Optical Properties of Cu Nanocrystalline-OPAA Composite Film: Optical Properties of Cu Nanocrystalline-OPAA Composite Film

Optically transparent Cu nanocrystalline/OPAA composite film was successfully prepared by electrodepositing Cu into ordered porous anodic alumina (OPAA) template using constant voltage direct current technique. The morphology, structure, linear optical absorption, third-order optical nonlinearity an...

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Veröffentlicht in:Wu ji cai liao xue bao 2011-09, Vol.26 (9), p.907-911
Hauptverfasser: LIU, Yan, YANG, Xiu-Chun, ZHOU, Hui, HOU, Jun-Wei, HAN, Shan-Shan, QIAN, Shi-Xiong
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container_end_page 911
container_issue 9
container_start_page 907
container_title Wu ji cai liao xue bao
container_volume 26
creator LIU, Yan
YANG, Xiu-Chun
ZHOU, Hui
HOU, Jun-Wei
HAN, Shan-Shan
QIAN, Shi-Xiong
description Optically transparent Cu nanocrystalline/OPAA composite film was successfully prepared by electrodepositing Cu into ordered porous anodic alumina (OPAA) template using constant voltage direct current technique. The morphology, structure, linear optical absorption, third-order optical nonlinearity and ultrafast dynamics of the Cu/OPAA composite were characterized by field emission scanning electron microscope (FESEM), transmission electron microscope (TEM). UV-Vis spectrophotometer, Z-scan technique and femtosecond pump-probe experiment. The results show that Cu nanoparicles have diameters of 40-50nm with face center cubic structure and disperse in the branched pores of the OPAA template, which induce a surface plasmon resonance (SPR) absorption at 584 nm. When the probe optical wavelength is far away from the SPR wavelength, Cu nanocrystalline/OPAA composite film possesses a character of light-induced absorption. When the probe optical wavelength is near the SPR wavelength, it possesses a photo-bleaching character. The composite film has a non-resonant third-order nonlinear susceptibility of 0.73x10(-9) esu and a response time of 1.3 ps.
doi_str_mv 10.3724/SP.J.1077.2011.00907
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subjects ANODES
COMPOSITES
Copper
CRYSTAL STRUCTURE
CU
ELECTRODEPOSITION
EMISSIONS
Field emission
MICROSTRUCTURES
Nanocrystals
Nanostructure
Nonlinear dynamics
Nonlinearity
OPTICAL PROPERTIES
SCANNING ELECTRON MICROSCOPY
Wavelengths
title Optical Properties of Cu Nanocrystalline-OPAA Composite Film: Optical Properties of Cu Nanocrystalline-OPAA Composite Film
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