Phase and structure changes during the sintering of compacts of high-speed steels obtained from powders with various rates of solidification

An investigation was made of the phase and structure transformations in compacts of high-speed steel R6M5F3 powder fractions −630+50 μm at the temperatures of solid-phase (1160–1220°C) and liquid-phase (1240°C) sintering. The structure of the compacts was crystalline or quasicrystalline, depending o...

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Veröffentlicht in:Powder metallurgy and metal ceramics 1999-11, Vol.38 (11-12), p.572-578
Hauptverfasser: Ul’shin, V. I., Poznyak, L. A., Ul’shin, S. V.
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container_issue 11-12
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container_title Powder metallurgy and metal ceramics
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creator Ul’shin, V. I.
Poznyak, L. A.
Ul’shin, S. V.
description An investigation was made of the phase and structure transformations in compacts of high-speed steel R6M5F3 powder fractions −630+50 μm at the temperatures of solid-phase (1160–1220°C) and liquid-phase (1240°C) sintering. The structure of the compacts was crystalline or quasicrystalline, depending on the degree of superheating and cooling rate of the melt during powder spraying. This was related to the presence of a cellular structure in particles of a critical size in the powder. Compacts of powder with the cellular structure experienced higher shrinkage during solid-phase sintering as a result of structre relaxation and recrystallization. The driving force of these processes is the change in chemical potential arising from the decomposition of highly supersaturated metastable solid solutions, and the excess grain-boundary energy of the quasicrystalline matrix structure.
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subjects Cellular structure
Chemical potential
Compacts
Cooling rate
High speed tool steels
Liquid phases
Phase transformations
Powder spraying
Recrystallization
Sintering
Sintering (powder metallurgy)
Solid phases
Solid solutions
Solidification
Solids
Superheating
title Phase and structure changes during the sintering of compacts of high-speed steels obtained from powders with various rates of solidification
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