Use of the modified quick easy cheap effective rugged and safe sample preparation approach for the simultaneous analysis of type A- and B-trichothecenes in wheat flour
A suitable extraction and purification method for the simultaneous liquid chromatography–mass spectrometry (LC–MS) determination of five mycotoxins, three type A, diacetoxyscirpenol (DAS), T-2 toxin (T-2) and HT-2 toxin (HT-2), and two type B-trichothecenes, deoxynivalenol (DON) and nivalenol (NIV),...
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| Veröffentlicht in: | Journal of Chromatography A 2010-02, Vol.1217 (9), p.1437-1440 |
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| container_title | Journal of Chromatography A |
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| creator | Sospedra, I. Blesa, J. Soriano, J.M. Mañes, J. |
| description | A suitable extraction and purification method for the simultaneous liquid chromatography–mass spectrometry (LC–MS) determination of five mycotoxins, three type A, diacetoxyscirpenol (DAS), T-2 toxin (T-2) and HT-2 toxin (HT-2), and two type B-trichothecenes, deoxynivalenol (DON) and nivalenol (NIV), has been optimised using a modified “Quick Easy Cheap Effective Rugged and Safe” (QuEChERS) method. Different solvents were studied in the extraction procedure to obtain better recoveries, which ranged from 86 to 108%, using a 85/15 (v/v) mixture of methanol/acetonitrile. The values obtained for recovery, repeatability and reproducibility of the optimized method are in agreement with Commission Directive 2005/26/EC for methods of analysis of
Fusarium toxins. Finally, this optimized procedure was applied in wheat flour samples commercialized in Spain. |
| doi_str_mv | 10.1016/j.chroma.2009.12.047 |
| format | Article |
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Fusarium toxins. Finally, this optimized procedure was applied in wheat flour samples commercialized in Spain.</description><subject>Acetonitriles - chemistry</subject><subject>Analytic Sample Preparation Methods - economics</subject><subject>Biological and medical sciences</subject><subject>Cereal and baking product industries</subject><subject>Chromatography, Liquid</subject><subject>deoxynivalenol</subject><subject>diacetoxyscirpenol</subject><subject>extraction</subject><subject>Flour - analysis</subject><subject>food analysis</subject><subject>food contamination</subject><subject>Food industries</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>HT-2 toxin</subject><subject>LC–MS</subject><subject>liquid chromatography</subject><subject>Mass Spectrometry</subject><subject>Methanol - chemistry</subject><subject>nivalenol</subject><subject>QuEChERS</subject><subject>Solvents</subject><subject>T-2 toxin</subject><subject>Trichothecenes</subject><subject>Trichothecenes - analysis</subject><subject>Triticum - chemistry</subject><subject>Triticum aestivum</subject><subject>Wheat flour</subject><issn>0021-9673</issn><issn>1873-3778</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kc1u1DAUhSMEotPCGyDwBrFK8E9iJxuktqKAVIkFzNq6da4nHpI4tZOieSJeE3cywI6NvfnOuffck2WvGC0YZfL9vjBd8AMUnNKmYLygpXqSbVitRC6Uqp9mG0o5yxupxFl2HuOeUqao4s-zsySRtBJyk_3aRiTekrlDMvjWWYctuV-c-UEQ4oGYDmEiaC2a2T0gCctulwgYWxLBYnqGqUcyBZwgwOz8SGCaggfTEevD0Te6YelnGNEvMSmhP0QXj0MPE5LL_Oh2lc_Bmc4ngcERI3Ej-ZmGz8T2fgkvsmcW-ogvT_9Ftr35-P36c3779dOX68vb3FRMzHnJZKVKIziXd6WoGShGsaqaum1Uo7gsmTHc0EoyUSplDAMrqbCKCVrXFaC4yN6tvinD_YJx1oOLBvt-XV83XNYNbViVyHIlTfAxBrR6Cm6AcNCM6seG9F6vDenHhjTjOjWUZK9PA5a7Adu_oj-VJODtCYBooLcBRuPiP44r2ZSCJu7NylnwGnYhMdtvnKYkrKY8pUvEh5XAdLAHh0FH43A02LqQ6tStd__f9Tfo_Lr6</recordid><startdate>20100226</startdate><enddate>20100226</enddate><creator>Sospedra, I.</creator><creator>Blesa, J.</creator><creator>Soriano, J.M.</creator><creator>Mañes, J.</creator><general>Elsevier B.V</general><general>Amsterdam; New York: Elsevier</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7U7</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope><scope>M7N</scope></search><sort><creationdate>20100226</creationdate><title>Use of the modified quick easy cheap effective rugged and safe sample preparation approach for the simultaneous analysis of type A- and B-trichothecenes in wheat flour</title><author>Sospedra, I. ; Blesa, J. ; Soriano, J.M. ; Mañes, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c513t-416574c3226b4381a710e5598d97972641cc2c05613477cc1af603f7130885ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Acetonitriles - chemistry</topic><topic>Analytic Sample Preparation Methods - economics</topic><topic>Biological and medical sciences</topic><topic>Cereal and baking product industries</topic><topic>Chromatography, Liquid</topic><topic>deoxynivalenol</topic><topic>diacetoxyscirpenol</topic><topic>extraction</topic><topic>Flour - analysis</topic><topic>food analysis</topic><topic>food contamination</topic><topic>Food industries</topic><topic>Fundamental and applied biological sciences. 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Different solvents were studied in the extraction procedure to obtain better recoveries, which ranged from 86 to 108%, using a 85/15 (v/v) mixture of methanol/acetonitrile. The values obtained for recovery, repeatability and reproducibility of the optimized method are in agreement with Commission Directive 2005/26/EC for methods of analysis of
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| subjects | Acetonitriles - chemistry Analytic Sample Preparation Methods - economics Biological and medical sciences Cereal and baking product industries Chromatography, Liquid deoxynivalenol diacetoxyscirpenol extraction Flour - analysis food analysis food contamination Food industries Fundamental and applied biological sciences. Psychology HT-2 toxin LC–MS liquid chromatography Mass Spectrometry Methanol - chemistry nivalenol QuEChERS Solvents T-2 toxin Trichothecenes Trichothecenes - analysis Triticum - chemistry Triticum aestivum Wheat flour |
| title | Use of the modified quick easy cheap effective rugged and safe sample preparation approach for the simultaneous analysis of type A- and B-trichothecenes in wheat flour |
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