Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)

► The crystal structure of Y[Fe(CN) 6]·4H 2O was investigated by DRXP and IR spectroscopy. ► The thermal decomposition produces the mixed oxide YFeO 3 with perovskite-type structure. ► The magnetic measurements reveal that Y[Fe(CN) 6]·4H 2O shows anti-ferromagnetic interactions at low temperatures....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of molecular structure 2011-09, Vol.1003 (1), p.129-133
Hauptverfasser: Gil, Diego M., Navarro, M.C., Lagarrigue, M.C., Guimpel, Julio, Carbonio, Raúl E., Gómez, M. Inés
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 133
container_issue 1
container_start_page 129
container_title Journal of molecular structure
container_volume 1003
creator Gil, Diego M.
Navarro, M.C.
Lagarrigue, M.C.
Guimpel, Julio
Carbonio, Raúl E.
Gómez, M. Inés
description ► The crystal structure of Y[Fe(CN) 6]·4H 2O was investigated by DRXP and IR spectroscopy. ► The thermal decomposition produces the mixed oxide YFeO 3 with perovskite-type structure. ► The magnetic measurements reveal that Y[Fe(CN) 6]·4H 2O shows anti-ferromagnetic interactions at low temperatures. Y[Fe(CN) 6]·4H 2O has been synthesized and characterized. The crystal structure was refined by Rietveld analysis using X-ray powder diffraction data. Y[Fe(CN) 6]·4H 2O crystallizes in the orthorhombic crystal system, space group Cmcm. Y 3+ ion is eight-coordinated forming a bicapped distorted trigonal prism YN 6O 2. Fe 3+ ion is six-coordinated in the form of an irregular octahedra FeC 6 group and cyanide linkages between YN 6O 2 and FeC 6 groups build an infinite polymeric array. The vibrational spectrum shows two bands corresponding to antisymmetric and symmetric stretching 12C 14N in the CN stretching region. These bands are accompanied by four weak isotopic bands at lower frequency due to the presence of 13C and 15N in relative natural abundance. The HOH bending band split into three bands around 1600 cm −1 due to the presence of two kinds of water molecules in the structure. The thermal decomposition has been followed by thermogravimetric and differential thermal analysis, IR spectroscopy and powder XRD. The size and morphology of the complex and its thermal decomposition products were evaluated by scanning electron microscopy. The magnetic measurements confirm that Y[Fe(CN) 6]·4H 2O shows an antiferromagnetic order at low temperatures.
doi_str_mv 10.1016/j.molstruc.2011.07.051
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_926308935</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022286011006211</els_id><sourcerecordid>1762121072</sourcerecordid><originalsourceid>FETCH-LOGICAL-c401t-b3328deaccb3176ef5378dca929e7814b06eb30c92bbac074c67fbd2cdd86a863</originalsourceid><addsrcrecordid>eNqFkd-L1DAQx4MouO75L2jePMHWSbKbpG8eiz8WDnw47zmk6fTM2jY1ScX-95dz9dWDgcDwmZnw_RDyikHNgMn3p3oMQ8pxcTUHxmpQNezZE7JhWvFKA9s9JRsAziuuJTwnL1I6ARQS2Ib8OMQ1ZTvQPwvyEpFG7P2EI075HU0zuhxDcmH2rjBLt1I7dXS0dxPm0ppjmDFmj4mGnq45R7-M9Dv-tm61U-gxRpuRXh6Px7cX5Flvh4Qv_75bcvvp47fDl-r66-fj4eq6cjtguWqF4LpD61wrmJLY74XSnbMNb1BptmtBYivANbxtrQO1c1L1bcdd12lptRRb8ua8t3zu54Ipm9Enh8NgJwxLMg2XAnQj9oW8_C9ZznPGGSheUHlGXYkjlYzMHP1o42oYmAcP5mT-eTAPHgwoUzyUwdfnwd4GY--iT-b2pgD74kA2otSWfDgTWEL55TGa5DxODjsfS_ymC_6xI_c5U6Du</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1762121072</pqid></control><display><type>article</type><title>Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)</title><source>Elsevier ScienceDirect Journals</source><creator>Gil, Diego M. ; Navarro, M.C. ; Lagarrigue, M.C. ; Guimpel, Julio ; Carbonio, Raúl E. ; Gómez, M. Inés</creator><creatorcontrib>Gil, Diego M. ; Navarro, M.C. ; Lagarrigue, M.C. ; Guimpel, Julio ; Carbonio, Raúl