Dual Emission from Rhenium(I) Complexes Induced by an Interligand Aromatic Interaction

A series of rhenium(I) diimine complexes cis,trans‐[Re(dmb)(CO)2(PR1R2R3)(PR4R5R6)]+ (dmb=4,4′‐dimethyl‐2,2′‐bipyridine, Rn=phenyl or alkyl), each of which bears two phosphine ligands with various numbers of phenyl groups, has been synthesized by using the photochemical ligand‐substitution reaction....

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Veröffentlicht in:	Chemistry : a European journal 2012-03, Vol.18 (11), p.3292-3304
Hauptverfasser:	Morimoto, Tatsuki, Ito, Megumi, Koike, Kazuhide, Kojima, Tatsuhiro, Ozeki, Tomoji, Ishitani, Osamu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Crystal structure dual emission Emission Excitation Ligands noncovalent interactions Phenyls Phosphines Photochemical photophysics rhenium Rotational X-ray diffraction
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