Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy)2](PF6) n (n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy)2]1

The molecular and electronic structures of the four members, [Cr(tpy)2](PF6) n (n = 3–0; complexes 1–4; tpy = 2,2′:6′,2″-terpyridine), of the electron transfer series [Cr(tpy)2] n+ have been determined experimentally by single-crystal X-ray crystallography, by their electro- and magnetochemistry, an...

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Veröffentlicht in:	Inorganic chemistry 2012-03, Vol.51 (6), p.3718-3732
Hauptverfasser:	Scarborough, Christopher C, Lancaster, Kyle M, DeBeer, Serena, Weyhermüller, Thomas, Sproules, Stephen, Wieghardt, Karl
Format:	Artikel
Sprache:	eng
Schlagworte:	Chromium - chemistry Crystallography, X-Ray Electron Spin Resonance Spectroscopy Models, Molecular Oxidation-Reduction Pyridines - chemistry
Online-Zugang:	Volltext
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