Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt

The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO 2 ) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10 −3 wt.% in the lead melt. T...

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Veröffentlicht in:Powder metallurgy and metal ceramics 2008-09, Vol.47 (9-10), p.607-615
Hauptverfasser: Eliseeva, O. I., Tsisar, V. P., Ivanova, I. I., Demidik, A. M.
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container_issue 9-10
container_start_page 607
container_title Powder metallurgy and metal ceramics
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creator Eliseeva, O. I.
Tsisar, V. P.
Ivanova, I. I.
Demidik, A. M.
description The corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo (TiO 2 ) steel in oxygen-containing lead melt is investigated at 550 and 650°C. It is determined that duplex magnetite scale is formed on the steel surface at 550°C and oxygen concentration of about 10 −3 wt.% in the lead melt. The scale grows symmetrically with regard to the initial steel-melt interface toward the liquid metal and matrix. The outer oxide layer consists of Fe 3 O 4 , the upper part of which contains plumboferrites, while the inner oxide is Cr-rich spinel Fe 1+x Cr 2−x O 4 . As the scale grows, the imperfection of the duplex oxide increases. The oxidation intensifies as interaction temperature increases to 650°C. The scale loses its protective properties and becomes penetrable for lead. With decreasing oxygen concentration in the lead melt (10 −5 wt.%), the scale growth becomes slower while the corrosion resistance of steel increases.
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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Corrosion resistance
Dispersion hardening steels
Duplex stainless steels
Ferritic stainless steels
Glass
Materials Science
Melts
Metallic Materials
Natural Materials
Oxides
Scale (corrosion)
Steels
Titanium dioxide
title Corrosion behavior of dispersion-strengthened ferritic Fe-13Cr-2Mo steel in lead melt
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