Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes
Nearly monodispersed CuIn0.7Ga0.3Se2 (CIGS) nanocrystals were successfully prepared using the thermal decomposition of copper, indium (In), gallium (Ga), and selenium–oleylamine (OLA) complexes via the heating‐up process. The phase formation sequence was CuSe→CuInSe2→CIGS. The CIGS nanocrystals synt...
Gespeichert in:
| Veröffentlicht in: | Journal of the American Ceramic Society 2011-09, Vol.94 (9), p.3030-3034 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3034 |
|---|---|
| container_issue | 9 |
| container_start_page | 3030 |
| container_title | Journal of the American Ceramic Society |
| container_volume | 94 |
| creator | Hsu, Wei-Hsiang Hsiang, Hsing-I Chang, Yu-Lun Ray, Dah-Tong Yen, Fu-Su |
| description | Nearly monodispersed CuIn0.7Ga0.3Se2 (CIGS) nanocrystals were successfully prepared using the thermal decomposition of copper, indium (In), gallium (Ga), and selenium–oleylamine (OLA) complexes via the heating‐up process. The phase formation sequence was CuSe→CuInSe2→CIGS. The CIGS nanocrystals synthesized using the heating‐up process exhibited a single chalcopyrite phase and its chemical composition was close to stoichiometric. However, phase separation of the In‐rich and Ga‐rich phases was found using the hot‐injection method due to the difference in reactivity between In–OLA and Ga–OLA complexes. |
| doi_str_mv | 10.1111/j.1551-2916.2011.04488.x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_miscellaneous_963863663</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1349422969</sourcerecordid><originalsourceid>FETCH-LOGICAL-i2618-ba71293c83d9605abab150347874c26e2467952bc30aa347a81ccd4fac23577e3</originalsourceid><addsrcrecordid>eNqFkctOGzEUQC1UpKbAP3gHXczUr_FjUwlFkASFAIIIqRvLcW7A6cQTxhM14euZIYhl8ebavkdncxDClOS0Pb-WOS0KmjFDZc4IpTkRQut8e4B6n4tvqEcIYZnSjHxHP1Jatk9qtOihdFnVK9eEKuJr8M8uhrRKuFrg_uZsFEmuBo7k_Oc9MDxxsfL1LjWuLEMDCd_vYvMMKbzCHE9TiE94WDXZKC7BvwtdnOMhtPL4lE3X-LauPKQE6RgdLlyZ4ORjHqHp5cVDf5iNbwaj_vk4C0xSnc2cosxwr_ncSFK4mZvRgnChtBKeSWBCKlOwmefEufbbaer9XCycZ7xQCvgROt1713X1soHU2FVIHsrSRag2yRrJteRS8pY8-y9JpWmdWivzNcqFEYwZ2aG_9-i_UMLOruuwcvXOUmK7cnZpu0C2C2S7cva9nN3aq_P-RXdtBdleEFID20-Bq_9aqbgq7ONkYMcP9PpuICf2D38DJMOcmQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1349422969</pqid></control><display><type>article</type><title>Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Hsu, Wei-Hsiang ; Hsiang, Hsing-I ; Chang, Yu-Lun ; Ray, Dah-Tong ; Yen, Fu-Su</creator><creatorcontrib>Hsu, Wei-Hsiang ; Hsiang, Hsing-I ; Chang, Yu-Lun ; Ray, Dah-Tong ; Yen, Fu-Su</creatorcontrib><description>Nearly monodispersed CuIn0.7Ga0.3Se2 (CIGS) nanocrystals were successfully prepared using the thermal decomposition of copper, indium (In), gallium (Ga), and selenium–oleylamine (OLA) complexes via the heating‐up process. The phase formation sequence was CuSe→CuInSe2→CIGS. The CIGS nanocrystals synthesized using the heating‐up process exhibited a single chalcopyrite phase and its chemical composition was close to stoichiometric. However, phase separation of the In‐rich and Ga‐rich phases was found using the hot‐injection method due to the difference in reactivity between In–OLA and Ga–OLA complexes.