Phases and morphotropic regions in the PbNb2/3 Mg1/3O3-PbTiO3 system
Ceramic samples of solid solutions (1 − x ) PbNb 2/3 Mg 1/3 O 3 · x PbTiO 3 (0 ≤ x ≤ 1.0, Δ x = 0.0025–0.05) are prepared by the columbite method. A detailed x − T phase diagram of the system is constructed (isothermal join at 25°C), and dielectric, piezoelectric, and elastic properties are investig...
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| Veröffentlicht in: | Inorganic materials 2009, Vol.45 (1), p.65-79 |
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| creator | Reznichenko, L. A. Shilkina, L. A. Razumovskaya, O. N. Yaroslavtseva, E. A. Dudkina, S. I. Verbenko, I. A. Demchenko, O. A. Andryushina, I. N. Yurasov, Yu. I. Esis, A. A. |
| description | Ceramic samples of solid solutions (1 −
x
) PbNb
2/3
Mg
1/3
O
3
·
x
PbTiO
3
(0 ≤
x
≤ 1.0, Δ
x
= 0.0025–0.05) are prepared by the columbite method. A detailed
x
−
T
phase diagram of the system is constructed (isothermal join at 25°C), and dielectric, piezoelectric, and elastic properties are investigated. It is established that the region of the morphotropic phase transition is positioned in the range 0.28 <
x
≤ 0.43 and consists of a series of narrower regions. Inside one phase (cubic, rhombohedral, tetragonal), regions are found in which a qualitative and quantitative difference in structural and electrical parameters is observed. An interpretation of the observed effects in the context of the defect structure of the objects is suggested. |
| doi_str_mv | 10.1134/S0020168509010117 |
| format | Article |
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x
) PbNb
2/3
Mg
1/3
O
3
·
x
PbTiO
3
(0 ≤
x
≤ 1.0, Δ
x
= 0.0025–0.05) are prepared by the columbite method. A detailed
x
−
T
phase diagram of the system is constructed (isothermal join at 25°C), and dielectric, piezoelectric, and elastic properties are investigated. It is established that the region of the morphotropic phase transition is positioned in the range 0.28 <
x
≤ 0.43 and consists of a series of narrower regions. Inside one phase (cubic, rhombohedral, tetragonal), regions are found in which a qualitative and quantitative difference in structural and electrical parameters is observed. An interpretation of the observed effects in the context of the defect structure of the objects is suggested.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S0020168509010117</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Ceramics ; Chemistry ; Chemistry and Materials Science ; Construction ; Dielectric properties ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science ; Phase diagrams ; Phase transformations ; Phases ; Piezoelectricity ; Solid solutions</subject><ispartof>Inorganic materials, 2009, Vol.45 (1), p.65-79</ispartof><rights>MAIK Nauka 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-39b8fa57efab72eb922e817e48216b438af35129178705aba1c514fce9a5b45e3</citedby><cites>FETCH-LOGICAL-c281t-39b8fa57efab72eb922e817e48216b438af35129178705aba1c514fce9a5b45e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0020168509010117$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0020168509010117$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Reznichenko, L. A.</creatorcontrib><creatorcontrib>Shilkina, L. A.</creatorcontrib><creatorcontrib>Razumovskaya, O. N.</creatorcontrib><creatorcontrib>Yaroslavtseva, E. A.</creatorcontrib><creatorcontrib>Dudkina, S. I.</creatorcontrib><creatorcontrib>Verbenko, I. A.</creatorcontrib><creatorcontrib>Demchenko, O. A.</creatorcontrib><creatorcontrib>Andryushina, I. N.</creatorcontrib><creatorcontrib>Yurasov, Yu. I.</creatorcontrib><creatorcontrib>Esis, A. A.</creatorcontrib><title>Phases and morphotropic regions in the PbNb2/3 Mg1/3O3-PbTiO3 system</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>Ceramic samples of solid solutions (1 −
x
) PbNb
2/3
Mg
1/3
O
3
·
x
PbTiO
3
(0 ≤
x
≤ 1.0, Δ
x
= 0.0025–0.05) are prepared by the columbite method. A detailed
x
−
T
phase diagram of the system is constructed (isothermal join at 25°C), and dielectric, piezoelectric, and elastic properties are investigated. It is established that the region of the morphotropic phase transition is positioned in the range 0.28 <
x
