Cucurbit[8]uril Mediated Donor–Acceptor Ternary Complexes: A Model System for Studying Charge-Transfer Interactions

A supramolecular self-assembly approach is described which allows for the convenient preparation of a wide range of charge-transfer (CT) donor–acceptor complexes in aqueous solutions. When one equiv of the macrocyclic host cucurbit[8]uril (CB[8]) is added to an aqueous donor and acceptor solution, a...

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Veröffentlicht in:	The journal of physical chemistry. B 2012-03, Vol.116 (9), p.2842-2849
Hauptverfasser:	Biedermann, Frank, Scherman, Oren A
Format:	Artikel
Sprache:	eng
Schlagworte:	Affinity Binding energy Calorimetry Electrostatics Formations Holes Mathematical models Self assembly
Online-Zugang:	Volltext
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