Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates
An account of the synthesis, spectroscopic, thermal and structural behavior of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates is presented. The reaction of antimony(III) bis(pyrrolidinedithiocarbamate) chloride with potassium organodithiocarbonate in equimolar ratio yielded the c...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2011-09, Vol.105 (3), p.937-946 |
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| creator | Chauhan, H. P. S. Bakshi, Abhilasha |
| description | An account of the synthesis, spectroscopic, thermal and structural behavior of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates is presented. The reaction of antimony(III) bis(pyrrolidinedithiocarbamate) chloride with potassium organodithiocarbonate in equimolar ratio yielded the corresponding mixed derivatives of the type [(CH
2
)
4
NCS
2
]
2
SbS
2
COR [where R = Me, Et, Pr
n
, Pr
i
, Bu
n
, and Bu
i
]. These newly synthesized complexes have been characterized by physicochemical [molecular weight determination, melting points, and elemental analysis], spectral [UV, IR, far-IR, NMR (
1
H and
13
C)], thermal [TG, DTA, and FAB
+
mass], and structural [powder XRD and SEM] studies. Analytical studies leads to purity and structural properties of the synthesized complexes on the other hand powder X-ray diffraction and SEM studies show that multiphase, polycrystalline, and rod-shaped complexes have been formed having nanorange crystallite size and monoclinic crystal system. |
| doi_str_mv | 10.1007/s10973-010-1234-6 |
| format | Article |
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2
)
4
NCS
2
]
2
SbS
2
COR [where R = Me, Et, Pr
n
, Pr
i
, Bu
n
, and Bu
i
]. These newly synthesized complexes have been characterized by physicochemical [molecular weight determination, melting points, and elemental analysis], spectral [UV, IR, far-IR, NMR (
1
H and
13
C)], thermal [TG, DTA, and FAB
+
mass], and structural [powder XRD and SEM] studies. Analytical studies leads to purity and structural properties of the synthesized complexes on the other hand powder X-ray diffraction and SEM studies show that multiphase, polycrystalline, and rod-shaped complexes have been formed having nanorange crystallite size and monoclinic crystal system.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-010-1234-6</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Calorimetry ; Chemistry ; Chemistry and Materials Science ; Chlorides ; Coordination compounds ; Crystallites ; Derivatives ; Exact sciences and technology ; Inorganic Chemistry ; Inorganic chemistry and origins of life ; Measurement Science and Instrumentation ; Nanomaterials ; Nanostructure ; Physical Chemistry ; Polymer Sciences ; Preparations and properties ; Scanning electron microscopy ; Spectroscopy</subject><ispartof>Journal of thermal analysis and calorimetry, 2011-09, Vol.105 (3), p.937-946</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2010</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-e2e8db01b6d1335ecfac29b87b131bb9360d6eef51a5c0ef17ae3564d1fa24ed3</citedby><cites>FETCH-LOGICAL-c383t-e2e8db01b6d1335ecfac29b87b131bb9360d6eef51a5c0ef17ae3564d1fa24ed3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-010-1234-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-010-1234-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24462283$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chauhan, H. P. S.</creatorcontrib><creatorcontrib>Bakshi, Abhilasha</creatorcontrib><title>Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>An account of the synthesis, spectroscopic, thermal and structural behavior of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates is presented. The reaction of antimony(III) bis(pyrrolidinedithiocarbamate) chloride with potassium organodithiocarbonate in equimolar ratio yielded the corresponding mixed derivatives of the type [(CH
2
)
4
NCS
2
]
2
SbS
2
COR [where R = Me, Et, Pr
n
, Pr
i
, Bu
n
, and Bu
i
]. These newly synthesized complexes have been characterized by physicochemical [molecular weight determination, melting points, and elemental analysis], spectral [UV, IR, far-IR, NMR (
1
H and
13
C)], thermal [TG, DTA, and FAB
+