≤ 0.43 and consists of a series of narrower regions. Inside one phase (cubic, rhombohedral, tetragonal), regions are found in which a qualitative and quantitative difference in structural and electrical parameters is observed. An interpretation of the observed effects in the context of the defect structure of the objects is suggested.</description><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Construction</subject><subject>Dielectric properties</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Phase diagrams</subject><subject>Phase transformations</subject><subject>Phases</subject><subject>Piezoelectricity</subject><subject>Solid solutions</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRS0EEuXxAey8glWox4_YXqLylAqtRFlHdpi0qZo42Omif0-qskPqahb3nBnNJeQG2D2AkONPxjiD3ChmGTAAfUJGkDOTCdD8lIz2cbbPz8lFSmvGmFTGjsjjfOUSJurab9qE2K1CH0NXlzTisg5tonVL-xXSuf_wfCzo-xLGYiayuV_UM0HTLvXYXJGzym0SXv_NS_L1_LSYvGbT2cvb5GGaldxAnwnrTeWUxsp5zdFbztGARmk45F4K4yqhgFvQRjPlvINSgaxKtE55qVBckrvD3i6Gny2mvmjqVOJm41oM21RYngsBjMuBvD1KCqVUPlwdQDiAZQwpRayKLtaNi7sCWLFvtvjX7ODwg5MGtl1iLNZhG9vh8yPSL8Ldd0A</recordid><startdate>2009</startdate><enddate>2009</enddate><creator>Reznichenko, L. A.</creator><creator>Shilkina, L. A.</creator><creator>Razumovskaya, O. N.</creator><creator>Yaroslavtseva, E. A.</creator><creator>Dudkina, S. I.</creator><creator>Verbenko, I. A.</creator><creator>Demchenko, O. A.</creator><creator>Andryushina, I. N.</creator><creator>Yurasov, Yu. I.</creator><creator>Esis, A. A.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7QQ</scope></search><sort><creationdate>2009</creationdate><title>Phases and morphotropic regions in the PbNb2/3 Mg1/3O3-PbTiO3 system</title><author>Reznichenko, L. A. ; Shilkina, L. A. ; Razumovskaya, O. N. ; Yaroslavtseva, E. A. ; Dudkina, S. I. ; Verbenko, I. A. ; Demchenko, O. A. ; Andryushina, I. N. ; Yurasov, Yu. I. ; Esis, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-39b8fa57efab72eb922e817e48216b438af35129178705aba1c514fce9a5b45e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Construction</topic><topic>Dielectric properties</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Phase diagrams</topic><topic>Phase transformations</topic><topic>Phases</topic><topic>Piezoelectricity</topic><topic>Solid solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reznichenko, L. A.</creatorcontrib><creatorcontrib>Shilkina, L. A.</creatorcontrib><creatorcontrib>Razumovskaya, O. N.</creatorcontrib><creatorcontrib>Yaroslavtseva, E. A.</creatorcontrib><creatorcontrib>Dudkina, S. I.</creatorcontrib><creatorcontrib>Verbenko, I. A.</creatorcontrib><creatorcontrib>Demchenko, O. A.</creatorcontrib><creatorcontrib>Andryushina, I. N.</creatorcontrib><creatorcontrib>Yurasov, Yu. I.</creatorcontrib><creatorcontrib>Esis, A. A.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Ceramic Abstracts</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reznichenko, L. A.</au><au>Shilkina, L. A.</au><au>Razumovskaya, O. N.</au><au>Yaroslavtseva, E. A.</au><au>Dudkina, S. I.</au><au>Verbenko, I. A.</au><au>Demchenko, O. A.</au><au>Andryushina, I. N.</au><au>Yurasov, Yu. I.</au><au>Esis, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phases and morphotropic regions in the PbNb2/3 Mg1/3O3-PbTiO3 system</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2009</date><risdate>2009</risdate><volume>45</volume><issue>1</issue><spage>65</spage><epage>79</epage><pages>65-79</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>Ceramic samples of solid solutions (1 −
x
) PbNb
2/3
Mg
1/3
O
3
·
x
PbTiO
3
(0 ≤
x
≤ 1.0, Δ
x
= 0.0025–0.05) are prepared by the columbite method. A detailed
x
−
T
phase diagram of the system is constructed (isothermal join at 25°C), and dielectric, piezoelectric, and elastic properties are investigated. It is established that the region of the morphotropic phase transition is positioned in the range 0.28 <
x
≤ 0.43 and consists of a series of narrower regions. Inside one phase (cubic, rhombohedral, tetragonal), regions are found in which a qualitative and quantitative difference in structural and electrical parameters is observed. An interpretation of the observed effects in the context of the defect structure of the objects is suggested.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0020168509010117</doi><tpages>15</tpages></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Ceramics Chemistry Chemistry and Materials Science Construction Dielectric properties Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Phase diagrams Phase transformations Phases Piezoelectricity Solid solutions |
| title | Phases and morphotropic regions in the PbNb2/3 Mg1/3O3-PbTiO3 system |
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