Thermolysis of hydrogen sulphate, nitrate and perchlorate salts of diphenylamine. Part LXVIII
Hydrogen sulphate, nitrate and perchlorate salts of diphenylamine have been prepared and characterized by elemental, spectral and gravimetric analyses. Thermal decomposition of these salts has been evaluated by TG (static air) and DSC (inert atmosphere). The proton transfer reaction plays a major ro...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2010-11, Vol.102 (2), p.723-728 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Kapoor, Inder Pal Singh Kapoor, Manisha Singh, Gurdip |
| description | Hydrogen sulphate, nitrate and perchlorate salts of diphenylamine have been prepared and characterized by elemental, spectral and gravimetric analyses. Thermal decomposition of these salts has been evaluated by TG (static air) and DSC (inert atmosphere). The proton transfer reaction plays a major role during thermolysis of these salts. The diphenylammonium hydrogen sulphate under thermal and microwave irradiation forms 4-(phenylamino) benzenesulphonic acid by sulphonation process, whereas nitrate and perchlorate salts do not form corresponding nitro and perchloro derivatives, rather they ignite and explode, respectively, to form gaseous products along with a residual carbon . |
| doi_str_mv | 10.1007/s10973-009-0230-1 |
| format | Article |
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The diphenylammonium hydrogen sulphate under thermal and microwave irradiation forms 4-(phenylamino) benzenesulphonic acid by sulphonation process, whereas nitrate and perchlorate salts do not form corresponding nitro and perchloro derivatives, rather they ignite and explode, respectively, to form gaseous products along with a residual carbon .</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-009-0230-1</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Applied sciences ; Benzenesulphonic acids ; Carbon ; Chemical industry and chemicals ; Chemistry ; Chemistry and Materials Science ; Derivatives ; Exact sciences and technology ; Industrial chemicals ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Microwaves ; Nitrates ; Perchlorates ; Physical Chemistry ; Polymer Sciences ; Powders, propellants, explosives ; Spectra ; Sulfates</subject><ispartof>Journal of thermal analysis and calorimetry, 2010-11, Vol.102 (2), p.723-728</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2009</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c350t-d7e648757629183b97a715eb4cfee4583a31bd71addeb6b1aa5ca9cf5f27f0e33</citedby><cites>FETCH-LOGICAL-c350t-d7e648757629183b97a715eb4cfee4583a31bd71addeb6b1aa5ca9cf5f27f0e33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-009-0230-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-009-0230-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23351675$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kapoor, Inder Pal Singh</creatorcontrib><creatorcontrib>Kapoor, Manisha</creatorcontrib><creatorcontrib>Singh, Gurdip</creatorcontrib><title>Thermolysis of hydrogen sulphate, nitrate and perchlorate salts of diphenylamine. 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The diphenylammonium hydrogen sulphate under thermal and microwave irradiation forms 4-(phenylamino) benzenesulphonic acid by sulphonation process, whereas nitrate and perchlorate salts do not form corresponding nitro and perchloro derivatives, rather they ignite and explode, respectively, to form gaseous products along with a residual carbon .</description><subject>Analytical Chemistry</subject><subject>Applied sciences</subject><subject>Benzenesulphonic acids</subject><subject>Carbon</subject><subject>Chemical industry and chemicals</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Derivatives</subject><subject>Exact sciences and technology</subject><subject>Industrial chemicals</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Microwaves</subject><subject>Nitrates</subject><subject>Perchlorates</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Powders, propellants, explosives</subject><subject>Spectra</subject><subject>Sulfates</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kEtPwzAQhCMEElXpD-CWC-JCijeu4_iIKh6VKsGhIC7I2jibJsh1gp0e-u9JH-LIaWe1M5-0E0XXwKbAmLwPwJTkCWMqYSlnCZxFIxB5nqQqzc4HzQedgWCX0SSEpmApsEyJXI2ir1VNftPaXWhC3FZxvSt9uyYXh63tauzpLnZN7wcRoyvjjrypbXvYA9r-kCmbria3s7hpHE3jN_R9vPz8WCwWV9FFhTbQ5DTH0fvT42r-kixfnxfzh2ViuGB9UkrKZrkUMksV5LxQEiUIKmamIpqJnCOHopSAZUlFVgCiMKhMJapUVow4H0e3R27n258thV5vmmDIWnTUboNWGc8FqJkYnHB0Gt-G4KnSnW826HcamN6XqY9l6qFMvS9Tw5C5OdExGLSVR2ea8BdMOReQyT07PfrCcHJr8vq73Xo3PP4P_BeqPoUV</recordid><startdate>20101101</startdate><enddate>20101101</enddate><creator>Kapoor, Inder Pal Singh</creator><creator>Kapoor, Manisha</creator><creator>Singh, Gurdip</creator><general>Springer Netherlands</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20101101</creationdate><title>Thermolysis of hydrogen sulphate, nitrate and perchlorate salts of diphenylamine. 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The diphenylammonium hydrogen sulphate under thermal and microwave irradiation forms 4-(phenylamino) benzenesulphonic acid by sulphonation process, whereas nitrate and perchlorate salts do not form corresponding nitro and perchloro derivatives, rather they ignite and explode, respectively, to form gaseous products along with a residual carbon .</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-009-0230-1</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2010-11, Vol.102 (2), p.723-728 |
| issn | 1388-6150 1588-2926 1572-8943 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Analytical Chemistry Applied sciences Benzenesulphonic acids Carbon Chemical industry and chemicals Chemistry Chemistry and Materials Science Derivatives Exact sciences and technology Industrial chemicals Inorganic Chemistry Measurement Science and Instrumentation Microwaves Nitrates Perchlorates Physical Chemistry Polymer Sciences Powders, propellants, explosives Spectra Sulfates |
| title | Thermolysis of hydrogen sulphate, nitrate and perchlorate salts of diphenylamine. Part LXVIII |
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