Continuous modulation of electronic structure of stable thiolate-protected Au25 cluster by Ag doping

Continuous modulation of electronic structure of stable thiolate-protected Au25 cluster by Ag doping

The effect of Ag doping on the electronic structure of a stable thiolate-protected Au(25) cluster (Au(25)(SR)(18)) was studied by measuring the optical spectra of Au(25-n)Ag(n)(SC(12)H(25))(18) (n = 0-11) and the results reveal that the electronic structure of Au(25)(SC(12)H(25))(18) is sensitive to...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-07, Vol.46 (26), p.4713-4715
Hauptverfasser: Negishi, Yuichi, Iwai, Takeyuki, Ide, Mao
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Sprache:eng
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Atomic structure
Clusters
Doping
Electronic structure
Modulation
Silver
Spectra
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container_title Chemical communications (Cambridge, England)
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creator Negishi, Yuichi
Iwai, Takeyuki
Ide, Mao
description The effect of Ag doping on the electronic structure of a stable thiolate-protected Au(25) cluster (Au(25)(SR)(18)) was studied by measuring the optical spectra of Au(25-n)Ag(n)(SC(12)H(25))(18) (n = 0-11) and the results reveal that the electronic structure of Au(25)(SC(12)H(25))(18) is sensitive to Ag doping and is continuously modulated by incorporation of Ag atoms.
doi_str_mv 10.1039/c0cc01021a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Atomic structure
Clusters
Doping
Electronic structure
Modulation
Silver
Spectra
title Continuous modulation of electronic structure of stable thiolate-protected Au25 cluster by Ag doping
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