The Effect of Different Ethoxylations for Sorbitan Monolaurate on Enhancing Simultaneous Saccharification and Fermentation (SSF) of Wheat Straw to Ethanol
In this paper, four nonionic surfactants with different hydrophilic–lipophilic balance (HLB) based on sorbitan monolaurate were synthesized by introducing ethylene oxide gas ( n = 20, 40, 60, and 80 ethylene oxide units). The chemical structure of the prepared ethoxylated surfactants was confirmed...
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Veröffentlicht in: | Applied biochemistry and biotechnology 2012, Vol.166 (1), p.22-35 |
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creator | Badawi, A. M. Fahmy, A. A. Mohamed, Karima A. Noor El-Din, M. R. Riad, M. G. |
description | In this paper, four nonionic surfactants with different hydrophilic–lipophilic balance (HLB) based on sorbitan monolaurate were synthesized by introducing ethylene oxide gas (
n
= 20, 40, 60, and 80 ethylene oxide units). The chemical structure of the prepared ethoxylated surfactants was confirmed using Fourier transform-infrared and
1
H NMR spectroscopes. The surface tension and thermodynamic properties of the prepared surfactants have been studied. The simultaneous saccharification and fermentation (SSF) process for ethanol production from microwave/alkali pretreated wheat straw has been assayed using nonionic surfactants have different ethylene oxide units. Ethanol yield was 82% and 61% for
Kluyveromyces marxianus
and
Saccharomyces cerevisiae
, respectively, with the addition of 2.5 g/l of the prepared nonionic surfactant (HLB = 18.2). Results show that the production of ethanol from microwave/alkali pretreated wheat straw increased with increasing the (HLB) value of the nonionic surfactant. |
doi_str_mv | 10.1007/s12010-011-9400-2 |
format | Article |
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n
= 20, 40, 60, and 80 ethylene oxide units). The chemical structure of the prepared ethoxylated surfactants was confirmed using Fourier transform-infrared and
1
H NMR spectroscopes. The surface tension and thermodynamic properties of the prepared surfactants have been studied. The simultaneous saccharification and fermentation (SSF) process for ethanol production from microwave/alkali pretreated wheat straw has been assayed using nonionic surfactants have different ethylene oxide units. Ethanol yield was 82% and 61% for
Kluyveromyces marxianus
and
Saccharomyces cerevisiae
, respectively, with the addition of 2.5 g/l of the prepared nonionic surfactant (HLB = 18.2). Results show that the production of ethanol from microwave/alkali pretreated wheat straw increased with increasing the (HLB) value of the nonionic surfactant.</description><identifier>ISSN: 0273-2289</identifier><identifier>EISSN: 1559-0291</identifier><identifier>DOI: 10.1007/s12010-011-9400-2</identifier><identifier>PMID: 21984384</identifier><identifier>CODEN: ABIBDL</identifier><language>eng</language><publisher>New York: Humana Press Inc</publisher><subject>Biochemistry ; Biological and medical sciences ; Biotechnology ; Chemical engineering ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Ethanol ; Ethanol - chemistry ; Ethanol - metabolism ; Ethylene Oxide - chemistry ; Fermentation ; Fourier Analysis ; Fourier transforms ; Fundamental and applied biological sciences. Psychology ; Hexoses - chemistry ; Hexoses - metabolism ; Kluyveromyces - chemistry ; Kluyveromyces - metabolism ; Kluyveromyces marxianus ; Lignin - chemistry ; Magnetic Resonance Spectroscopy ; Methods. Procedures. Technologies ; Microbial engineering. Fermentation and microbial culture technology ; Nonionic surfactants ; Saccharomyces cerevisiae ; Saccharomyces cerevisiae - chemistry ; Saccharomyces cerevisiae - metabolism ; Surface tension ; Surface-Active Agents - chemistry ; Surface-Active Agents - metabolism ; Surfactants ; Triticum - chemistry ; Triticum aestivum ; Wheat straw ; Yeast</subject><ispartof>Applied biochemistry and biotechnology, 2012, Vol.166 (1), p.22-35</ispartof><rights>Springer Science+Business Media, LLC 2011</rights><rights>2015 INIST-CNRS</rights><rights>Springer Science+Business Media, LLC 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-ace7f35bde021824af35dd066a107888c352078f910efcef238b2ef8597ee17e3</citedby><cites>FETCH-LOGICAL-c432t-ace7f35bde021824af35dd066a107888c352078f910efcef238b2ef8597ee17e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12010-011-9400-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12010-011-9400-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,4024,27923,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25589152$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21984384$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Badawi, A. M.