The effect of hydrogen sulphide on ammonium bisulphite when used as an oxygen scavenger in aqueous solutions
► 100 ppm ABS or less does not fully scavenge dissolved oxygen in NaCl solutions. ► At low pH, the sulphide level increased with increasing ABS concentration. ► There were more sulphides in deionised water with ABS compared to NaCl solutions. ► Material qualification test programs of well production...
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| Veröffentlicht in: | Corrosion science 2011-12, Vol.53 (12), p.4014-4025 |
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| container_title | Corrosion science |
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| creator | Lasebikan, B.A. Akisanya, A.R. Deans, W.F. Macphee, D.E. |
| description | ► 100
ppm ABS or less does not fully scavenge dissolved oxygen in NaCl solutions. ► At low pH, the sulphide level increased with increasing ABS concentration. ► There were more sulphides in deionised water with ABS compared to NaCl solutions. ► Material qualification test programs of well production tubing should include ABS. ► Sulphite-free oxygen scavengers should be considered for use in oil and gas wells.
The effectiveness of ammonium bisulphite (ABS) as oxygen scavenger and the behaviour of H
2S in brine/ABS solutions are examined. Deionised water, 1
wt.% NaCl and 3.5
wt.% NaCl with different ABS concentrations are bubbled with H
2S gas, while the dissolved oxygen, sulphide,
E
H
and pH are measured. With the exception of natural seawater, ABS concentration much greater than 100
ppmw (parts per million by weight) is needed to completely scavenge dissolved oxygen in all the solutions considered. The reaction between ABS and H
2S leads to increase in sulphide. The implications of the results for environment assisted cracking of oil and gas production tubings are discussed. |
| doi_str_mv | 10.1016/j.corsci.2011.08.011 |
| format | Article |
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ppm ABS or less does not fully scavenge dissolved oxygen in NaCl solutions. ► At low pH, the sulphide level increased with increasing ABS concentration. ► There were more sulphides in deionised water with ABS compared to NaCl solutions. ► Material qualification test programs of well production tubing should include ABS. ► Sulphite-free oxygen scavengers should be considered for use in oil and gas wells.
The effectiveness of ammonium bisulphite (ABS) as oxygen scavenger and the behaviour of H
2S in brine/ABS solutions are examined. Deionised water, 1
wt.% NaCl and 3.5
wt.% NaCl with different ABS concentrations are bubbled with H
2S gas, while the dissolved oxygen, sulphide,
E
H
and pH are measured. With the exception of natural seawater, ABS concentration much greater than 100
ppmw (parts per million by weight) is needed to completely scavenge dissolved oxygen in all the solutions considered. The reaction between ABS and H
2S leads to increase in sulphide. The implications of the results for environment assisted cracking of oil and gas production tubings are discussed.</description><identifier>ISSN: 0010-938X</identifier><identifier>EISSN: 1879-0496</identifier><identifier>DOI: 10.1016/j.corsci.2011.08.011</identifier><identifier>CODEN: CRRSAA</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>A. Acid solutions ; ABS ; ABS resins ; Applied sciences ; B. Electrochemical calculation ; C. Acid corrosion ; C. Pourbaix diagram ; C. Sulphidation ; C. Sulphide cracking ; Corrosion ; Corrosion environments ; Dissolution ; Exact sciences and technology ; Fracture mechanics ; Hydrogen sulfide ; Metals. Metallurgy ; Natural gas ; Scavengers ; Sulfides</subject><ispartof>Corrosion science, 2011-12, Vol.53 (12), p.4014-4025</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c451t-85c3340798f5efae5479edf2d26cc163f0031ffea17238ea9893fd7b6a64bc073</citedby><cites>FETCH-LOGICAL-c451t-85c3340798f5efae5479edf2d26cc163f0031ffea17238ea9893fd7b6a64bc073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.corsci.2011.08.011$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24624025$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lasebikan, B.A.</creatorcontrib><creatorcontrib>Akisanya, A.R.</creatorcontrib><creatorcontrib>Deans, W.F.</creatorcontrib><creatorcontrib>Macphee, D.E.</creatorcontrib><title>The effect of hydrogen sulphide on ammonium bisulphite when used as an oxygen scavenger in aqueous solutions</title><title>Corrosion science</title><description>► 100
ppm ABS or less does not fully scavenge dissolved oxygen in NaCl solutions. ► At low pH, the sulphide level increased with increasing ABS concentration. ► There were more sulphides in deionised water with ABS compared to NaCl solutions. ► Material qualification test programs of well production tubing should include ABS. ► Sulphite-free oxygen scavengers should be considered for use in oil and gas wells.
