One-pot self-assembly of flower-like Cu2S structures with near-infrared photoluminescent properties

Novel flower-like Cu2S structures with strong photoluminescence emission in the near-infrared region have been synthesized via a simple, low-cost, and environmentally friendly chemical reaction from an oleic acid solution containing Cu(NO3)2[middle dot]3H2O and S. Field-emission scanning electron mi...

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Veröffentlicht in:CrystEngComm 2011-01, Vol.13 (21), p.6549-6554
Hauptverfasser: Li, Na, Zhang, Xiaoling, Chen, Shutang, Yang, Wen, Kang, Huaizhi, Tan, Weihong
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container_issue 21
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container_title CrystEngComm
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creator Li, Na
Zhang, Xiaoling
Chen, Shutang
Yang, Wen
Kang, Huaizhi
Tan, Weihong
description Novel flower-like Cu2S structures with strong photoluminescence emission in the near-infrared region have been synthesized via a simple, low-cost, and environmentally friendly chemical reaction from an oleic acid solution containing Cu(NO3)2[middle dot]3H2O and S. Field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) reveal the flower-like nanostructures are monodispersed in large quantities. The formation of the flower-like structures can be tuned by adjusting the molar ratio of the two reaction reagents, concentration of precursors, reaction temperature, or reaction time. The possible growth mechanism of the formation of flower-like Cu2S structures was proposed.
doi_str_mv 10.1039/c1ce05603d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Copper sulfides
Nanocomposites
Nanomaterials
Nanostructure
Photoluminescence
Precursors
Scanning electron microscopy
Self assembly
title One-pot self-assembly of flower-like Cu2S structures with near-infrared photoluminescent properties
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