koozdLDlOJawSYU-Vmb-4rN6fKDWhTKi_KFxcPS85Gn-3sAt3LZVMSAPSF2505LHm_B8yGXMDZ4RgyutWMKfzX6y-waqGf</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Cureton, LaShonda T.</creator><creator>Richard Turner, S.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20111201</creationdate><title>Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers</title><author>Cureton, LaShonda T. ; Richard Turner, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-760229cf8a3770f28eca0b8fa22211c13f31f88c9c0247f219190bce56b90113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>4,4′-Dihydroxyterphenyl</topic><topic>Applied sciences</topic><topic>Bisphenol A</topic><topic>Block copolymers</topic><topic>Copolymers</topic><topic>Elongation</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Inorganic and organomineral polymers</topic><topic>Molecular weight</topic><topic>Physicochemistry of polymers</topic><topic>Poly(arylene ether sulfone)</topic><topic>Polydimethylsiloxane block copolymers</topic><topic>Preparation</topic><topic>Segments</topic><topic>Tensile properties</topic><topic>Thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cureton, LaShonda T.</creatorcontrib><creatorcontrib>Richard Turner, S.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cureton, LaShonda T.</au><au>Richard Turner, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers</atitle><jtitle>European polymer journal</jtitle><date>2011-12-01</date><risdate>2011</risdate><volume>47</volume><issue>12</issue><spage>2303</spage><epage>2310</epage><pages>2303-2310</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments. We have synthesized new poly(arylene ether sulfone) (PAES) and polydimethylsiloxane (PDMS) segmented block copolymers where the PAES segments contain 20–30% of 4,4′-dihydroxyterphenol (DHTP) and 70–80% of bisphenol A (BA) units. The tensile and thermal properties of these new polymeric materials were measured and were compared to those of existing bisphenol A PAES–PDMS segmented block copolymers (BA PAES- b-PDMS). Also, a high molecular weight BA–DHTP PAES random copolymer containing 80% BA and 20% DHTP was prepared and its properties were compared to Udel®, a commercial PAES based on BA. The BA–DHTP PAES random copolymer had a significantly higher modulus, 1800 MPa and a higher T g, 196 °C when compared to Udel®. In the segmented block copolymer materials, increased modulus and tensile strain at break (elongation) were also found when DHTP was incorporated into the PAES segments.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2011.09.006</doi><tpages>8</tpages></addata></record>
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subjects 4,4′-Dihydroxyterphenyl
Applied sciences
Bisphenol A
Block copolymers
Copolymers
Elongation
Ethers
Exact sciences and technology
Inorganic and organomineral polymers
Molecular weight
Physicochemistry of polymers
Poly(arylene ether sulfone)
Polydimethylsiloxane block copolymers
Preparation
Segments
Tensile properties
Thermal properties
title Synthesis and properties of bisphenol A–terphenol poly(arylene ether sulfone)–polydimethylsiloxane segmented block copolymers
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