Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation
A new Aquivion™ E79-03S short-side chain perfluorosulfonic membrane with a thickness of 30 μm (dry form) and an equivalent weight (EW) of 790 g/equiv recently developed by Solvay-Solexis for high-temperature operation was tested in a pressurised (3 bar abs.) polymer electrolyte membrane (PEM) single...
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| Veröffentlicht in: | Journal of power sources 2011-11, Vol.196 (21), p.8925-8930 |
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| creator | Stassi, A. Gatto, I. Passalacqua, E. Antonucci, V. Arico, A.S. Merlo, L. Oldani, C. Pagano, E. |
| description | A new Aquivion™ E79-03S short-side chain perfluorosulfonic membrane with a thickness of 30
μm (dry form) and an equivalent weight (EW) of 790
g/equiv recently developed by Solvay-Solexis for high-temperature operation was tested in a pressurised (3
bar abs.) polymer electrolyte membrane (PEM) single cell at a temperature of 130
°C. For comparison, a standard Nafion™ membrane (EW 1100
g/equiv) of similar thickness (50
μm) was investigated under similar operating conditions. Both membranes were tested for high temperature operation in conjunction with an in-house prepared carbon supported Pt electrocatalyst. The electrocatalyst consisted of nanosized Pt particles (particle size ∼2
nm) dispersed on a high surface area carbon black. The electrochemical tests showed better performance for the Aquivion™ membrane as compared to Nafion™ with promising properties for high temperature PEM fuel cell applications. Beside the higher open circuit voltage and lower ohmic constraints, a higher electrocatalytic activity was observed at high temperature for the electrocatalyst-Aquivion™ ionomer interface indicating a better catalyst utilization. |
| doi_str_mv | 10.1016/j.jpowsour.2010.12.084 |
| format | Article |
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μm (dry form) and an equivalent weight (EW) of 790
g/equiv recently developed by Solvay-Solexis for high-temperature operation was tested in a pressurised (3
bar abs.) polymer electrolyte membrane (PEM) single cell at a temperature of 130
°C. For comparison, a standard Nafion™ membrane (EW 1100
g/equiv) of similar thickness (50
μm) was investigated under similar operating conditions. Both membranes were tested for high temperature operation in conjunction with an in-house prepared carbon supported Pt electrocatalyst. The electrocatalyst consisted of nanosized Pt particles (particle size ∼2
nm) dispersed on a high surface area carbon black. The electrochemical tests showed better performance for the Aquivion™ membrane as compared to Nafion™ with promising properties for high temperature PEM fuel cell applications. Beside the higher open circuit voltage and lower ohmic constraints, a higher electrocatalytic activity was observed at high temperature for the electrocatalyst-Aquivion™ ionomer interface indicating a better catalyst utilization.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2010.12.084</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Aquivion ; Automotive applications ; Carbon ; Chains (polymeric) ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrocatalysts ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolytes ; Energy ; Energy. Thermal use of fuels ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells ; Ground, air and sea transportation, marine construction ; High temperature ; Membranes ; Nanostructure ; PEM fuel cell ; Platinum ; Polymer electrolyte membrane ; Road transportation and traffic ; Short-side chain</subject><ispartof>Journal of power sources, 2011-11, Vol.196 (21), p.8925-8930</ispartof><rights>2011 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c481t-5d8ae1d99e4ddedc2af4edf2a709acf10548f3dd962eeac6e47b108c3bf272653</citedby><cites>FETCH-LOGICAL-c481t-5d8ae1d99e4ddedc2af4edf2a709acf10548f3dd962eeac6e47b108c3bf272653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378775311000115$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,3537,23909,23910,25118,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24497577$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Stassi, A.</creatorcontrib><creatorcontrib>Gatto, I.</creatorcontrib><creatorcontrib>Passalacqua, E.</creatorcontrib><creatorcontrib>Antonucci, V.</creatorcontrib><creatorcontrib>Arico, A.S.</creatorcontrib><creatorcontrib>Merlo, L.</creatorcontrib><creatorcontrib>Oldani, C.</creatorcontrib><creatorcontrib>Pagano, E.</creatorcontrib><title>Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation</title><title>Journal of power sources</title><description>A new Aquivion™ E79-03S short-side chain perfluorosulfonic membrane with a thickness of 30
μm (dry form) and an equivalent weight (EW) of 790
g/equiv recently developed by Solvay-Solexis for high-temperature operation was tested in a pressurised (3
bar abs.) polymer electrolyte membrane (PEM) single cell at a temperature of 130
°C. For comparison, a standard Nafion™ membrane (EW 1100
g/equiv) of similar thickness (50
μm) was investigated under similar operating conditions. Both membranes were tested for high temperature operation in conjunction with an in-house prepared carbon supported Pt electrocatalyst. The electrocatalyst consisted of nanosized Pt particles (particle size ∼2