The effectiveness of ammonium bisulphite (ABS) as oxygen scavenger and the behaviour of H
2S in brine/ABS solutions are examined. Deionised water, 1
wt.% NaCl and 3.5
wt.% NaCl with different ABS concentrations are bubbled with H
2S gas, while the dissolved oxygen, sulphide,
E
H
and pH are measured. With the exception of natural seawater, ABS concentration much greater than 100
ppmw (parts per million by weight) is needed to completely scavenge dissolved oxygen in all the solutions considered. The reaction between ABS and H
2S leads to increase in sulphide. The implications of the results for environment assisted cracking of oil and gas production tubings are discussed.</description><subject>A. Acid solutions</subject><subject>ABS</subject><subject>ABS resins</subject><subject>Applied sciences</subject><subject>B. Electrochemical calculation</subject><subject>C. Acid corrosion</subject><subject>C. Pourbaix diagram</subject><subject>C. Sulphidation</subject><subject>C. Sulphide cracking</subject><subject>Corrosion</subject><subject>Corrosion environments</subject><subject>Dissolution</subject><subject>Exact sciences and technology</subject><subject>Fracture mechanics</subject><subject>Hydrogen sulfide</subject><subject>Metals. Metallurgy</subject><subject>Natural gas</subject><subject>Scavengers</subject><subject>Sulfides</subject><issn>0010-938X</issn><issn>1879-0496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kE9r3DAQxUVpoNtNvkEPupSe7I4sW5YvhRLypxDIZQu5Ca082tViS1vJTrvfPto65JjTg-H3Zt48Qr4wKBkw8f1QmhCTcWUFjJUgyywfyIrJtiug7sRHsgJgUHRcPn0in1M6AEBmYUWGzR4pWotmosHS_amPYYeepnk47l2PNHiqxzF4N49065bxhPTvPkNzwp7qRLWn4d_pv83oZ_Q7jNRl358Zw5xoCsM8ueDTJbmwekh49apr8vv2ZnN9Xzw83v26_vlQmLphUyEbw3kNbSdtg1ZjU7cd9rbqK2EME9wCcJYja9ZWXKLuZMdt326FFvXWQMvX5Nuy9xhDzpAmNbpkcBi0PwdSXSU4Y5KLTNYLaWJIKaJVx-hGHU-KgTp3qw5q6Vadu1UgVZZs-_p6QOePBxu1Ny69eataVDVUTeZ-LBzmb58dRpU3oTfYu5gbV31w7x96AUrvk2M</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Lasebikan, B.A.</creator><creator>Akisanya, A.R.</creator><creator>Deans, W.F.</creator><creator>Macphee, D.E.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20111201</creationdate><title>The effect of hydrogen sulphide on ammonium bisulphite when used as an oxygen scavenger in aqueous solutions</title><author>Lasebikan, B.A. ; Akisanya, A.R. ; Deans, W.F. ; Macphee, D.E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c451t-85c3340798f5efae5479edf2d26cc163f0031ffea17238ea9893fd7b6a64bc073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>A. Acid solutions</topic><topic>ABS</topic><topic>ABS resins</topic><topic>Applied sciences</topic><topic>B. Electrochemical calculation</topic><topic>C. Acid corrosion</topic><topic>C. Pourbaix diagram</topic><topic>C. Sulphidation</topic><topic>C. Sulphide cracking</topic><topic>Corrosion</topic><topic>Corrosion environments</topic><topic>Dissolution</topic><topic>Exact sciences and technology</topic><topic>Fracture mechanics</topic><topic>Hydrogen sulfide</topic><topic>Metals. Metallurgy</topic><topic>Natural gas</topic><topic>Scavengers</topic><topic>Sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lasebikan, B.A.</creatorcontrib><creatorcontrib>Akisanya, A.R.</creatorcontrib><creatorcontrib>Deans, W.F.</creatorcontrib><creatorcontrib>Macphee, D.E.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Corrosion science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lasebikan, B.A.</au><au>Akisanya, A.R.</au><au>Deans, W.F.</au><au>Macphee, D.E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of hydrogen sulphide on ammonium bisulphite when used as an oxygen scavenger in aqueous solutions</atitle><jtitle>Corrosion science</jtitle><date>2011-12-01</date><risdate>2011</risdate><volume>53</volume><issue>12</issue><spage>4014</spage><epage>4025</epage><pages>4014-4025</pages><issn>0010-938X</issn><eissn>1879-0496</eissn><coden>CRRSAA</coden><abstract>► 100
ppm ABS or less does not fully scavenge dissolved oxygen in NaCl solutions. ► At low pH, the sulphide level increased with increasing ABS concentration. ► There were more sulphides in deionised water with ABS compared to NaCl solutions. ► Material qualification test programs of well production tubing should include ABS. ► Sulphite-free oxygen scavengers should be considered for use in oil and gas wells.
The effectiveness of ammonium bisulphite (ABS) as oxygen scavenger and the behaviour of H
2S in brine/ABS solutions are examined. Deionised water, 1
wt.% NaCl and 3.5
wt.% NaCl with different ABS concentrations are bubbled with H
2S gas, while the dissolved oxygen, sulphide,
E
H
and pH are measured. With the exception of natural seawater, ABS concentration much greater than 100
ppmw (parts per million by weight) is needed to completely scavenge dissolved oxygen in all the solutions considered. The reaction between ABS and H
2S leads to increase in sulphide. The implications of the results for environment assisted cracking of oil and gas production tubings are discussed.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.corsci.2011.08.011</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0010-938X |
| ispartof | Corrosion science, 2011-12, Vol.53 (12), p.4014-4025 |
| issn | 0010-938X 1879-0496 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_926311836 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | A. Acid solutions ABS ABS resins Applied sciences B. Electrochemical calculation C. Acid corrosion C. Pourbaix diagram C. Sulphidation C. Sulphide cracking Corrosion Corrosion environments Dissolution Exact sciences and technology Fracture mechanics Hydrogen sulfide Metals. Metallurgy Natural gas Scavengers Sulfides |
| title | The effect of hydrogen sulphide on ammonium bisulphite when used as an oxygen scavenger in aqueous solutions |
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