New Microwave Dielectric Ceramics BaLn2(MoO4)4 (Ln = Nd and Sm) with Low Loss

In the present work, a pure monoclinic phase of BaNd2(MoO4)4 and BaSm2(MoO4)4 was formed at 850°C and 600°C, respectively, via a solid‐state reaction method. The ceramic samples were found to be well densified at 960°C. Dense and homogeneous microstructures were revealed from the scanning electron m...

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Veröffentlicht in:Journal of the American Ceramic Society 2011-09, Vol.94 (9), p.2800-2803
Hauptverfasser: Zhou, Di, Pang, Li-Xia, Guo, Jing, Wu, Ying, Zhang, Gao-Qun, Dai, Wei, Wang, Hong, Yao, Xi
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container_end_page 2803
container_issue 9
container_start_page 2800
container_title Journal of the American Ceramic Society
container_volume 94
creator Zhou, Di
Pang, Li-Xia
Guo, Jing
Wu, Ying
Zhang, Gao-Qun
Dai, Wei
Wang, Hong
Yao, Xi
description In the present work, a pure monoclinic phase of BaNd2(MoO4)4 and BaSm2(MoO4)4 was formed at 850°C and 600°C, respectively, via a solid‐state reaction method. The ceramic samples were found to be well densified at 960°C. Dense and homogeneous microstructures were revealed from the scanning electron microscopy. The microwave dielectric behaviors were studied as a function of sintering temperature and characterized in the temperature range 25°C–120°C. The best properties were obtained in ceramics sintered at 960°C with a permittivity ~11.7, a Q × f value of 45 000 GHz and a temperature coefficient of frequency about −41 ppm/°C for BaNd2(MoO4)4 ceramic at 9.9 GHz, and a permittivity ~11.8, a Q × f value of 20 000 GHz, and a temperature coefficient of frequency about −34 ppm/°C for BaSm2(MoO4)4 ceramic at 9.7 GHz, respectively.
doi_str_mv 10.1111/j.1551-2916.2011.04727.x
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subjects Ceramics
Coefficients
Dielectric constant
Dielectrics
Microstructure
Microwaves
Optimization
Permittivity
Sintering
title New Microwave Dielectric Ceramics BaLn2(MoO4)4 (Ln = Nd and Sm) with Low Loss
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