Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt
The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO 2 ) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10 −3 wt.% in the lead melt. T...
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Veröffentlicht in: | Powder metallurgy and metal ceramics 2008-09, Vol.47 (9-10), p.607-615 |
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creator | Eliseeva, O. I. Tsisar, V. P. Ivanova, I. I. Demidik, A. M. |
description | The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO
2
) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10
−3
wt.% in the lead melt. The scale grows symmetrically with regard to the initial steel-melt interface toward the liquid metal and matrix. The outer oxide layer consists of Fe
3
O
4
, the upper part of which contains plumboferrites, while the inner oxide is Cr-rich spinel Fe
1+x
Cr
2−x
O
4
. As the scale grows, the imperfection of the duplex oxide increases. The oxidation intensifies as interaction temperature increases to 650°C. The scale loses its protective properties and becomes penetrable for lead. With decreasing oxygen concentration in the lead melt (10
−5
wt.%), the scale growth becomes slower while the corrosion resistance of steel increases. |
doi_str_mv | 10.1007/s11106-008-9063-x |
format | Article |
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2
) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10
−3
wt.% in the lead melt. The scale grows symmetrically with regard to the initial steel-melt interface toward the liquid metal and matrix. The outer oxide layer consists of Fe
3
O
4
, the upper part of which contains plumboferrites, while the inner oxide is Cr-rich spinel Fe
1+x
Cr
2−x
O
4
. As the scale grows, the imperfection of the duplex oxide increases. The oxidation intensifies as interaction temperature increases to 650°C. The scale loses its protective properties and becomes penetrable for lead. With decreasing oxygen concentration in the lead melt (10
−5
wt.%), the scale growth becomes slower while the corrosion resistance of steel increases.</description><identifier>ISSN: 1068-1302</identifier><identifier>EISSN: 1573-9066</identifier><identifier>DOI: 10.1007/s11106-008-9063-x</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Corrosion resistance ; Dispersion hardening steels ; Duplex stainless steels ; Ferritic stainless steels ; Glass ; Materials Science ; Melts ; Metallic Materials ; Natural Materials ; Oxides ; Scale (corrosion) ; Steels ; Titanium dioxide</subject><ispartof>Powder metallurgy and metal ceramics, 2008-09, Vol.47 (9-10), p.607-615</ispartof><rights>Springer Science+Business Media, Inc. 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c411t-6eda8f9c87d4a06105d3572edd685babe8e3904ee65a9e8d156b30eb381289333</citedby><cites>FETCH-LOGICAL-c411t-6eda8f9c87d4a06105d3572edd685babe8e3904ee65a9e8d156b30eb381289333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11106-008-9063-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11106-008-9063-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Eliseeva, O. I.</creatorcontrib><creatorcontrib>Tsisar, V. P.</creatorcontrib><creatorcontrib>Ivanova, I. I.</creatorcontrib><creatorcontrib>Demidik, A. M.</creatorcontrib><title>Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt</title><title>Powder metallurgy and metal ceramics</title><addtitle>Powder Metall Met Ceram</addtitle><description>The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO
2
) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10
−3
wt.% in the lead melt. The scale grows symmetrically with regard to the initial steel-melt interface toward the liquid metal and matrix. The outer oxide layer consists of Fe
3
O
4
, the upper part of which contains plumboferrites, while the inner oxide is Cr-rich spinel Fe
1+x
Cr
2−x
O
4
. As the scale grows, the imperfection of the duplex oxide increases. The oxidation intensifies as interaction temperature increases to 650°C. The scale loses its protective properties and becomes penetrable for lead. With decreasing oxygen concentration in the lead melt (10
−5
