Allenes in Molecular Materials
This Minireview provides a critical account of the development of allene‐containing advanced functional materials, starting with the design and synthesis of stable and enantiopure building blocks. A variety of systems, including shape‐persistent macrocycles, foldamers, polymers, charge‐transfer chro...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-03, Vol.51 (12), p.2818-2828 |
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| container_end_page | 2828 |
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| container_issue | 12 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Rivera-Fuentes, Pablo Diederich, François |
| description | This Minireview provides a critical account of the development of allene‐containing advanced functional materials, starting with the design and synthesis of stable and enantiopure building blocks. A variety of systems, including shape‐persistent macrocycles, foldamers, polymers, charge‐transfer chromophores, dendrimers, liquid crystals, and redox‐switchable chiral chromophores are discussed from the viewpoint of their syntheses, properties, and potential applications. The goal of this Minireview is to inspire new uses of enantiopure allenes for the rational design of advanced materials.
Property development: A critical account of the development of allene‐based molecular materials is presented in this Minireview. Shape‐persistent macrocycles, foldamers, polymers, and other allene‐containing functional materials are discussed, with a focus on their synthesis and chiroptical properties. |
| doi_str_mv | 10.1002/anie.201108001 |
| format | Article |
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| ispartof | Angewandte Chemie International Edition, 2012-03, Vol.51 (12), p.2818-2828 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | allenes chirality helical structures macrocycles molecular materials R&D Research & development |
| title | Allenes in Molecular Materials |
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