Spectroscopic capture and reactivity of S = 1/2 nickel(III)-oxygen intermediates in the reaction of a Ni(II)-salt with mCPBA

Ni(III)-intermediates are trapped by EPR and UV/Vis spectroscopy in the reaction of a Ni(II) salt with mCPBA. On the basis of their oxo-transfer and hydrogen-atom abstraction abilities the intermediates are assigned as the elusive terminal Ni(III)-oxo/hydroxo species. The findings suggest that Ni(II...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-04, Vol.48 (31), p.3730-3732
Hauptverfasser:	Pfaff, Florian Felix, Heims, Florian, Kundu, Subrata, Mebs, Stefan, Ray, Kallol
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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