[1,5]-Anion Relay/[2,3]-Wittig Rearrangement of 3,3-Bis(silyl) Allyl Enol Ethers: Synthesis of Useful Vinyl Bis(silane) Species

The [1,5]-anion relay/[2,3]-Wittig rearrangement of 3,3-bis(silyl) enol allyl ethers has been developed. This reaction provides an efficient method to synthesize versatile vinyl bissilanes, which can be transformed into trisubstituted vinylsilanes through a [1,4]-Brook rearrangement/alkylation proto...

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Veröffentlicht in:	Organic letters 2012-02, Vol.14 (4), p.1094-1097
Hauptverfasser:	Sun, Xianwei, Lei, Jian, Sun, Changzhen, Song, Zhenlei, Yan, Linjie
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Cyclization Ethers - chemistry Molecular Structure Silanes - chemical synthesis Vinyl Compounds - chemical synthesis
Online-Zugang:	Volltext
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