E. ; Gómez, M. Inés</creatorcontrib><description>► The crystal structure of Y[Fe(CN) 6]·4H 2O was investigated by DRXP and IR spectroscopy. ► The thermal decomposition produces the mixed oxide YFeO 3 with perovskite-type structure. ► The magnetic measurements reveal that Y[Fe(CN) 6]·4H 2O shows anti-ferromagnetic interactions at low temperatures. Y[Fe(CN) 6]·4H 2O has been synthesized and characterized. The crystal structure was refined by Rietveld analysis using X-ray powder diffraction data. Y[Fe(CN) 6]·4H 2O crystallizes in the orthorhombic crystal system, space group Cmcm. Y 3+ ion is eight-coordinated forming a bicapped distorted trigonal prism YN 6O 2. Fe 3+ ion is six-coordinated in the form of an irregular octahedra FeC 6 group and cyanide linkages between YN 6O 2 and FeC 6 groups build an infinite polymeric array. The vibrational spectrum shows two bands corresponding to antisymmetric and symmetric stretching 12C 14N in the CN stretching region. These bands are accompanied by four weak isotopic bands at lower frequency due to the presence of 13C and 15N in relative natural abundance. The HOH bending band split into three bands around 1600 cm −1 due to the presence of two kinds of water molecules in the structure. The thermal decomposition has been followed by thermogravimetric and differential thermal analysis, IR spectroscopy and powder XRD. The size and morphology of the complex and its thermal decomposition products were evaluated by scanning electron microscopy. The magnetic measurements confirm that Y[Fe(CN) 6]·4H 2O shows an antiferromagnetic order at low temperatures.</description><identifier>ISSN: 0022-2860</identifier><identifier>EISSN: 1872-8014</identifier><identifier>DOI: 10.1016/j.molstruc.2011.07.051</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Arrays ; Banded structure ; Bands ; Construction ; Crystal structure ; cyanides ; Hexacyanoferrate (III) ; Infrared spectroscopy ; iron ; magnetic properties ; Powder X-ray diffraction ; Rietveld analysis ; scanning electron microscopy ; Spectroscopy ; Stretching ; temperature ; Thermal analysis ; Thermal decomposition ; thermal degradation ; thermogravimetry ; X-radiation ; yttrium</subject><ispartof>Journal of molecular structure, 2011-09, Vol.1003 (1), p.129-133</ispartof><rights>2011 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c401t-b3328deaccb3176ef5378dca929e7814b06eb30c92bbac074c67fbd2cdd86a863</citedby><cites>FETCH-LOGICAL-c401t-b3328deaccb3176ef5378dca929e7814b06eb30c92bbac074c67fbd2cdd86a863</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022286011006211$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>Gil, Diego M.</creatorcontrib><creatorcontrib>Navarro, M.C.</creatorcontrib><creatorcontrib>Lagarrigue, M.C.</creatorcontrib><creatorcontrib>Guimpel, Julio</creatorcontrib><creatorcontrib>Carbonio, Raúl E.</creatorcontrib><creatorcontrib>Gómez, M. Inés</creatorcontrib><title>Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)</title><title>Journal of molecular structure</title><description>► The crystal structure of Y[Fe(CN) 6]·4H 2O was investigated by DRXP and IR spectroscopy. ► The thermal decomposition produces the mixed oxide YFeO 3 with perovskite-type structure. ► The magnetic measurements reveal that Y[Fe(CN) 6]·4H 2O shows anti-ferromagnetic interactions at low temperatures. Y[Fe(CN) 6]·4H 2O has been synthesized and characterized. The crystal structure was refined by Rietveld analysis using X-ray powder diffraction data. Y[Fe(CN) 6]·4H 2O crystallizes in the orthorhombic crystal system, space group Cmcm. Y 3+ ion is eight-coordinated forming a bicapped distorted trigonal prism YN 6O 2. Fe 3+ ion is six-coordinated in the form of an irregular octahedra FeC 6 