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1551-2916.2011.04488.x</identifier><language>eng</language><publisher>Malden, USA: Blackwell Publishing Inc</publisher><subject>CERAMICS ; CHALCOPYRITE ; Chemical composition ; CIGS ; COMPOSITION ; COPPER INDIUM SELENIDE ; COPPER SELENIDE ; CRYSTAL STRUCTURE ; DECOMPOSITION ; Gallium ; HEATING ; Indium ; Nanocrystals ; Phase separation ; Thermal decomposition</subject><ispartof>Journal of the American Ceramic Society, 2011-09, Vol.94 (9), p.3030-3034</ispartof><rights>2011 The American Ceramic Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fj.1551-2916.2011.04488.x$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fj.1551-2916.2011.04488.x$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27907,27908,45557,45558</link.rule.ids></links><search><creatorcontrib>Hsu, Wei-Hsiang</creatorcontrib><creatorcontrib>Hsiang, Hsing-I</creatorcontrib><creatorcontrib>Chang, Yu-Lun</creatorcontrib><creatorcontrib>Ray, Dah-Tong</creatorcontrib><creatorcontrib>Yen, Fu-Su</creatorcontrib><title>Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes</title><title>Journal of the American Ceramic Society</title><description>Nearly monodispersed CuIn0.7Ga0.3Se2 (CIGS) nanocrystals were successfully prepared using the thermal decomposition of copper, indium (In), gallium (Ga), and selenium–oleylamine (OLA) complexes via the heating‐up process. The phase formation sequence was CuSe→CuInSe2→CIGS. The CIGS nanocrystals synthesized using the heating‐up process exhibited a single chalcopyrite phase and its chemical composition was close to stoichiometric. However, phase separation of the In‐rich and Ga‐rich phases was found using the hot‐injection method due to the difference in reactivity between In–OLA and Ga–OLA complexes.</description><subject>CERAMICS</subject><subject>CHALCOPYRITE</subject><subject>Chemical composition</subject><subject>CIGS</subject><subject>COMPOSITION</subject><subject>COPPER INDIUM SELENIDE</subject><subject>COPPER SELENIDE</subject><subject>CRYSTAL STRUCTURE</subject><subject>DECOMPOSITION</subject><subject>Gallium</subject><subject>HEATING</subject><subject>Indium</subject><subject>Nanocrystals</subject><subject>Phase separation</subject><subject>Thermal decomposition</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkctOGzEUQC1UpKbAP3gHXczUr_FjUwlFkASFAIIIqRvLcW7A6cQTxhM14euZIYhl8ebavkdncxDClOS0Pb-WOS0KmjFDZc4IpTkRQut8e4B6n4tvqEcIYZnSjHxHP1Jatk9qtOihdFnVK9eEKuJr8M8uhrRKuFrg_uZsFEmuBo7k_Oc9MDxxsfL1LjWuLEMDCd_vYvMMKbzCHE9TiE94WDXZKC7BvwtdnOMhtPL4lE3X-LauPKQE6RgdLlyZ4ORjHqHp5cVDf5iNbwaj_vk4C0xSnc2cosxwr_ncSFK4mZvRgnChtBKeSWBCKlOwmefEufbbaer9XCycZ7xQCvgROt1713X1soHU2FVIHsrSRag2yRrJteRS8pY8-y9JpWmdWivzNcqFEYwZ2aG_9-i_UMLOruuwcvXOUmK7cnZpu0C2C2S7cva9nN3aq_P-RXdtBdleEFID20-Bq_9aqbgq7ONkYMcP9PpuICf2D38DJMOcmQ</recordid><startdate>201109</startdate><enddate>201109</enddate><creator>Hsu, Wei-Hsiang</creator><creator>Hsiang, Hsing-I</creator><creator>Chang, Yu-Lun</creator><creator>Ray, Dah-Tong</creator><creator>Yen, Fu-Su</creator><general>Blackwell Publishing Inc</general><scope>BSCLL</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope></search><sort><creationdate>201109</creationdate><title>Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes</title><author>Hsu, Wei-Hsiang ; Hsiang, Hsing-I ; Chang, Yu-Lun ; Ray, Dah-Tong ; Yen, Fu-Su</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2618-ba71293c83d9605abab150347874c26e2467952bc30aa347a81ccd4fac23577e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>CERAMICS</topic><topic>CHALCOPYRITE</topic><topic>Chemical composition</topic><topic>CIGS</topic><topic>COMPOSITION</topic><topic>COPPER INDIUM SELENIDE</topic><topic>COPPER SELENIDE</topic><topic>CRYSTAL STRUCTURE</topic><topic>DECOMPOSITION</topic><topic>Gallium</topic><topic>HEATING</topic><topic>Indium</topic><topic>Nanocrystals</topic><topic>Phase separation</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hsu, Wei-Hsiang</creatorcontrib><creatorcontrib>Hsiang, Hsing-I</creatorcontrib><creatorcontrib>Chang, Yu-Lun</creatorcontrib><creatorcontrib>Ray, Dah-Tong</creatorcontrib><creatorcontrib>Yen, Fu-Su</creatorcontrib><collection>Istex</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hsu, Wei-Hsiang</au><au>Hsiang, Hsing-I</au><au>Chang, Yu-Lun</au><au>Ray, Dah-Tong</au><au>Yen, Fu-Su</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2011-09</date><risdate>2011</risdate><volume>94</volume><issue>9</issue><spage>3030</spage><epage>3034</epage><pages>3030-3034</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Nearly monodispersed CuIn0.7Ga0.3Se2 (CIGS) nanocrystals were successfully prepared using the thermal decomposition of copper, indium (In), gallium (Ga), and selenium–oleylamine (OLA) complexes via the heating‐up process. The phase formation sequence was CuSe→CuInSe2→CIGS. The CIGS nanocrystals synthesized using the heating‐up process exhibited a single chalcopyrite phase and its chemical composition was close to stoichiometric. However, phase separation of the In‐rich and Ga‐rich phases was found using the hot‐injection method due to the difference in reactivity between In–OLA and Ga–OLA complexes.</abstract><cop>Malden, USA</cop><pub>Blackwell Publishing Inc</pub><doi>10.1111/j.1551-2916.2011.04488.x</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7820 |
| ispartof | Journal of the American Ceramic Society, 2011-09, Vol.94 (9), p.3030-3034 |
| issn | 0002-7820 1551-2916 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_963863663 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | CERAMICS CHALCOPYRITE Chemical composition CIGS COMPOSITION COPPER INDIUM SELENIDE COPPER SELENIDE CRYSTAL STRUCTURE DECOMPOSITION Gallium HEATING Indium Nanocrystals Phase separation Thermal decomposition |
| title | Formation Mechanisms of Cu(In0.7Ga0.3)Se2 Nanocrystallites Synthesized Using Hot-Injection and Heating-Up Processes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T22%3A42%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Formation%20Mechanisms%20of%20Cu(In0.7Ga0.3)Se2%20Nanocrystallites%20Synthesized%20Using%20Hot-Injection%20and%20Heating-Up%20Processes&rft.jtitle=Journal%20of%20the%20American%20Ceramic%20Society&rft.au=Hsu,%20Wei-Hsiang&rft.date=2011-09&rft.volume=94&rft.issue=9&rft.spage=3030&rft.epage=3034&rft.pages=3030-3034&rft.issn=0002-7820&rft.eissn=1551-2916&rft_id=info:doi/10.1111/j.1551-2916.2011.04488.x&rft_dat=%3Cproquest_wiley%3E1349422969%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1349422969&rft_id=info:pmid/&rfr_iscdi=true |