mass], and structural [powder XRD and SEM] studies. Analytical studies leads to purity and structural properties of the synthesized complexes on the other hand powder X-ray diffraction and SEM studies show that multiphase, polycrystalline, and rod-shaped complexes have been formed having nanorange crystallite size and monoclinic crystal system.</description><subject>Analytical Chemistry</subject><subject>Calorimetry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Coordination compounds</subject><subject>Crystallites</subject><subject>Derivatives</subject><subject>Exact sciences and technology</subject><subject>Inorganic Chemistry</subject><subject>Inorganic chemistry and origins of life</subject><subject>Measurement Science and Instrumentation</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Preparations and properties</subject><subject>Scanning electron microscopy</subject><subject>Spectroscopy</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u1TAQhSMEElXpA7DLBnErNeCxE8dZoqrAlSqxANaWfybU4NjBdhZZ8er46law62rOzHxzFnOa5jWQd0DI-D4DmUbWESAdUNZ3_FlzAYMQHZ0of141q5rDQF42Vzk7TSgQPg1iumj-fN1DecDizE2bVzQlxWziemrrOC3K37Qq2DaXtJmyJeWr3KzD3Ma5bopbYtgPx-PxutUuH9Y9peiddQGtKw8uGpW0WlSJ18r_2v3_YQyqYH7VvJiVz3j1WC-b7x_vvt1-7u6_fDrefrjvDBOsdEhRWE1AcwuMDWhmZeikxaiBgdYT48RyxHkANRiCM4wK2cB7C7OiPVp22bw9-64p_t4wF7m4bNB7FTBuWU6cib4fe1HJw5MkjJwC5ZSdUDijpn4tJ5zlmtyi0i6ByFMy8pyMJKe-JiN5vXnzaK-yUX5OKhiX_x3SvueUClY5euZyXYUfmOTPuKVQf_SE-V8w-KGG</recordid><startdate>20110901</startdate><enddate>20110901</enddate><creator>Chauhan, H. P. S.</creator><creator>Bakshi, Abhilasha</creator><general>Springer Netherlands</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110901</creationdate><title>Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates</title><author>Chauhan, H. P. S. ; Bakshi, Abhilasha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-e2e8db01b6d1335ecfac29b87b131bb9360d6eef51a5c0ef17ae3564d1fa24ed3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Analytical Chemistry</topic><topic>Calorimetry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Coordination compounds</topic><topic>Crystallites</topic><topic>Derivatives</topic><topic>Exact sciences and technology</topic><topic>Inorganic Chemistry</topic><topic>Inorganic chemistry and origins of life</topic><topic>Measurement Science and Instrumentation</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Preparations and properties</topic><topic>Scanning electron microscopy</topic><topic>Spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chauhan, H. P. S.</creatorcontrib><creatorcontrib>Bakshi, Abhilasha</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chauhan, H. P. S.</au><au>Bakshi, Abhilasha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2011-09-01</date><risdate>2011</risdate><volume>105</volume><issue>3</issue><spage>937</spage><epage>946</epage><pages>937-946</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>An account of the synthesis, spectroscopic, thermal and structural behavior of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates is presented. The reaction of antimony(III) bis(pyrrolidinedithiocarbamate) chloride with potassium organodithiocarbonate in equimolar ratio yielded the corresponding mixed derivatives of the type [(CH
2
)
4
NCS
2
]
2
SbS
2
COR [where R = Me, Et, Pr
n
, Pr
i
, Bu
n
, and Bu
i
]. These newly synthesized complexes have been characterized by physicochemical [molecular weight determination, melting points, and elemental analysis], spectral [UV, IR, far-IR, NMR (
1
H and
13
C)], thermal [TG, DTA, and FAB
+
mass], and structural [powder XRD and SEM] studies. Analytical studies leads to purity and structural properties of the synthesized complexes on the other hand powder X-ray diffraction and SEM studies show that multiphase, polycrystalline, and rod-shaped complexes have been formed having nanorange crystallite size and monoclinic crystal system.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-010-1234-6</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of thermal analysis and calorimetry, 2011-09, Vol.105 (3), p.937-946 |
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| subjects | Analytical Chemistry Calorimetry Chemistry Chemistry and Materials Science Chlorides Coordination compounds Crystallites Derivatives Exact sciences and technology Inorganic Chemistry Inorganic chemistry and origins of life Measurement Science and Instrumentation Nanomaterials Nanostructure Physical Chemistry Polymer Sciences Preparations and properties Scanning electron microscopy Spectroscopy |
| title | Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates |
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