Hydrothermal syntheses, crystal structures and physicochemical properties of 2-D and 3-D inorganic coordination cobalt(II)-sulfite polymers

The hydrothermal reaction of [Co(III)(NH(3))(6)]Cl(3) with Na(2)SO(3) yields, depending on the concentration of Na(2)SO(3), compounds {Na[Co(II)(2)(SO(3))(2)(mu(3)-OH)(H(2)O)]}(infinity) (1) and {Na(4)[Co(II)(2)(SO(3))(4)]}(infinity) (2). When (NH(4))(2)SO(3) x H(2)O was substituted for Na(2)SO(3),...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (35), p.8296-8305
Hauptverfasser:	Chilas, George I, Lalioti, Nicolia, Vaimakis, Tiverios, Kubicki, Maciej, Kabanos, Themistoklis
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical bonds Clusters Cobalt Cobalt compounds Crosslinking Ground state Sodium Three dimensional
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!