Observation and partly characterisation of silver nanoparticles in X-ray irradiated radiophotoluminescent phosphate glass

► Direct observation and characterisation of silver nanoparticles in X-ray irradiated phosphate glass were demonstrated. ► Correlations between the Ag + concentration and X-ray-induced silver species were examined. ► Evidence of spherical silver nanoparticles with sizes ranging from 5 to 30 nm was o...

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Veröffentlicht in:Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms Beam interactions with materials and atoms, 2011-12, Vol.269 (23), p.2814-2818
Hauptverfasser: Zheng, Wang, Kurobori, Toshio
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Kurobori, Toshio
description ► Direct observation and characterisation of silver nanoparticles in X-ray irradiated phosphate glass were demonstrated. ► Correlations between the Ag + concentration and X-ray-induced silver species were examined. ► Evidence of spherical silver nanoparticles with sizes ranging from 5 to 30 nm was obtained. ► Three-dimensional contour plots using combined excitation–emission spectroscopy were recorded. The direct observation and characterisation of silver nanoparticles or clusters embedded in a Ag +-activated phosphate glass was demonstrated. Correlations between the isolated Ag + concentration and X-ray-induced silver species were systematically examined using optical measurements. Evidence of spherical silver nanoparticles or clusters with sizes ranging from 5 to 30 nm was obtained from the lattice spacings and from energy dispersive X-ray spectroscopy combined with transmission electron microscopy. Three-dimensional contour plots using combined excitation–emission spectroscopy were also recorded to allow identification of the complicated spectroscopic features of the sample.
doi_str_mv 10.1016/j.nimb.2011.08.019
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subjects Clusters
Excitation spectra
Glass dosimeter
Nanoparticles
Phosphate glass
Radiophotoluminescence (RPL)
Shape
Silver
Silver defects
Spectroscopy
TEM
Three dimensional
title Observation and partly characterisation of silver nanoparticles in X-ray irradiated radiophotoluminescent phosphate glass
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