Synthesis, Reactivity, and Computational Analysis of Halophosphines Supported by Dianionic Guanidinate Ligands

The reported chemistry and reactivity of guanidinate supported group 15 elements in the +3 oxidation state, particularly phosphorus, is limited when compared to their ubiquity in supporting metallic elements across the periodic table. We have synthesized a series of chlorophosphines utilizing homo-...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-03, Vol.134 (11), p.5398-5414
Hauptverfasser:	Brazeau, Allison L, Hänninen, Mikko M, Tuononen, Heikki M, Jones, Nathan D, Ragogna, Paul J
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Crystallography, X-Ray Guanidines - chemistry Ligands Models, Molecular Molecular Structure Phosphines - chemical synthesis Phosphines - chemistry Quantum Theory
Online-Zugang:	Volltext
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