A study of M-X-BR3 (M = Pt, Pd or Rh; X = Cl or I) interactions in square planar ambiphilic ligand complexes: structural, spectroscopic, electrochemical and computational comparisons with borane-free analogues

Reaction of [PtCl(2)(COD)] and [PtI(2)(COD)] with 2,7-di-tert-butyl-5-diphenylboryl-4-diphenylphosphino-9,9-dimethylthioxanthene (TXPB) afforded square planar [PtCl(2)(TXPB)] (1B) and [PtI(2)(TXPB)] (4B), both of which were crystallographically characterized. Single-crystal X-ray quality crystals we...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2012-03, Vol.41 (12), p.3523-3535
Hauptverfasser:	Emslie, David J H, Cowie, Bradley E, Oakley, Simon R, Huk, Natalie L, Jenkins, Hilary A, Harrington, Laura E, Britten, James F
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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