wt.%), the scale growth becomes slower while the corrosion resistance of steel increases.</description><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Corrosion resistance</subject><subject>Dispersion hardening steels</subject><subject>Duplex stainless steels</subject><subject>Ferritic stainless steels</subject><subject>Glass</subject><subject>Materials Science</subject><subject>Melts</subject><subject>Metallic Materials</subject><subject>Natural Materials</subject><subject>Oxides</subject><subject>Scale (corrosion)</subject><subject>Steels</subject><subject>Titanium dioxide</subject><issn>1068-1302</issn><issn>1573-9066</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kU1r3DAQhk1Jofn6AbmJHtpc1MxItj6OZckXpOTSnIVsjXcdvNZW8pbk30dmC4VCc5oZ8bzvoHmr6gLhGwLoq4yIoDiA4RaU5C8fqmNstFwmdVR6UIajBPGpOsn5GaCoajyunlYxpZiHOLGWNv73EBOLPQtD3lFannmeE03reUMTBdZTSsM8dOyGitsqcfEjsjwTjWyY2Eg-sC2N81n1sfdjpvM_9bR6urn-ubrjD4-396vvD7yrEWeuKHjT287oUHtQCE2QjRYUgjJN61syJC3URKrxlkzARrUSqJUGhbFSytPq68F3l-KvPeXZbYfc0Tj6ieI-OyuU0FYILOSXd0nZSAFWL5aX74KolUC0Wizo53_Q57hPU_mwM6bWICQsi_EAdeXMOVHvdmnY-vTqENwSnTtE50p0bonOvRSNOGhyYac1pb_G_xe9AX1Imoc</recordid><startdate>20080901</startdate><enddate>20080901</enddate><creator>Eliseeva, O. I.</creator><creator>Tsisar, V. P.</creator><creator>Ivanova, I. I.</creator><creator>Demidik, A. M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080901</creationdate><title>Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt</title><author>Eliseeva, O. I. ; Tsisar, V. P. ; Ivanova, I. I. ; Demidik, A. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-6eda8f9c87d4a06105d3572edd685babe8e3904ee65a9e8d156b30eb381289333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Corrosion resistance</topic><topic>Dispersion hardening steels</topic><topic>Duplex stainless steels</topic><topic>Ferritic stainless steels</topic><topic>Glass</topic><topic>Materials Science</topic><topic>Melts</topic><topic>Metallic Materials</topic><topic>Natural Materials</topic><topic>Oxides</topic><topic>Scale (corrosion)</topic><topic>Steels</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eliseeva, O. I.</creatorcontrib><creatorcontrib>Tsisar, V. P.</creatorcontrib><creatorcontrib>Ivanova, I. I.</creatorcontrib><creatorcontrib>Demidik, A. M.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Powder metallurgy and metal ceramics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eliseeva, O. I.</au><au>Tsisar, V. P.</au><au>Ivanova, I. I.</au><au>Demidik, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt</atitle><jtitle>Powder metallurgy and metal ceramics</jtitle><stitle>Powder Metall Met Ceram</stitle><date>2008-09-01</date><risdate>2008</risdate><volume>47</volume><issue>9-10</issue><spage>607</spage><epage>615</epage><pages>607-615</pages><issn>1068-1302</issn><eissn>1573-9066</eissn><abstract>The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO
2
) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10
−3
wt.% in the lead melt. The scale grows symmetrically with regard to the initial steel-melt interface toward the liquid metal and matrix. The outer oxide layer consists of Fe
3
O
4
, the upper part of which contains plumboferrites, while the inner oxide is Cr-rich spinel Fe
1+x
Cr
2−x
O
4
. As the scale grows, the imperfection of the duplex oxide increases. The oxidation intensifies as interaction temperature increases to 650°C. The scale loses its protective properties and becomes penetrable for lead. With decreasing oxygen concentration in the lead melt (10
−5
wt.%), the scale growth becomes slower while the corrosion resistance of steel increases.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11106-008-9063-x</doi><tpages>9</tpages></addata></record> |
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subjects | Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Corrosion resistance Dispersion hardening steels Duplex stainless steels Ferritic stainless steels Glass Materials Science Melts Metallic Materials Natural Materials Oxides Scale (corrosion) Steels Titanium dioxide |
title | Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt |
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