Optical Properties of Cu Nanocrystalline-OPAA Composite Film: Optical Properties of Cu Nanocrystalline-OPAA Composite Film
Optically transparent Cu nanocrystalline/OPAA composite film was successfully prepared by electrodepositing Cu into ordered porous anodic alumina (OPAA) template using constant voltage direct current technique. The morphology, structure, linear optical absorption, third-order optical nonlinearity an...
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Veröffentlicht in: | Wu ji cai liao xue bao 2011-09, Vol.26 (9), p.907-911 |
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creator | LIU, Yan YANG, Xiu-Chun ZHOU, Hui HOU, Jun-Wei HAN, Shan-Shan QIAN, Shi-Xiong |
description | Optically transparent Cu nanocrystalline/OPAA composite film was successfully prepared by electrodepositing Cu into ordered porous anodic alumina (OPAA) template using constant voltage direct current technique. The morphology, structure, linear optical absorption, third-order optical nonlinearity and ultrafast dynamics of the Cu/OPAA composite were characterized by field emission scanning electron microscope (FESEM), transmission electron microscope (TEM). UV-Vis spectrophotometer, Z-scan technique and femtosecond pump-probe experiment. The results show that Cu nanoparicles have diameters of 40-50nm with face center cubic structure and disperse in the branched pores of the OPAA template, which induce a surface plasmon resonance (SPR) absorption at 584 nm. When the probe optical wavelength is far away from the SPR wavelength, Cu nanocrystalline/OPAA composite film possesses a character of light-induced absorption. When the probe optical wavelength is near the SPR wavelength, it possesses a photo-bleaching character. The composite film has a non-resonant third-order nonlinear susceptibility of 0.73x10(-9) esu and a response time of 1.3 ps. |
doi_str_mv | 10.3724/SP.J.1077.2011.00907 |
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The morphology, structure, linear optical absorption, third-order optical nonlinearity and ultrafast dynamics of the Cu/OPAA composite were characterized by field emission scanning electron microscope (FESEM), transmission electron microscope (TEM). UV-Vis spectrophotometer, Z-scan technique and femtosecond pump-probe experiment. The results show that Cu nanoparicles have diameters of 40-50nm with face center cubic structure and disperse in the branched pores of the OPAA template, which induce a surface plasmon resonance (SPR) absorption at 584 nm. When the probe optical wavelength is far away from the SPR wavelength, Cu nanocrystalline/OPAA composite film possesses a character of light-induced absorption. When the probe optical wavelength is near the SPR wavelength, it possesses a photo-bleaching character. The composite film has a non-resonant third-order nonlinear susceptibility of 0.73x10(-9) esu and a response time of 1.3 ps.</description><identifier>ISSN: 1000-324X</identifier><identifier>DOI: 10.3724/SP.J.1077.2011.00907</identifier><language>chi</language><subject>ANODES ; COMPOSITES ; Copper ; CRYSTAL STRUCTURE ; CU ; ELECTRODEPOSITION ; EMISSIONS ; Field emission ; MICROSTRUCTURES ; Nanocrystals ; Nanostructure ; Nonlinear dynamics ; Nonlinearity ; OPTICAL PROPERTIES ; SCANNING ELECTRON MICROSCOPY ; Wavelengths</subject><ispartof>Wu ji cai liao xue bao, 2011-09, Vol.26 (9), p.907-911</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c232t-edc1b56f45e641a99ac194f07b3edc8eacea41fb299b562ec45b074ca8b103db3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids></links><search><creatorcontrib>LIU, Yan</creatorcontrib><creatorcontrib>YANG, Xiu-Chun</creatorcontrib><creatorcontrib>ZHOU, Hui</creatorcontrib><creatorcontrib>HOU, Jun-Wei</creatorcontrib><creatorcontrib>HAN, Shan-Shan</creatorcontrib><creatorcontrib>QIAN, Shi-Xiong</creatorcontrib><title>Optical Properties of Cu Nanocrystalline-OPAA Composite Film: Optical Properties of Cu Nanocrystalline-OPAA Composite Film</title><title>Wu ji cai liao xue bao</title><description>Optically transparent Cu nanocrystalline/OPAA composite film was successfully prepared by electrodepositing Cu into ordered porous anodic alumina (OPAA) template using constant voltage direct current technique. The morphology, structure, linear optical absorption, third-order optical nonlinearity and ultrafast dynamics of the Cu/OPAA composite were characterized by field emission scanning electron microscope (FESEM), transmission electron microscope (TEM). UV-Vis spectrophotometer, Z-scan technique and femtosecond pump-probe experiment. The results show that Cu nanoparicles have diameters of 40-50nm with face center cubic structure and disperse in the branched pores of the OPAA template, which induce a surface plasmon resonance (SPR) absorption at 584 nm. When the probe optical wavelength is far away from the SPR wavelength, Cu nanocrystalline/OPAA composite film possesses a character of light-induced absorption. When the probe optical wavelength is near the SPR wavelength, it possesses a photo-bleaching character. 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The morphology, structure, linear optical absorption, third-order optical nonlinearity and ultrafast dynamics of the Cu/OPAA composite were characterized by field emission scanning electron microscope (FESEM), transmission electron microscope (TEM). UV-Vis spectrophotometer, Z-scan technique and femtosecond pump-probe experiment. The results show that Cu nanoparicles have diameters of 40-50nm with face center cubic structure and disperse in the branched pores of the OPAA template, which induce a surface plasmon resonance (SPR) absorption at 584 nm. When the probe optical wavelength is far away from the SPR wavelength, Cu nanocrystalline/OPAA composite film possesses a character of light-induced absorption. When the probe optical wavelength is near the SPR wavelength, it possesses a photo-bleaching character. The composite film has a non-resonant third-order nonlinear susceptibility of 0.73x10(-9) esu and a response time of 1.3 ps.</abstract><doi>10.3724/SP.J.1077.2011.00907</doi><tpages>5</tpages></addata></record> |
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source | EZB Electronic Journals Library |
subjects | ANODES COMPOSITES Copper CRYSTAL STRUCTURE CU ELECTRODEPOSITION EMISSIONS Field emission MICROSTRUCTURES Nanocrystals Nanostructure Nonlinear dynamics Nonlinearity OPTICAL PROPERTIES SCANNING ELECTRON MICROSCOPY Wavelengths |
title | Optical Properties of Cu Nanocrystalline-OPAA Composite Film: Optical Properties of Cu Nanocrystalline-OPAA Composite Film |
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