α-Amidoalkylating Agents from N-Acyl-α-amino Acids: 1-(N-Acylamino)alkyltriphenylphosphonium Salts

N-Acyl-α-amino acids were efficiently transformed in a two-step procedure into 1-N-(acylamino)alkyltriphenylphosphonium salts, new powerful α-amidoalkylating agents. The effect of the α-amino acid structure, the base used [MeONa or a silica gel-supported piperidine (SiO2–Pip)], and the main electro...

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Veröffentlicht in:	Journal of organic chemistry 2012-02, Vol.77 (4), p.1952-1960
Hauptverfasser:	Mazurkiewicz, Roman, Adamek, Jakub, Październiok-Holewa, Agnieszka, Zielińska, Katarzyna, Simka, Wojciech, Gajos, Anna, Szymura, Karol
Format:	Artikel
Sprache:	eng
Schlagworte:	Acylation Alkylating Agents - chemical synthesis Amides - chemistry Amino Acids - chemistry Borates Boric Acids - chemistry Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Magnetic Resonance Spectroscopy Organic chemistry Organometalloidal and organometallic compounds Organophosphorus Compounds - chemical synthesis Oxidation-Reduction P derivatives Peptides Preparations and properties Silicon Dioxide - chemistry
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