Terminal hafnium phosphinidene complexes and phosphinidene ligand exchange

Thermolysis of the structurally characterized hafnium phosphide complex, CpCp*HfMe(PHPh) (2), resulted in formation of the triphosphanato compound CpCp*Hf(P3Ph3) (3). Trapping reactions with PMe3 gave evidence for an intermediate phosphinidene complex, which was corroborated by synthesis of the rela...

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Veröffentlicht in:	Chemical science (Cambridge) 2011-01, Vol.2 (7), p.1320-1325
Hauptverfasser:	Waterman, Rory, Tilley, TDon
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Derivatives Dipping Hafnium Insertion Ligands Synthesis Terminals
Online-Zugang:	Volltext
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