Enhanced sinterability of BaZr sub(0.1Ce) sub(0).7Y sub(0.1Yb) sub(0).1O sub(3-[delta] by addition of nickel oxide)

The effect of nickel oxide addition on the sintering behavior and electrical properties of BaZr sub(0.1Ce) sub(0).7Y sub(0.1Yb) sub(0).1O sub(3-[delta] (BZCYYb) as an electrolyte for solid oxide fuel cells was systematically studied. Results suggest that the addition of a small amount ([approx]1 wt%...

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Veröffentlicht in:Journal of power sources 2011-12, Vol.196 (23), p.9980-9984
Hauptverfasser: Liu, Yong, Yang, Lei, Liu, Mingfei, Tang, Zhiyuan, Liu, Meilin
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container_end_page 9984
container_issue 23
container_start_page 9980
container_title Journal of power sources
container_volume 196
creator Liu, Yong
Yang, Lei
Liu, Mingfei
Tang, Zhiyuan
Liu, Meilin
description The effect of nickel oxide addition on the sintering behavior and electrical properties of BaZr sub(0.1Ce) sub(0).7Y sub(0.1Yb) sub(0).1O sub(3-[delta] (BZCYYb) as an electrolyte for solid oxide fuel cells was systematically studied. Results suggest that the addition of a small amount ([approx]1 wt%) of NiO to BZCYYb greatly promoted densification, achieving [approx]96% of the theoretical density after sintering at 1350 degree C in air for 3 h (reducing the sintering temperature by [approx]200 degree C). Further, a sample sintered at 1450 degree C for 3 h showed high open circuit voltages (OCVs) when used as the electrolyte membrane to separate the two electrodes under typical SOFC operating conditions, indicating that the electrical conductivity of the electrical conductivity of the BZCYYb was not adversely affected by the addition of [approx]1 wt% NiO.)
doi_str_mv 10.1016/j.jpowsour.2011.08.047
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Results suggest that the addition of a small amount ([approx]1 wt%) of NiO to BZCYYb greatly promoted densification, achieving [approx]96% of the theoretical density after sintering at 1350 degree C in air for 3 h (reducing the sintering temperature by [approx]200 degree C). 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subjects Electrical conductivity
Electrical resistivity
Electrodes
Electrolytes
Nickel oxides
Resistivity
Sintering
Solid oxide fuel cells
title Enhanced sinterability of BaZr sub(0.1Ce) sub(0).7Y sub(0.1Yb) sub(0).1O sub(3-[delta] by addition of nickel oxide)
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