Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance
[Display omitted] ► Sulfated tin oxide is an effective catalyst for the dehydration of xylose to furfural. ► Sulfated tin oxide catalyst can be reused through the re-sulfation process. ► Both of Lewis and Brønsted acid sites collaborate to produce furfural. Various sulfated metal oxides were tested...
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| Veröffentlicht in: | Applied catalysis. A, General General, 2011-11, Vol.408 (1), p.117-124 |
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| container_title | Applied catalysis. A, General |
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| creator | Suzuki, Takeshi Yokoi, Toshiyuki Otomo, Ryoichi Kondo, Junko N. Tatsumi, Takashi |
| description | [Display omitted]
► Sulfated tin oxide is an effective catalyst for the dehydration of xylose to furfural. ► Sulfated tin oxide catalyst can be reused through the re-sulfation process. ► Both of Lewis and Brønsted acid sites collaborate to produce furfural.
Various sulfated metal oxides were tested as solid acid catalyst for the dehydration of xylose to furfural under milder conditions. On the basis of our findings that sulfated tin oxide exhibited the highest catalytic activity, the effects of the content of SO
4
2− group and the calcination temperature on the structural properties and catalytic performance were investigated, and the reusability of the sulfated tin oxide catalyst was evaluated. The acid property on the sulfated tin oxide catalyst was characterized by in situ FT-IR observations of the CO-adsorbed sample. Finally, the reaction mechanism of dehydration of xylose over the SO
4
2−/SnO
2 catalyst was considered. |
| doi_str_mv | 10.1016/j.apcata.2011.09.009 |
| format | Article |
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► Sulfated tin oxide is an effective catalyst for the dehydration of xylose to furfural. ► Sulfated tin oxide catalyst can be reused through the re-sulfation process. ► Both of Lewis and Brønsted acid sites collaborate to produce furfural.
Various sulfated metal oxides were tested as solid acid catalyst for the dehydration of xylose to furfural under milder conditions. On the basis of our findings that sulfated tin oxide exhibited the highest catalytic activity, the effects of the content of SO
4
2− group and the calcination temperature on the structural properties and catalytic performance were investigated, and the reusability of the sulfated tin oxide catalyst was evaluated. The acid property on the sulfated tin oxide catalyst was characterized by in situ FT-IR observations of the CO-adsorbed sample. Finally, the reaction mechanism of dehydration of xylose over the SO
4
2−/SnO
2 catalyst was considered.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2011.09.009</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Catalysis ; Catalysts ; Chemistry ; Cobalt ; Dehydration ; Dehydration of xylose ; Exact sciences and technology ; General and physical chemistry ; Metal oxides ; Sulfated metal oxides ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ; Tin dioxide ; Tin oxide ; Tin oxides ; Xylose</subject><ispartof>Applied catalysis. A, General, 2011-11, Vol.408 (1), p.117-124</ispartof><rights>2011 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-3190e5f79a859b959e7dc759776f9e2ac30f3687df8ed8e5ade46611a72374e83</citedby><cites>FETCH-LOGICAL-c434t-3190e5f79a859b959e7dc759776f9e2ac30f3687df8ed8e5ade46611a72374e83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0926860X11005345$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25501469$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Suzuki, Takeshi</creatorcontrib><creatorcontrib>Yokoi, Toshiyuki</creatorcontrib><creatorcontrib>Otomo, Ryoichi</creatorcontrib><creatorcontrib>Kondo, Junko N.</creatorcontrib><creatorcontrib>Tatsumi, Takashi</creatorcontrib><title>Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance</title><title>Applied catalysis. A, General</title><description>[Display omitted]
► Sulfated tin oxide is an effective catalyst for the dehydration of xylose to furfural. ► Sulfated tin oxide catalyst can be reused through the re-sulfation process. ► Both of Lewis and Brønsted acid sites collaborate to produce furfural.
