From red to near infra-red OLEDs: the remarkable effect of changing from X = -Cl to -NCS in a cyclometallated [Pt(N^C^N)X] complex {N^C^N = 5-mesityl-1,3-di-(2-pyridyl)benzene}
[PtL(6)X] {X = Cl or NCS and L(6) = 5-mesityl-1,3-di(2-pyridyl)-benzene} display similar luminescence in solution but, in the solid state, the packing of the molecules is different, with short PtPt interactions for X = NCS, leading to a red-shifted emission band. The effect has been used to generate...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (26), p.3182-3184 |
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| container_issue | 26 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 48 |
| creator | Rossi, Ester Colombo, Alessia Dragonetti, Claudia Roberto, Dominique Demartin, Francesco Cocchi, Massimo Brulatti, Pierpaolo Fattori, Valeria Williams, J A Gareth |
| description | [PtL(6)X] {X = Cl or NCS and L(6) = 5-mesityl-1,3-di(2-pyridyl)-benzene} display similar luminescence in solution but, in the solid state, the packing of the molecules is different, with short PtPt interactions for X = NCS, leading to a red-shifted emission band. The effect has been used to generate OLEDs that emit squarely in the NIR region (855 nm). |
| doi_str_mv | 10.1039/c2cc16399c |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2012-01, Vol.48 (26), p.3182-3184 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | From red to near infra-red OLEDs: the remarkable effect of changing from X = -Cl to -NCS in a cyclometallated [Pt(N^C^N)X] complex {N^C^N = 5-mesityl-1,3-di-(2-pyridyl)benzene} |
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