Effect of solution treatment on precipitation behaviors and age hardening response of Al–Cu alloys with Sc addition

► Effects of Sc addition on the precipitation and age hardening of Al–Cu alloy were investigated. ► The critical influence of solution treatment on the Sc effect was revealed. ► A significant enhancement in age hardening response was experimentally found and quantitatively assessed. Influences of so...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 2011-12, Vol.530, p.607-617
Hauptverfasser: Chen, B.A., Pan, L., Wang, R.H., Liu, G., Cheng, P.M., Xiao, L., Sun, J.
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container_title Materials science & engineering. A, Structural materials : properties, microstructure and processing
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creator Chen, B.A.
Pan, L.
Wang, R.H.
Liu, G.
Cheng, P.M.
Xiao, L.
Sun, J.
description ► Effects of Sc addition on the precipitation and age hardening of Al–Cu alloy were investigated. ► The critical influence of solution treatment on the Sc effect was revealed. ► A significant enhancement in age hardening response was experimentally found and quantitatively assessed. Influences of solution treatment on precipitation behaviors and age hardening response of Al–2.5 wt% Cu–0.3 wt% Sc alloys were investigated, in comparison with Sc-free one. The Al 3Sc dispersoids, formed during homogenization, were either survived or dissolved to become Sc solute atoms in solution treatment, depending on the solution temperature. When the temperature for solution treatment is 873 K, most of the Al 3Sc dispersoids were dissolved and a significant enhancement in the uniform precipitation of finer θ′-Al 2Cu particles was achieved in following aging treatment, causing a noticeable increase in peak-aging hardness by about 90% compared to Sc-free alloys. The enhanced age hardening effect was quantitatively related to the remarkable reduction in effective inter-particle spacing of the plate-shaped θ′-Al 2Cu precipitates. When the temperature for solution treatment is 793 K, however, most of the Al 3Sc dispersoids were survived after solution treatment and facilitated the heterogeneous precipitation of θ′-Al 2Cu plates directly on the {1 0 0} facets of dispersoids in following aging treatment. Concomitantly, the uniform precipitation of θ′-Al 2Cu plates was greatly suppressed, resulting in a reduced age hardening response. The age hardening responses were quantitatively assessed by using a modified strengthening model that is applicable to the plate-shaped precipitates. The calculations were in good agreement with experimental results. The present results show the importance of controlling solution treatments to achieve significant promotion effect of Sc addition on the precipitation hardening in heat-treatable aluminum alloys.
doi_str_mv 10.1016/j.msea.2011.10.030
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Influences of solution treatment on precipitation behaviors and age hardening response of Al–2.5 wt% Cu–0.3 wt% Sc alloys were investigated, in comparison with Sc-free one. The Al 3Sc dispersoids, formed during homogenization, were either survived or dissolved to become Sc solute atoms in solution treatment, depending on the solution temperature. When the temperature for solution treatment is 873 K, most of the Al 3Sc dispersoids were dissolved and a significant enhancement in the uniform precipitation of finer θ′-Al 2Cu particles was achieved in following aging treatment, causing a noticeable increase in peak-aging hardness by about 90% compared to Sc-free alloys. The enhanced age hardening effect was quantitatively related to the remarkable reduction in effective inter-particle spacing of the plate-shaped θ′-Al 2Cu precipitates. When the temperature for solution treatment is 793 K, however, most of the Al 3Sc dispersoids were survived after solution treatment and facilitated the heterogeneous precipitation of θ′-Al 2Cu plates directly on the {1 0 0} facets of dispersoids in following aging treatment. Concomitantly, the uniform precipitation of θ′-Al 2Cu plates was greatly suppressed, resulting in a reduced age hardening response. The age hardening responses were quantitatively assessed by using a modified strengthening model that is applicable to the plate-shaped precipitates. The calculations were in good agreement with experimental results. The present results show the importance of controlling solution treatments to achieve significant promotion effect of Sc addition on the precipitation hardening in heat-treatable aluminum alloys.</description><identifier>ISSN: 0921-5093</identifier><identifier>EISSN: 1873-4936</identifier><identifier>DOI: 10.1016/j.msea.2011.10.030</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Aluminum alloys ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Materials science ; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations ; Physics ; Precipitation ; Precipitation hardening ; Sc addition ; Solid solution, precipitation, and dispersion hardening; aging ; Solution treatment ; Treatment of materials and its effects on microstructure and properties</subject><ispartof>Materials science &amp; engineering. 