Fast Cu(In,Ga)Se2 precursor growth: Impact on solar cell
In order to reduce the co-evaporation time of Cu(In,Ga)Se2 (CIGSe) thin film absorber, a sequential approach has been investigated. CIGSe layers have been grown using the three-step based CUPRO (Cu-Poor/Rich/Off) process at substrate temperature of 600 and 500 degree C. The first step consists in th...
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description | In order to reduce the co-evaporation time of Cu(In,Ga)Se2 (CIGSe) thin film absorber, a sequential approach has been investigated. CIGSe layers have been grown using the three-step based CUPRO (Cu-Poor/Rich/Off) process at substrate temperature of 600 and 500 degree C. The first step consists in the growth of Cu-poor ([Cu]/[In+Ga]=0.9) precursor layers. This paper aims at investigating the impact of this layer deposition duration on the CIGSe and respective solar cell properties. It is observed that for the two substrate temperatures investigated, the morphological and structural properties of the CIGSe layers do not change with increasing precursor deposition speed, even when it is increased by ten. Furthermore, the respective device performance also appears not affected by this reduction of the precursor growth time; all cells demonstrate 15% efficiency. From this work, the duration of our standard deposition process could be decreased from 23 to 14min without performance loss independently of the substrate temperature. |
doi_str_mv | 10.1016/j.tsf.2011.01.098 |
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CIGSe layers have been grown using the three-step based CUPRO (Cu-Poor/Rich/Off) process at substrate temperature of 600 and 500 degree C. The first step consists in the growth of Cu-poor ([Cu]/[In+Ga]=0.9) precursor layers. This paper aims at investigating the impact of this layer deposition duration on the CIGSe and respective solar cell properties. It is observed that for the two substrate temperatures investigated, the morphological and structural properties of the CIGSe layers do not change with increasing precursor deposition speed, even when it is increased by ten. Furthermore, the respective device performance also appears not affected by this reduction of the precursor growth time; all cells demonstrate 15% efficiency. From this work, the duration of our standard deposition process could be decreased from 23 to 14min without performance loss independently of the substrate temperature.</description><identifier>ISSN: 0040-6090</identifier><identifier>EISSN: 1879-2731</identifier><identifier>DOI: 10.1016/j.tsf.2011.01.098</identifier><identifier>CODEN: THSFAP</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Applied sciences ; Copper ; COPPER INDIUM SELENIDE ; COPPER SELENIDE ; Cross-disciplinary physics: materials science; rheology ; DEPOSITION ; Devices ; ELECTRONIC PRODUCTS ; Energy ; Exact sciences and technology ; IMPACT PROPERTIES ; Materials science ; Methods of deposition of films and coatings; film growth and epitaxy ; Natural energy ; Photovoltaic cells ; Photovoltaic conversion ; Physics ; Precursors ; SOLAR CELLS ; Solar cells. 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CIGSe layers have been grown using the three-step based CUPRO (Cu-Poor/Rich/Off) process at substrate temperature of 600 and 500 degree C. The first step consists in the growth of Cu-poor ([Cu]/[In+Ga]=0.9) precursor layers. This paper aims at investigating the impact of this layer deposition duration on the CIGSe and respective solar cell properties. It is observed that for the two substrate temperatures investigated, the morphological and structural properties of the CIGSe layers do not change with increasing precursor deposition speed, even when it is increased by ten. Furthermore, the respective device performance also appears not affected by this reduction of the precursor growth time; all cells demonstrate 15% efficiency. From this work, the duration of our standard deposition process could be decreased from 23 to 14min without performance loss independently of the substrate temperature.</description><subject>Applied sciences</subject><subject>Copper</subject><subject>COPPER INDIUM SELENIDE</subject><subject>COPPER SELENIDE</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>DEPOSITION</subject><subject>Devices</subject><subject>ELECTRONIC PRODUCTS</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>IMPACT PROPERTIES</subject><subject>Materials science</subject><subject>Methods of deposition of films and coatings; film growth and epitaxy</subject><subject>Natural energy</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Physics</subject><subject>Precursors</subject><subject>SOLAR CELLS</subject><subject>Solar cells. 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Photoelectrochemical cells</topic><topic>Solar energy</topic><topic>Theory and models of film growth</topic><topic>THIN FILMS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>PAINCHAUD, T</creatorcontrib><creatorcontrib>BARREAU, N</creatorcontrib><creatorcontrib>ARZEL, L</creatorcontrib><creatorcontrib>KESSLER, J</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thin solid films</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>PAINCHAUD, T</au><au>BARREAU, N</au><au>ARZEL, L</au><au>KESSLER, J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fast Cu(In,Ga)Se2 precursor growth: Impact on solar cell</atitle><jtitle>Thin solid films</jtitle><date>2011-08-31</date><risdate>2011</risdate><volume>519</volume><issue>21</issue><spage>7221</spage><epage>7223</epage><pages>7221-7223</pages><issn>0040-6090</issn><eissn>1879-2731</eissn><coden>THSFAP</coden><abstract>In order to reduce the co-evaporation time of Cu(In,Ga)Se2 (CIGSe) thin film absorber, a sequential approach has been investigated. CIGSe layers have been grown using the three-step based CUPRO (Cu-Poor/Rich/Off) process at substrate temperature of 600 and 500 degree C. The first step consists in the growth of Cu-poor ([Cu]/[In+Ga]=0.9) precursor layers. This paper aims at investigating the impact of this layer deposition duration on the CIGSe and respective solar cell properties. It is observed that for the two substrate temperatures investigated, the morphological and structural properties of the CIGSe layers do not change with increasing precursor deposition speed, even when it is increased by ten. Furthermore, the respective device performance also appears not affected by this reduction of the precursor growth time; all cells demonstrate 15% efficiency. 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subjects | Applied sciences Copper COPPER INDIUM SELENIDE COPPER SELENIDE Cross-disciplinary physics: materials science rheology DEPOSITION Devices ELECTRONIC PRODUCTS Energy Exact sciences and technology IMPACT PROPERTIES Materials science Methods of deposition of films and coatings film growth and epitaxy Natural energy Photovoltaic cells Photovoltaic conversion Physics Precursors SOLAR CELLS Solar cells. Photoelectrochemical cells Solar energy Theory and models of film growth THIN FILMS |
title | Fast Cu(In,Ga)Se2 precursor growth: Impact on solar cell |
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