group and cyanide linkages between YN 6O 2 and FeC 6 groups build an infinite polymeric array. The vibrational spectrum shows two bands corresponding to antisymmetric and symmetric stretching 12C 14N in the CN stretching region. These bands are accompanied by four weak isotopic bands at lower frequency due to the presence of 13C and 15N in relative natural abundance. The HOH bending band split into three bands around 1600 cm −1 due to the presence of two kinds of water molecules in the structure. The thermal decomposition has been followed by thermogravimetric and differential thermal analysis, IR spectroscopy and powder XRD. The size and morphology of the complex and its thermal decomposition products were evaluated by scanning electron microscopy. The magnetic measurements confirm that Y[Fe(CN) 6]·4H 2O shows an antiferromagnetic order at low temperatures.</description><subject>Arrays</subject><subject>Banded structure</subject><subject>Bands</subject><subject>Construction</subject><subject>Crystal structure</subject><subject>cyanides</subject><subject>Hexacyanoferrate (III)</subject><subject>Infrared spectroscopy</subject><subject>iron</subject><subject>magnetic properties</subject><subject>Powder X-ray diffraction</subject><subject>Rietveld analysis</subject><subject>scanning electron microscopy</subject><subject>Spectroscopy</subject><subject>Stretching</subject><subject>temperature</subject><subject>Thermal analysis</subject><subject>Thermal decomposition</subject><subject>thermal degradation</subject><subject>thermogravimetry</subject><subject>X-radiation</subject><subject>yttrium</subject><issn>0022-2860</issn><issn>1872-8014</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkd-L1DAQx4MouO75L2jePMHWSbKbpG8eiz8WDnw47zmk6fTM2jY1ScX-95dz9dWDgcDwmZnw_RDyikHNgMn3p3oMQ8pxcTUHxmpQNezZE7JhWvFKA9s9JRsAziuuJTwnL1I6ARQS2Ib8OMQ1ZTvQPwvyEpFG7P2EI075HU0zuhxDcmH2rjBLt1I7dXS0dxPm0ppjmDFmj4mGnq45R7-M9Dv-tm61U-gxRpuRXh6Px7cX5Flvh4Qv_75bcvvp47fDl-r66-fj4eq6cjtguWqF4LpD61wrmJLY74XSnbMNb1BptmtBYivANbxtrQO1c1L1bcdd12lptRRb8ua8t3zu54Ipm9Enh8NgJwxLMg2XAnQj9oW8_C9ZznPGGSheUHlGXYkjlYzMHP1o42oYmAcP5mT-eTAPHgwoUzyUwdfnwd4GY--iT-b2pgD74kA2otSWfDgTWEL55TGa5DxODjsfS_ymC_6xI_c5U6Du</recordid><startdate>20110928</startdate><enddate>20110928</enddate><creator>Gil, Diego M.</creator><creator>Navarro, M.C.</creator><creator>Lagarrigue, M.C.</creator><creator>Guimpel, Julio</creator><creator>Carbonio, Raúl E.</creator><creator>Gómez, M. Inés</creator><general>Elsevier B.V</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20110928</creationdate><title>Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)</title><author>Gil, Diego M. ; Navarro, M.C. ; Lagarrigue, M.C. ; Guimpel, Julio ; Carbonio, Raúl E. ; Gómez, M. Inés</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c401t-b3328deaccb3176ef5378dca929e7814b06eb30c92bbac074c67fbd2cdd86a863</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Arrays</topic><topic>Banded structure</topic><topic>Bands</topic><topic>Construction</topic><topic>Crystal structure</topic><topic>cyanides</topic><topic>Hexacyanoferrate (III)</topic><topic>Infrared spectroscopy</topic><topic>iron</topic><topic>magnetic properties</topic><topic>Powder X-ray diffraction</topic><topic>Rietveld analysis</topic><topic>scanning electron microscopy</topic><topic>Spectroscopy</topic><topic>Stretching</topic><topic>temperature</topic><topic>Thermal analysis</topic><topic>Thermal decomposition</topic><topic>thermal degradation</topic><topic>thermogravimetry</topic><topic>X-radiation</topic><topic>yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gil, Diego M.</creatorcontrib><creatorcontrib>Navarro, M.C.</creatorcontrib><creatorcontrib>Lagarrigue, M.C.