Dark state vibronic coupling in the A(2[capital Pi]) ? [X with combining tilde](2[capital Sigma]+) band of ethynyl radical via high resolution infrared absorption spectroscopy

The high resolution infrared spectrum for the A (2[capital Pi]) ? [X with combining tilde] (2[capital Sigma]+) origin band of jet-cooled ethynyl radical (C2H) in the gas phase is reported, which exhibits a strong, parity-specific local perturbation in the upper 2[capital Pi]1/2 state. Based on revis...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2011-01, Vol.13 (39), p.17474-17483
Hauptverfasser:	Sharp-Williams, Erin N, Roberts, Melanie A, Nesbitt, David J
Format:	Artikel
Sprache:	eng
Schlagworte:	Combustion Coriolis force High resolution Infrared absorption Joining Origins Radicals Rotational
Online-Zugang:	Volltext
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