nm) dispersed on a high surface area carbon black. The electrochemical tests showed better performance for the Aquivion™ membrane as compared to Nafion™ with promising properties for high temperature PEM fuel cell applications. Beside the higher open circuit voltage and lower ohmic constraints, a higher electrocatalytic activity was observed at high temperature for the electrocatalyst-Aquivion™ ionomer interface indicating a better catalyst utilization.</description><subject>Applied sciences</subject><subject>Aquivion</subject><subject>Automotive applications</subject><subject>Carbon</subject><subject>Chains (polymeric)</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrocatalysts</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolytes</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Ground, air and sea transportation, marine construction</subject><subject>High temperature</subject><subject>Membranes</subject><subject>Nanostructure</subject><subject>PEM fuel cell</subject><subject>Platinum</subject><subject>Polymer electrolyte membrane</subject><subject>Road transportation and traffic</subject><subject>Short-side chain</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u3CAUhVGUSplM8woRm6grTwH_YO9aRW1SaaR2kawRA5cMI-zrgN0qD5L3Lc6ks-0Kgb5zzz0cQq4523DGm8-HzWHEPwnnuBFseRQb1lZnZMVbWRZC1vU5WbFStoWUdXlBLlM6MMY4l2xFXn9BdBh7PRigBvtRR59woOhowOGJ6sHStMc4FcnbTOy1H-iYNWHGiGkODgdvaA_9LuoBEs3D6N4_7ekEfeb0NEegI4aXHiKFAGaK-TLBSULdDIEaCIHim8Dj8JF8cDokuHo_1-Tx-7eH2_ti-_Pux-3XbWGqlk9FbVsN3HYdVNaCNUK7CqwTWrJOG8dZXbWutLZrBIA2DVRyx1lryp0TUjR1uSafjnPHiM8zpEn1Pi2r5L1wTqoTTcnKtpOZbI6kyalTBKfG6HsdXxRnaqlBHdS_GtRSg-JC5Rqy8ObdQiejg8uRjU8ntaiqTtZyMfhy5CDn_e0hqmQ85Fasj_nTlEX_P6u_k2KoPQ</recordid><startdate>20111101</startdate><enddate>20111101</enddate><creator>Stassi, A.</creator><creator>Gatto, I.</creator><creator>Passalacqua, E.</creator><creator>Antonucci, V.</creator><creator>Arico, A.S.</creator><creator>Merlo, L.</creator><creator>Oldani, C.</creator><creator>Pagano, E.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20111101</creationdate><title>Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation</title><author>Stassi, A. ; Gatto, I. ; Passalacqua, E. ; Antonucci, V. ; Arico, A.S. ; Merlo, L. ; Oldani, C. ; Pagano, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c481t-5d8ae1d99e4ddedc2af4edf2a709acf10548f3dd962eeac6e47b108c3bf272653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Aquivion</topic><topic>Automotive applications</topic><topic>Carbon</topic><topic>Chains (polymeric)</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrocatalysts</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolytes</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>Ground, air and sea transportation, marine construction</topic><topic>High temperature</topic><topic>Membranes</topic><topic>Nanostructure</topic><topic>PEM fuel cell</topic><topic>Platinum</topic><topic>Polymer electrolyte membrane</topic><topic>Road transportation and traffic</topic><topic>Short-side chain</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stassi, A.</creatorcontrib><creatorcontrib>Gatto, I.</creatorcontrib><creatorcontrib>Passalacqua, E.</creatorcontrib><creatorcontrib>Antonucci, V.</creatorcontrib><creatorcontrib>Arico, A.S.</creatorcontrib><creatorcontrib>Merlo, L.</creatorcontrib><creatorcontrib>Oldani, C.</creatorcontrib><creatorcontrib>Pagano, E.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stassi, A.</au><au>Gatto, I.</au><au>Passalacqua, E.</au><au>Antonucci, V.</au><au>Arico, A.S.</au><au>Merlo, L.</au><au>Oldani, C.</au><au>Pagano, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation</atitle><jtitle>Journal of power sources</jtitle><date>2011-11-01</date><risdate>2011</risdate><volume>196</volume><issue>21</issue><spage>8925</spage><epage>8930</epage><pages>8925-8930</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>A new Aquivion™ E79-03S short-side chain perfluorosulfonic membrane with a thickness of 30
μm (dry form) and an equivalent weight (EW) of 790
g/equiv recently developed by Solvay-Solexis for high-temperature operation was tested in a pressurised (3
bar abs.) polymer electrolyte membrane (PEM) single cell at a temperature of 130
°C. For comparison, a standard Nafion™ membrane (EW 1100
g/equiv) of similar thickness (50
μm) was investigated under similar operating conditions. Both membranes were tested for high temperature operation in conjunction with an in-house prepared carbon supported Pt electrocatalyst. The electrocatalyst consisted of nanosized Pt particles (particle size ∼2
nm) dispersed on a high surface area carbon black. The electrochemical tests showed better performance for the Aquivion™ membrane as compared to Nafion™ with promising properties for high temperature PEM fuel cell applications. Beside the higher open circuit voltage and lower ohmic constraints, a higher electrocatalytic activity was observed at high temperature for the electrocatalyst-Aquivion™ ionomer interface indicating a better catalyst utilization.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2010.12.084</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of power sources, 2011-11, Vol.196 (21), p.8925-8930 |
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| subjects | Applied sciences Aquivion Automotive applications Carbon Chains (polymeric) Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrocatalysts Electrochemical conversion: primary and secondary batteries, fuel cells Electrolytes Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Ground, air and sea transportation, marine construction High temperature Membranes Nanostructure PEM fuel cell Platinum Polymer electrolyte membrane Road transportation and traffic Short-side chain |
| title | Performance comparison of long and short-side chain perfluorosulfonic membranes for high temperature polymer electrolyte membrane fuel cell operation |
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