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A, Structural materials : properties, microstructure and processing</title><description>► Effects of Sc addition on the precipitation and age hardening of Al–Cu alloy were investigated. ► The critical influence of solution treatment on the Sc effect was revealed. ► A significant enhancement in age hardening response was experimentally found and quantitatively assessed. Influences of solution treatment on precipitation behaviors and age hardening response of Al–2.5 wt% Cu–0.3 wt% Sc alloys were investigated, in comparison with Sc-free one. The Al 3Sc dispersoids, formed during homogenization, were either survived or dissolved to become Sc solute atoms in solution treatment, depending on the solution temperature. When the temperature for solution treatment is 873 K, most of the Al 3Sc dispersoids were dissolved and a significant enhancement in the uniform precipitation of finer θ′-Al 2Cu particles was achieved in following aging treatment, causing a noticeable increase in peak-aging hardness by about 90% compared to Sc-free alloys. The enhanced age hardening effect was quantitatively related to the remarkable reduction in effective inter-particle spacing of the plate-shaped θ′-Al 2Cu precipitates. When the temperature for solution treatment is 793 K, however, most of the Al 3Sc dispersoids were survived after solution treatment and facilitated the heterogeneous precipitation of θ′-Al 2Cu plates directly on the {1 0 0} facets of dispersoids in following aging treatment. Concomitantly, the uniform precipitation of θ′-Al 2Cu plates was greatly suppressed, resulting in a reduced age hardening response. The age hardening responses were quantitatively assessed by using a modified strengthening model that is applicable to the plate-shaped precipitates. The calculations were in good agreement with experimental results. 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A, Structural materials : properties, microstructure and processing</jtitle><date>2011-12-15</date><risdate>2011</risdate><volume>530</volume><spage>607</spage><epage>617</epage><pages>607-617</pages><issn>0921-5093</issn><eissn>1873-4936</eissn><abstract>► Effects of Sc addition on the precipitation and age hardening of Al–Cu alloy were investigated. ► The critical influence of solution treatment on the Sc effect was revealed. ► A significant enhancement in age hardening response was experimentally found and quantitatively assessed. Influences of solution treatment on precipitation behaviors and age hardening response of Al–2.5 wt% Cu–0.3 wt% Sc alloys were investigated, in comparison with Sc-free one. The Al 3Sc dispersoids, formed during homogenization, were either survived or dissolved to become Sc solute atoms in solution treatment, depending on the solution temperature. When the temperature for solution treatment is 873 K, most of the Al 3Sc dispersoids were dissolved and a significant enhancement in the uniform precipitation of finer θ′-Al 2Cu particles was achieved in following aging treatment, causing a noticeable increase in peak-aging hardness by about 90% compared to Sc-free alloys. The enhanced age hardening effect was quantitatively related to the remarkable reduction in effective inter-particle spacing of the plate-shaped θ′-Al 2Cu precipitates. When the temperature for solution treatment is 793 K, however, most of the Al 3Sc dispersoids were survived after solution treatment and facilitated the heterogeneous precipitation of θ′-Al 2Cu plates directly on the {1 0 0} facets of dispersoids in following aging treatment. Concomitantly, the uniform precipitation of θ′-Al 2Cu plates was greatly suppressed, resulting in a reduced age hardening response. The age hardening responses were quantitatively assessed by using a modified strengthening model that is applicable to the plate-shaped precipitates. The calculations were in good agreement with experimental results. The present results show the importance of controlling solution treatments to achieve significant promotion effect of Sc addition on the precipitation hardening in heat-treatable aluminum alloys.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><doi>10.1016/j.msea.2011.10.030</doi><tpages>11</tpages></addata></record>
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subjects Aluminum alloys
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Precipitation
Precipitation hardening
Sc addition
Solid solution, precipitation, and dispersion hardening
aging
Solution treatment
Treatment of materials and its effects on microstructure and properties
title Effect of solution treatment on precipitation behaviors and age hardening response of Al–Cu alloys with Sc addition
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