</creatorcontrib><creatorcontrib>Fahmy, A. A.</creatorcontrib><creatorcontrib>Mohamed, Karima A.</creatorcontrib><creatorcontrib>Noor El-Din, M. R.</creatorcontrib><creatorcontrib>Riad, M. G.</creatorcontrib><title>The Effect of Different Ethoxylations for Sorbitan Monolaurate on Enhancing Simultaneous Saccharification and Fermentation (SSF) of Wheat Straw to Ethanol</title><title>Applied biochemistry and biotechnology</title><addtitle>Appl Biochem Biotechnol</addtitle><addtitle>Appl Biochem Biotechnol</addtitle><description>In this paper, four nonionic surfactants with different hydrophilic–lipophilic balance (HLB) based on sorbitan monolaurate were synthesized by introducing ethylene oxide gas (
n
= 20, 40, 60, and 80 ethylene oxide units). The chemical structure of the prepared ethoxylated surfactants was confirmed using Fourier transform-infrared and
1
H NMR spectroscopes. The surface tension and thermodynamic properties of the prepared surfactants have been studied. The simultaneous saccharification and fermentation (SSF) process for ethanol production from microwave/alkali pretreated wheat straw has been assayed using nonionic surfactants have different ethylene oxide units. Ethanol yield was 82% and 61% for
Kluyveromyces marxianus
and
Saccharomyces cerevisiae
, respectively, with the addition of 2.5 g/l of the prepared nonionic surfactant (HLB = 18.2). Results show that the production of ethanol from microwave/alkali pretreated wheat straw increased with increasing the (HLB) value of the nonionic surfactant.</description><subject>Biochemistry</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Chemical engineering</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Ethanol</subject><subject>Ethanol - chemistry</subject><subject>Ethanol - metabolism</subject><subject>Ethylene Oxide - chemistry</subject><subject>Fermentation</subject><subject>Fourier Analysis</subject><subject>Fourier transforms</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Hexoses - chemistry</subject><subject>Hexoses - metabolism</subject><subject>Kluyveromyces - chemistry</subject><subject>Kluyveromyces - metabolism</subject><subject>Kluyveromyces marxianus</subject><subject>Lignin - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Methods. Procedures. Technologies</subject><subject>Microbial engineering. Fermentation and microbial culture technology</subject><subject>Nonionic surfactants</subject><subject>Saccharomyces cerevisiae</subject><subject>Saccharomyces cerevisiae - chemistry</subject><subject>Saccharomyces cerevisiae - metabolism</subject><subject>Surface tension</subject><subject>Surface-Active Agents - chemistry</subject><subject>Surface-Active Agents - metabolism</subject><subject>Surfactants</subject><subject>Triticum - chemistry</subject><subject>Triticum aestivum</subject><subject>Wheat straw</subject><subject>Yeast</subject><issn>0273-2289</issn><issn>1559-0291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkcFu1DAQhi0EokvhAbggCwkBh4DHiTf2EZVdQCrikCKOkdcZN6kSu9iOoK_C0-KQhUpIiJPH48__P6OfkMfAXgFj9esInAErGEChKsYKfodsQAhVMK7gLtkwXpcF51KdkAcxXjEGXIr6PjnhoGRVympDflz0SHfWoknUW_p2yGVAl-gu9f77zajT4F2k1gfa-HAYknb0o3d-1HPQCal3dOd67czgLmkzTPOYCfRzpI02ptdhsIP5JUK16-gew5TV18aLptm_XFy_9KgTbVLQ32jyi7XODg_JPavHiI-O5yn5vN9dnL0vzj-9-3D25rwwVclToQ3WthSHDhkHySudL13HtlsNrJZSmlLwXFgFDK1By0t54GilUDUi1Fiekuer7nXwX2eMqZ2GaHAc10VaxbdSlkzx_5NQbWtgUmTy6V_klZ-Dy2ssUJlTk5AhWCETfIwBbXsdhkmHmxZYuwTcrgG3OeB2CbhdRnhyFJ4PE3Z_fvxONAPPjoCORo82LNnEW04IqUAsQnzlYn5ylxhuJ_y3-0_Fk75M</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Badawi, A. M.</creator><creator>Fahmy, A. A.</creator><creator>Mohamed, Karima A.</creator><creator>Noor El-Din, M. R.</creator><creator>Riad, M. G.</creator><general>Humana Press Inc</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7T7</scope><scope>7TM</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>P64</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>RC3</scope><scope>SOI</scope><scope>7X8</scope><scope>7QO</scope></search><sort><creationdate>2012</creationdate><title>The Effect of Different Ethoxylations for Sorbitan Monolaurate on Enhancing Simultaneous Saccharification and Fermentation (SSF) of Wheat Straw to Ethanol</title><author>Badawi, A. M. ; Fahmy, A. A. ; Mohamed, Karima A. ; Noor El-Din, M. R. ; Riad, M. