Structure of cesium loaded iron phosphate glasses: An infrared and Raman spectroscopy study
The structure of cesium loaded iron phosphate glasses (IPG) was investigated using infrared and Raman spectroscopy. The spectra of the cesium doped samples revealed a structural modification of the parent glass owing to the incorporation of cesium. The structural changes could be correlated with the...
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| Veröffentlicht in: | Journal of nuclear materials 2012, Vol.420 (1), p.49-53 |
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| container_issue | 1 |
| container_start_page | 49 |
| container_title | Journal of nuclear materials |
| container_volume | 420 |
| creator | Joseph, Kitheri Premila, M. Amarendra, G. Govindan Kutty, K.V. Sundar, C.S. Vasudeva Rao, P.R. |
| description | The structure of cesium loaded iron phosphate glasses (IPG) was investigated using infrared and Raman spectroscopy. The spectra of the cesium doped samples revealed a structural modification of the parent glass owing to the incorporation of cesium. The structural changes could be correlated with the variation observed in the glass transition temperature of these glasses. Increased Cs-mediated cationic cross linking appears to be the reason for the initial rise in glass transition temperature up to 21
mol% Cs
2O in IPG; while, breakdown of the phosphate network with increasing cesium content, brings down the glass transition temperature. |
| doi_str_mv | 10.1016/j.jnucmat.2011.09.008 |
| format | Article |
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mol% Cs
2O in IPG; while, breakdown of the phosphate network with increasing cesium content, brings down the glass transition temperature.</description><subject>Applied sciences</subject><subject>Cesium</subject><subject>Controled nuclear fusion plants</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Exact sciences and technology</subject><subject>Fission nuclear power plants</subject><subject>Fuels</subject><subject>Glass</subject><subject>Glass transition temperature</subject><subject>Infrared</subject><subject>Installations for energy generation and conversion: thermal and electrical energy</subject><subject>Iron</subject><subject>Nuclear fuels</subject><subject>Phosphate glass</subject><subject>Raman spectroscopy</subject><subject>Spectra</subject><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkE2L1TAUhoMoeL3jTxCyEd20niRN27iRYdAZYWDAGVcuQpoPJ5c2rTmtcP-9Ge7Fpa7O5nnPy_sQ8oZBzYC1Hw71IW12MmvNgbEaVA3QPyM71neianoOz8kOgPNKMCZfkleIBwCQCuSO_Lhf82bXLXs6B2o9xm2i42ycdzTmOdHlccbl0aye_hwNoseP9DLRmEI2uTAmOfrNTCZRXLxd84x2Xo4U180dL8iLYEb0r893T75_-fxwdVPd3l1_vbq8rWzTwVrZtowYBPPKetcPnVMiGNYrBtIJUEFC1xnbDkE1TQNOMT6I1sMw8MYIFYLYk3env0uef20eVz1FtH4cTfLzhlq1opdMdW0h3_-TZLIU9h0v4vZEnlBbNmH2QS85TiYfNQP9pF0f9Fm7ftKuQemiveTenisMWjMWTclG_Bvmsml61vLCfTpxvpj5HX3WaKNPRUHMRaR2c_xP0x-nqJup</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Joseph, Kitheri</creator><creator>Premila, M.</creator><creator>Amarendra, G.</creator><creator>Govindan Kutty, K.V.</creator><creator>Sundar, C.S.</creator><creator>Vasudeva Rao, P.R.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2012</creationdate><title>Structure of cesium loaded iron phosphate glasses: An infrared and Raman spectroscopy study</title><author>Joseph, Kitheri ; Premila, M. ; Amarendra, G. ; Govindan Kutty, K.V. ; Sundar, C.S. ; Vasudeva Rao, P.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c470t-c6016b31e9ced8b7d93fa189105d309f5077ac6bf94440d912b36e0bb24a39ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Cesium</topic><topic>Controled nuclear fusion plants</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>Fission nuclear power plants</topic><topic>Fuels</topic><topic>Glass</topic><topic>Glass transition temperature</topic><topic>Infrared</topic><topic>Installations for energy generation and conversion: thermal and electrical energy</topic><topic>Iron</topic><topic>Nuclear fuels</topic><topic>Phosphate glass</topic><topic>Raman spectroscopy</topic><topic>Spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Joseph, Kitheri</creatorcontrib><creatorcontrib>Premila, M.</creatorcontrib><creatorcontrib>Amarendra, G.</creatorcontrib><creatorcontrib>Govindan Kutty, K.V.</creatorcontrib><creatorcontrib>Sundar, C.S.</creatorcontrib><creatorcontrib>Vasudeva Rao, P.R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Joseph, Kitheri</au><au>Premila, M.</au><au>Amarendra, G.</au><au>Govindan Kutty, K.V.</au><au>Sundar, C.S.</au><au>Vasudeva Rao, P.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of cesium loaded iron phosphate glasses: An infrared and Raman spectroscopy study</atitle><jtitle>Journal of nuclear materials</jtitle><date>2012</date><risdate>2012</risdate><volume>420</volume><issue>1</issue><spage>49</spage><epage>53</epage><pages>49-53</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><coden>JNUMAM</coden><abstract>The structure of cesium loaded iron phosphate glasses (IPG) was investigated using infrared and Raman spectroscopy. 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mol% Cs
2O in IPG; while, breakdown of the phosphate network with increasing cesium content, brings down the glass transition temperature.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnucmat.2011.09.008</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of nuclear materials, 2012, Vol.420 (1), p.49-53 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Cesium Controled nuclear fusion plants Energy Energy. Thermal use of fuels Exact sciences and technology Fission nuclear power plants Fuels Glass Glass transition temperature Infrared Installations for energy generation and conversion: thermal and electrical energy Iron Nuclear fuels Phosphate glass Raman spectroscopy Spectra |
| title | Structure of cesium loaded iron phosphate glasses: An infrared and Raman spectroscopy study |
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