Synthesis of paramagnetic polymers using ionic liquid chemistry
Herein, the synthesis of polymeric ionic liquids (PILs) with paramagnetic anions based on tetrachloroferrate(iii) (FeCl4-) and tetrabromoferrate(iii) (FeBr4-) is presented. The formation of the novel polymers encompassing the paramagnetic anions is proven by UV-VIS and Raman spectroscopy. Paramagnet...
Gespeichert in:
| Veröffentlicht in: | Polymer chemistry 2011-01, Vol.2 (6), p.1275-1278 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1278 |
|---|---|
| container_issue | 6 |
| container_start_page | 1275 |
| container_title | Polymer chemistry |
| container_volume | 2 |
| creator | Döbbelin, Markus Jovanovski, Vasko Llarena, Irantzu Claros Marfil, Luis J. Cabañero, Germán Rodriguez, Javier Mecerreyes, David |
| description | Herein, the synthesis of polymeric ionic liquids (PILs) with paramagnetic anions based on tetrachloroferrate(iii) (FeCl4-) and tetrabromoferrate(iii) (FeBr4-) is presented. The formation of the novel polymers encompassing the paramagnetic anions is proven by UV-VIS and Raman spectroscopy. Paramagnetic properties are analyzed using a SQUID measuring system. Some of the obtained PILs show higher magnetic susceptibility values than previously measured for paramagnetic ionic liquids. It is further found that the magnetic susceptibility can be tailored by controlling the iron content in the anion. Interestingly, casted films of the PILs show a strong response to a neodymium magnet. As a potential application, a microgel based on a paramagnetic PIL is used as a reusable catalyst in Friedel-Crafts alkylation. The paramagnetic PIL microgel can be easily separated and reused after the reaction making these new materials interesting for green chemistry processes. |
| doi_str_mv | 10.1039/c1py00044f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_963915508</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>963915508</sourcerecordid><originalsourceid>FETCH-LOGICAL-c329t-c17158abe53d133d2a9be3f7b70e012e3062fe267da8d75741cd867c96f3eabc3</originalsourceid><addsrcrecordid>eNpFkE1LxDAYhIMouOhe_AW9CUI1ydskzUlk8QsWPKjnkKZvdiP92qQ99N9bWdHTDMPDDAwhV4zeMgr6zrFhppQWhT8hK6aEzrWW_PTPi-KcrFP6WhgKrOAgV-T-fe7GPaaQst5ng422tbsOx-CyoW_mFmPKphS6XRb6bgmbcJhCnbk9tiGNcb4kZ942Cde_ekE-nx4_Ni_59u35dfOwzR1wPeaOKSZKW6GAmgHU3OoKwatKUaSMI1DJPXKpalvWSqiCubqUymnpAW3l4IJcH3uH2B8mTKNZ9h02je2wn5LREjQTgpYLeXMkXexTiujNEENr42wYNT8_mf-f4BuRpVv2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>963915508</pqid></control><display><type>article</type><title>Synthesis of paramagnetic polymers using ionic liquid chemistry</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Döbbelin, Markus ; Jovanovski, Vasko ; Llarena, Irantzu ; Claros Marfil, Luis J. ; Cabañero, Germán ; Rodriguez, Javier ; Mecerreyes, David</creator><creatorcontrib>Döbbelin, Markus ; Jovanovski, Vasko ; Llarena, Irantzu ; Claros Marfil, Luis J. ; Cabañero, Germán ; Rodriguez, Javier ; Mecerreyes, David</creatorcontrib><description>Herein, the synthesis of polymeric ionic liquids (PILs) with paramagnetic anions based on tetrachloroferrate(iii) (FeCl4-) and tetrabromoferrate(iii) (FeBr4-) is presented. The formation of the novel polymers encompassing the paramagnetic anions is proven by UV-VIS and Raman spectroscopy. Paramagnetic properties are analyzed using a SQUID measuring system. Some of the obtained PILs show higher magnetic susceptibility values than previously measured for paramagnetic ionic liquids. It is further found that the magnetic susceptibility can be tailored by controlling the iron content in the anion. Interestingly, casted films of the PILs show a strong response to a neodymium magnet. As a potential application, a microgel based on a paramagnetic PIL is used as a reusable catalyst in Friedel-Crafts alkylation. The paramagnetic PIL microgel can be easily separated and reused after the reaction making these new materials interesting for green chemistry processes.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/c1py00044f</identifier><language>eng</language><subject>Anions ; Ionic liquids ; Iron ; Magnetic permeability ; Magnetic susceptibility ; Microgels ; Polymers ; Synthesis</subject><ispartof>Polymer chemistry, 2011-01, Vol.2 (6), p.1275-1278</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c329t-c17158abe53d133d2a9be3f7b70e012e3062fe267da8d75741cd867c96f3eabc3</citedby><cites>FETCH-LOGICAL-c329t-c17158abe53d133d2a9be3f7b70e012e3062fe267da8d75741cd867c96f3eabc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Döbbelin, Markus</creatorcontrib><creatorcontrib>Jovanovski, Vasko</creatorcontrib><creatorcontrib>Llarena, Irantzu</creatorcontrib><creatorcontrib>Claros Marfil, Luis J.