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-ace7f35bde021824af35dd066a107888c352078f910efcef238b2ef8597ee17e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Biochemistry</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>Chemical engineering</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Ethanol</topic><topic>Ethanol - chemistry</topic><topic>Ethanol - metabolism</topic><topic>Ethylene Oxide - chemistry</topic><topic>Fermentation</topic><topic>Fourier Analysis</topic><topic>Fourier transforms</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Hexoses - chemistry</topic><topic>Hexoses - metabolism</topic><topic>Kluyveromyces - chemistry</topic><topic>Kluyveromyces - metabolism</topic><topic>Kluyveromyces marxianus</topic><topic>Lignin - chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Methods. Procedures. Technologies</topic><topic>Microbial engineering. Fermentation and microbial culture technology</topic><topic>Nonionic surfactants</topic><topic>Saccharomyces cerevisiae</topic><topic>Saccharomyces cerevisiae - chemistry</topic><topic>Saccharomyces cerevisiae - metabolism</topic><topic>Surface tension</topic><topic>Surface-Active Agents - chemistry</topic><topic>Surface-Active Agents - metabolism</topic><topic>Surfactants</topic><topic>Triticum - chemistry</topic><topic>Triticum aestivum</topic><topic>Wheat straw</topic><topic>Yeast</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Badawi, A. 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M.</au><au>Fahmy, A. A.</au><au>Mohamed, Karima A.</au><au>Noor El-Din, M. R.</au><au>Riad, M. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Effect of Different Ethoxylations for Sorbitan Monolaurate on Enhancing Simultaneous Saccharification and Fermentation (SSF) of Wheat Straw to Ethanol</atitle><jtitle>Applied biochemistry and biotechnology</jtitle><stitle>Appl Biochem Biotechnol</stitle><addtitle>Appl Biochem Biotechnol</addtitle><date>2012</date><risdate>2012</risdate><volume>166</volume><issue>1</issue><spage>22</spage><epage>35</epage><pages>22-35</pages><issn>0273-2289</issn><eissn>1559-0291</eissn><coden>ABIBDL</coden><abstract>In this paper, four nonionic surfactants with different hydrophilic–lipophilic balance (HLB) based on sorbitan monolaurate were synthesized by introducing ethylene oxide gas (
n
= 20, 40, 60, and 80 ethylene oxide units). The chemical structure of the prepared ethoxylated surfactants was confirmed using Fourier transform-infrared and
1
H NMR spectroscopes. The surface tension and thermodynamic properties of the prepared surfactants have been studied. The simultaneous saccharification and fermentation (SSF) process for ethanol production from microwave/alkali pretreated wheat straw has been assayed using nonionic surfactants have different ethylene oxide units. Ethanol yield was 82% and 61% for
Kluyveromyces marxianus
and
Saccharomyces cerevisiae
, respectively, with the addition of 2.5 g/l of the prepared nonionic surfactant (HLB = 18.2). Results show that the production of ethanol from microwave/alkali pretreated wheat straw increased with increasing the (HLB) value of the nonionic surfactant.</abstract><cop>New York</cop><pub>Humana Press Inc</pub><pmid>21984384</pmid><doi>10.1007/s12010-011-9400-2</doi><tpages>14</tpages></addata></record> |
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subjects | Biochemistry Biological and medical sciences Biotechnology Chemical engineering Chemical synthesis Chemistry Chemistry and Materials Science Ethanol Ethanol - chemistry Ethanol - metabolism Ethylene Oxide - chemistry Fermentation Fourier Analysis Fourier transforms Fundamental and applied biological sciences. Psychology Hexoses - chemistry Hexoses - metabolism Kluyveromyces - chemistry Kluyveromyces - metabolism Kluyveromyces marxianus Lignin - chemistry Magnetic Resonance Spectroscopy Methods. Procedures. Technologies Microbial engineering. Fermentation and microbial culture technology Nonionic surfactants Saccharomyces cerevisiae Saccharomyces cerevisiae - chemistry Saccharomyces cerevisiae - metabolism Surface tension Surface-Active Agents - chemistry Surface-Active Agents - metabolism Surfactants Triticum - chemistry Triticum aestivum Wheat straw Yeast |
title | The Effect of Different Ethoxylations for Sorbitan Monolaurate on Enhancing Simultaneous Saccharification and Fermentation (SSF) of Wheat Straw to Ethanol |
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