Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior

The polymerization of acrylonitrile mediated by various trithiocarbonates as reversible addition-fragmentation chain-transfer agents is studied. It is shown that, when polymerization is performed in DMSO, a narrowly dispersed PAN with a controlled molecular mass can be prepared. The pseudoliving rad...

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Veröffentlicht in:	Polymer science. Series B 2011-08, Vol.53 (7-8), p.391-403
Hauptverfasser:	Chernikova, E. V., Poteryaeva, Z. A., Belyaev, S. S., Nifant’ev, I. E., Shlyakhtin, A. V., Kostina, Yu. V., Cherevan’, A. S., Efimov, M. N., Bondarenko, G. N., Sivtsov, E. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Addition polymerization Chains (polymeric) Chemistry Chemistry and Materials Science Infrared radiation Molecular structure Polymer Sciences Polymerization Radicals Reagents Synthesis
Online-Zugang:	Volltext
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