Synthesis and characterization of well-aligned catalyst-free phosphorus-doped ZnO nanowires

► Well aligned phosphorus-doped ZnO nanowires were grown on (100) Si wafer by the conventional (PVD) method. ► No metal catalysts or buffer layer were used in the growth process. ► The lattice fringes were in the ordered atomic arrangement, corresponding to the (002) fringes of the hexagonal ZnO. ►...

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Veröffentlicht in:Journal of alloys and compounds 2012-01, Vol.512 (1), p.68-72
Hauptverfasser: Karamdel, J., Dee, C.F., Saw, K.G., Varghese, B., Sow, C.H., Ahmad, I., Majlis, B.Y.
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container_end_page 72
container_issue 1
container_start_page 68
container_title Journal of alloys and compounds
container_volume 512
creator Karamdel, J.
Dee, C.F.
Saw, K.G.
Varghese, B.
Sow, C.H.
Ahmad, I.
Majlis, B.Y.
description ► Well aligned phosphorus-doped ZnO nanowires were grown on (100) Si wafer by the conventional (PVD) method. ► No metal catalysts or buffer layer were used in the growth process. ► The lattice fringes were in the ordered atomic arrangement, corresponding to the (002) fringes of the hexagonal ZnO. ► The substitution of P on O sites causes an increment of lattice spacing in doped NWs compared to pure one. Highly crystalline P-doped ZnO nanowires were grown by physical vapour transport technique without presence of any catalysts. Grown nanowires were well aligned and had good crystallinity with evolution of preferred orientation (002). Both EDX and Rutherford backscattering spectrometry (RBS) results revealed that phosphorus atoms were incorporated in the ZnO nanowires with the content of less than 1%. The XRD results confirmed an increase in lattice spacing which is attributed to substitution of P on oxygen sites. The photoluminescence spectra of grown nanowires showed a strong emission peak at 3.248eV with a shoulder at 3.184eV, corresponding with FA (free electron to acceptor) and DAP (donor–acceptor pair) levels of P-doped ZnO. The lattice spacing from HRTEM agrees with the achieved results from XRD measurement.
doi_str_mv 10.1016/j.jallcom.2011.09.018
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Highly crystalline P-doped ZnO nanowires were grown by physical vapour transport technique without presence of any catalysts. Grown nanowires were well aligned and had good crystallinity with evolution of preferred orientation (002). Both EDX and Rutherford backscattering spectrometry (RBS) results revealed that phosphorus atoms were incorporated in the ZnO nanowires with the content of less than 1%. The XRD results confirmed an increase in lattice spacing which is attributed to substitution of P on oxygen sites. The photoluminescence spectra of grown nanowires showed a strong emission peak at 3.248eV with a shoulder at 3.184eV, corresponding with FA (free electron to acceptor) and DAP (donor–acceptor pair) levels of P-doped ZnO. 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subjects Alignment
Alloys
Catalyst free
Catalysts
Chemical synthesis methods
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Free electrons
Lattices
Materials science
Methods of nanofabrication
Nanocrystals and nanoparticles
Nanowires
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures
Phosphorus-doped
Physics
Preferred orientation
Zinc oxide
ZnO
title Synthesis and characterization of well-aligned catalyst-free phosphorus-doped ZnO nanowires
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