</creatorcontrib><creatorcontrib>Guimpel, Julio</creatorcontrib><creatorcontrib>Carbonio, Raúl E.</creatorcontrib><creatorcontrib>Gómez, M. Inés</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of molecular structure</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gil, Diego M.</au><au>Navarro, M.C.</au><au>Lagarrigue, M.C.</au><au>Guimpel, Julio</au><au>Carbonio, Raúl E.</au><au>Gómez, M. Inés</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)</atitle><jtitle>Journal of molecular structure</jtitle><date>2011-09-28</date><risdate>2011</risdate><volume>1003</volume><issue>1</issue><spage>129</spage><epage>133</epage><pages>129-133</pages><issn>0022-2860</issn><eissn>1872-8014</eissn><abstract>► The crystal structure of Y[Fe(CN) 6]·4H 2O was investigated by DRXP and IR spectroscopy. ► The thermal decomposition produces the mixed oxide YFeO 3 with perovskite-type structure. ► The magnetic measurements reveal that Y[Fe(CN) 6]·4H 2O shows anti-ferromagnetic interactions at low temperatures. Y[Fe(CN) 6]·4H 2O has been synthesized and characterized. The crystal structure was refined by Rietveld analysis using X-ray powder diffraction data. Y[Fe(CN) 6]·4H 2O crystallizes in the orthorhombic crystal system, space group Cmcm. Y 3+ ion is eight-coordinated forming a bicapped distorted trigonal prism YN 6O 2. Fe 3+ ion is six-coordinated in the form of an irregular octahedra FeC 6 group and cyanide linkages between YN 6O 2 and FeC 6 groups build an infinite polymeric array. The vibrational spectrum shows two bands corresponding to antisymmetric and symmetric stretching 12C 14N in the CN stretching region. These bands are accompanied by four weak isotopic bands at lower frequency due to the presence of 13C and 15N in relative natural abundance. The HOH bending band split into three bands around 1600 cm −1 due to the presence of two kinds of water molecules in the structure. The thermal decomposition has been followed by thermogravimetric and differential thermal analysis, IR spectroscopy and powder XRD. The size and morphology of the complex and its thermal decomposition products were evaluated by scanning electron microscopy. The magnetic measurements confirm that Y[Fe(CN) 6]·4H 2O shows an antiferromagnetic order at low temperatures.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.molstruc.2011.07.051</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0022-2860
ispartof Journal of molecular structure, 2011-09, Vol.1003 (1), p.129-133
issn 0022-2860
1872-8014
language eng
recordid cdi_proquest_miscellaneous_926308935
source Elsevier ScienceDirect Journals
subjects Arrays
Banded structure
Bands
Construction
Crystal structure
cyanides
Hexacyanoferrate (III)
Infrared spectroscopy
iron
magnetic properties
Powder X-ray diffraction
Rietveld analysis
scanning electron microscopy
Spectroscopy
Stretching
temperature
Thermal analysis
Thermal decomposition
thermal degradation
thermogravimetry
X-radiation
yttrium
title Crystal structure refinement, spectroscopic study and magnetic properties of yttrium hexacyanoferrate (III)
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-21T21%3A10%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Crystal%20structure%20refinement,%20spectroscopic%20study%20and%20magnetic%20properties%20of%20yttrium%20hexacyanoferrate%20(III)&rft.jtitle=Journal%20of%20molecular%20structure&rft.au=Gil,%20Diego%20M.&rft.date=2011-09-28&rft.volume=1003&rft.issue=1&rft.spage=129&rft.epage=133&rft.pages=129-133&rft.issn=0022-2860&rft.eissn=1872-8014&rft_id=info:doi/10.1016/j.molstruc.2011.07.051&rft_dat=%3Cproquest_cross%3E1762121072%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1762121072&rft_id=info:pmid/&rft_els_id=S0022286011006211&rfr_iscdi=true