</creatorcontrib><creatorcontrib>Cabañero, Germán</creatorcontrib><creatorcontrib>Rodriguez, Javier</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><title>Synthesis of paramagnetic polymers using ionic liquid chemistry</title><title>Polymer chemistry</title><description>Herein, the synthesis of polymeric ionic liquids (PILs) with paramagnetic anions based on tetrachloroferrate(iii) (FeCl4-) and tetrabromoferrate(iii) (FeBr4-) is presented. The formation of the novel polymers encompassing the paramagnetic anions is proven by UV-VIS and Raman spectroscopy. Paramagnetic properties are analyzed using a SQUID measuring system. Some of the obtained PILs show higher magnetic susceptibility values than previously measured for paramagnetic ionic liquids. It is further found that the magnetic susceptibility can be tailored by controlling the iron content in the anion. Interestingly, casted films of the PILs show a strong response to a neodymium magnet. As a potential application, a microgel based on a paramagnetic PIL is used as a reusable catalyst in Friedel-Crafts alkylation. The paramagnetic PIL microgel can be easily separated and reused after the reaction making these new materials interesting for green chemistry processes.</description><subject>Anions</subject><subject>Ionic liquids</subject><subject>Iron</subject><subject>Magnetic permeability</subject><subject>Magnetic susceptibility</subject><subject>Microgels</subject><subject>Polymers</subject><subject>Synthesis</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LxDAYhIMouOhe_AW9CUI1ydskzUlk8QsWPKjnkKZvdiP92qQ99N9bWdHTDMPDDAwhV4zeMgr6zrFhppQWhT8hK6aEzrWW_PTPi-KcrFP6WhgKrOAgV-T-fe7GPaaQst5ng422tbsOx-CyoW_mFmPKphS6XRb6bgmbcJhCnbk9tiGNcb4kZ942Cde_ekE-nx4_Ni_59u35dfOwzR1wPeaOKSZKW6GAmgHU3OoKwatKUaSMI1DJPXKpalvWSqiCubqUymnpAW3l4IJcH3uH2B8mTKNZ9h02je2wn5LREjQTgpYLeXMkXexTiujNEENr42wYNT8_mf-f4BuRpVv2</recordid><startdate>20110101</startdate><enddate>20110101</enddate><creator>Döbbelin, Markus</creator><creator>Jovanovski, Vasko</creator><creator>Llarena, Irantzu</creator><creator>Claros Marfil, Luis J.</creator><creator>Cabañero, Germán</creator><creator>Rodriguez, Javier</creator><creator>Mecerreyes, David</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110101</creationdate><title>Synthesis of paramagnetic polymers using ionic liquid chemistry</title><author>Döbbelin, Markus ; Jovanovski, Vasko ; Llarena, Irantzu ; Claros Marfil, Luis J. ; Cabañero, Germán ; Rodriguez, Javier ; Mecerreyes, David</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c329t-c17158abe53d133d2a9be3f7b70e012e3062fe267da8d75741cd867c96f3eabc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Anions</topic><topic>Ionic liquids</topic><topic>Iron</topic><topic>Magnetic permeability</topic><topic>Magnetic susceptibility</topic><topic>Microgels</topic><topic>Polymers</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Döbbelin, Markus</creatorcontrib><creatorcontrib>Jovanovski, Vasko</creatorcontrib><creatorcontrib>Llarena, Irantzu</creatorcontrib><creatorcontrib>Claros Marfil, Luis J.</creatorcontrib><creatorcontrib>Cabañero, Germán</creatorcontrib><creatorcontrib>Rodriguez, Javier</creatorcontrib><creatorcontrib>Mecerreyes, David</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Döbbelin, Markus</au><au>Jovanovski, Vasko</au><au>Llarena, Irantzu</au><au>Claros Marfil, Luis J.</au><au>Cabañero, Germán</au><au>Rodriguez, Javier</au><au>Mecerreyes, David</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of paramagnetic polymers using ionic liquid chemistry</atitle><jtitle>Polymer chemistry</jtitle><date>2011-01-01</date><risdate>2011</risdate><volume>2</volume><issue>6</issue><spage>1275</spage><epage>1278</epage><pages>1275-1278</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>Herein, the synthesis of polymeric ionic liquids (PILs) with paramagnetic anions based on tetrachloroferrate(iii) (FeCl4-) and tetrabromoferrate(iii) (FeBr4-) is presented. The formation of the novel polymers encompassing the paramagnetic anions is proven by UV-VIS and Raman spectroscopy. Paramagnetic properties are analyzed using a SQUID measuring system. Some of the obtained PILs show higher magnetic susceptibility values than previously measured for paramagnetic ionic liquids. It is further found that the magnetic susceptibility can be tailored by controlling the iron content in the anion. Interestingly, casted films of the PILs show a strong response to a neodymium magnet. As a potential application, a microgel based on a paramagnetic PIL is used as a reusable catalyst in Friedel-Crafts alkylation. The paramagnetic PIL microgel can be easily separated and reused after the reaction making these new materials interesting for green chemistry processes.</abstract><doi>10.1039/c1py00044f</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2011-01, Vol.2 (6), p.1275-1278 |
| issn | 1759-9954 1759-9962 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_963915508 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Ionic liquids Iron Magnetic permeability Magnetic susceptibility Microgels Polymers Synthesis |
| title | Synthesis of paramagnetic polymers using ionic liquid chemistry |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T08%3A50%3A53IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20paramagnetic%20polymers%20using%20ionic%20liquid%20chemistry&rft.jtitle=Polymer%20chemistry&rft.au=D%C3%B6bbelin,%20Markus&rft.date=2011-01-01&rft.volume=2&rft.issue=6&rft.spage=1275&rft.epage=1278&rft.pages=1275-1278&rft.issn=1759-9954&rft.eissn=1759-9962&rft_id=info:doi/10.1039/c1py00044f&rft_dat=%3Cproquest_cross%3E963915508%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=963915508&rft_id=info:pmid/&rfr_iscdi=true |