Optical properties of lead-bismuth cuprous glasses

The optical transmission and absorption spectra in UV- VIS were recorded in the wavelength range 350–800 nm for different glass compositions in the system (CuO)x(PbO)50−x(Bi2O3)50 (x = 2.5, 5.0, 7.5, 10.0, 12.5, 15.0, 20.0). Absorption coefficient (α), optical energy gap (Eopt), refractive index (nD...

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Veröffentlicht in:Bulletin of materials science 2003-10, Vol.26 (6), p.639-642
Hauptverfasser: Deshmukh, P T, Burghate, D K, Deogaonkar, V S, Yawale, S P, Pakade, S V
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container_end_page 642
container_issue 6
container_start_page 639
container_title Bulletin of materials science
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creator Deshmukh, P T
Burghate, D K
Deogaonkar, V S
Yawale, S P
Pakade, S V
description The optical transmission and absorption spectra in UV- VIS were recorded in the wavelength range 350–800 nm for different glass compositions in the system (CuO)x(PbO)50−x(Bi2O3)50 (x = 2.5, 5.0, 7.5, 10.0, 12.5, 15.0, 20.0). Absorption coefficient (α), optical energy gap (Eopt), refractive index (nD), optical dielectric constant (ε′∞), measure of extent of band tailing (ΔE), constant (β) and ratio of carrier concentration to the effective mass (N/m*) have been reported. The effects of compositions of glasses on these parameters have been discussed. It has been indicated that a small compositional modification of the glasses lead to an important change in all the optical properties including non-linear behaviour. The optical parameters were found to be almost the same for different glasses in the same family.
doi_str_mv 10.1007/BF02704329
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subjects Absorption spectra
Absorptivity
Bismuth trioxide
Carrier density
Composition
COPPER OXIDE
DIELECTRIC CONSTANT
Energy gap
Glass
GLASSES
Lead oxides
Nonlinearity
OPTICAL PROPERTIES
Parameters
PROPERTIES
REFRACTIVE INDEX
Refractivity
Wavelengths
title Optical properties of lead-bismuth cuprous glasses
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