Various sulfated metal oxides were tested as solid acid catalyst for the dehydration of xylose to furfural under milder conditions. On the basis of our findings that sulfated tin oxide exhibited the highest catalytic activity, the effects of the content of SO
4
2− group and the calcination temperature on the structural properties and catalytic performance were investigated, and the reusability of the sulfated tin oxide catalyst was evaluated. The acid property on the sulfated tin oxide catalyst was characterized by in situ FT-IR observations of the CO-adsorbed sample. Finally, the reaction mechanism of dehydration of xylose over the SO
4
2−/SnO
2 catalyst was considered.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Cobalt</subject><subject>Dehydration</subject><subject>Dehydration of xylose</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Metal oxides</subject><subject>Sulfated metal oxides</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><subject>Tin dioxide</subject><subject>Tin oxide</subject><subject>Tin oxides</subject><subject>Xylose</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9Uc1uFSEUJkYTr9U3cMHGuJoRhuHPhYmprTZp4sYm3RGEQ8rN3GEEpul9El9Xxnvj0hWE7-8cPoTeUtJTQsWHfW8XZ6vtB0JpT3RPiH6GdlRJ1jEl-XO0I3oQnRLk_iV6VcqeEDKMmu_Q7y_wcPTZ1phmnAJ-Ok6pAE6PkHFZp2AreFxjw56iB7ylTMdSP-KbOUwrzA7KJqsPgJcMiz07uTT7uN0aOv9FS82rq2u2UyOmBXKNTWpnf_as0eH2GlI-2Ob6Gr0Idirw5nxeoLvrqx-X37rb719vLj_fdm5kY-0Y1QR4kNoqrn9qrkF6J7mWUgQNg3WMBCaU9EGBV8Cth1EISq0cmBxBsQv0_uTbhvq1QqnmEIuDabIzpLUYLZgaFRdDY44npsuplAzBLDkebD4aSsxWg9mbUw1mq8EQbVoNTfbuHGCLs1PIbbtY_mkHzgkdxcb7dOJB2_YxQjbFxe1_fczgqvEp_j_oD1iRpBM</recordid><startdate>20111128</startdate><enddate>20111128</enddate><creator>Suzuki, Takeshi</creator><creator>Yokoi, Toshiyuki</creator><creator>Otomo, Ryoichi</creator><creator>Kondo, Junko N.</creator><creator>Tatsumi, Takashi</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20111128</creationdate><title>Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance</title><author>Suzuki, Takeshi ; Yokoi, Toshiyuki ; Otomo, Ryoichi ; Kondo, Junko N. ; Tatsumi, Takashi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-3190e5f79a859b959e7dc759776f9e2ac30f3687df8ed8e5ade46611a72374e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Cobalt</topic><topic>Dehydration</topic><topic>Dehydration of xylose</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Metal oxides</topic><topic>Sulfated metal oxides</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><topic>Tin dioxide</topic><topic>Tin oxide</topic><topic>Tin oxides</topic><topic>Xylose</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Suzuki, Takeshi</creatorcontrib><creatorcontrib>Yokoi, Toshiyuki</creatorcontrib><creatorcontrib>Otomo, Ryoichi</creatorcontrib><creatorcontrib>Kondo, Junko N.</creatorcontrib><creatorcontrib>Tatsumi, Takashi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Suzuki, Takeshi</au><au>Yokoi, Toshiyuki</au><au>Otomo, Ryoichi</au><au>Kondo, Junko N.</au><au>Tatsumi, Takashi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance</atitle><jtitle>Applied catalysis. A, General</jtitle><date>2011-11-28</date><risdate>2011</risdate><volume>408</volume><issue>1</issue><spage>117</spage><epage>124</epage><pages>117-124</pages><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>[Display omitted]
► Sulfated tin oxide is an effective catalyst for the dehydration of xylose to furfural. ► Sulfated tin oxide catalyst can be reused through the re-sulfation process. ► Both of Lewis and Brønsted acid sites collaborate to produce furfural.
Various sulfated metal oxides were tested as solid acid catalyst for the dehydration of xylose to furfural under milder conditions. On the basis of our findings that sulfated tin oxide exhibited the highest catalytic activity, the effects of the content of SO
4
2− group and the calcination temperature on the structural properties and catalytic performance were investigated, and the reusability of the sulfated tin oxide catalyst was evaluated. The acid property on the sulfated tin oxide catalyst was characterized by in situ FT-IR observations of the CO-adsorbed sample. Finally, the reaction mechanism of dehydration of xylose over the SO
4
2−/SnO
2 catalyst was considered.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2011.09.009</doi><tpages>8</tpages></addata></record> |
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| ispartof | Applied catalysis. A, General, 2011-11, Vol.408 (1), p.117-124 |
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| subjects | Catalysis Catalysts Chemistry Cobalt Dehydration Dehydration of xylose Exact sciences and technology General and physical chemistry Metal oxides Sulfated metal oxides Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tin dioxide Tin oxide Tin oxides Xylose |
| title | Dehydration of xylose over sulfated tin oxide catalyst: Influences of the preparation conditions on the structural properties and catalytic performance |
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