The 1,1-Carboboration of Bis(alkynyl)phosphanes as a Route to Phosphole Compounds
Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3‐borylphospholes through a twofold 1,1‐carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki–Miyaura type cross‐coupling reactions (see scheme)....
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-02, Vol.51 (8), p.1954-1957 |
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| container_end_page | 1957 |
|---|---|
| container_issue | 8 |
| container_start_page | 1954 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 51 |
| creator | Möbus, Juri Bonnin, Quentin Ueda, Kirika Fröhlich, Roland Itami, Kenichiro Kehr, Gerald Erker, Gerhard |
| description | Neat and tidy: B(C6F5)3 efficiently converts a series of bis(alkynyl)phosphanes into highly substituted 3‐borylphospholes through a twofold 1,1‐carboboration reaction sequence. The boron substituted phospholes were also used as substrates in Suzuki–Miyaura type cross‐coupling reactions (see scheme). |
| doi_str_mv | 10.1002/anie.201107398 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
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| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_921567183 |
| source | Wiley Journals |
| subjects | boranes Boron carboboration cross-coupling phospholes Sequences Series (mathematics) |
| title | The 1,1-Carboboration of Bis(alkynyl)phosphanes as a Route to Phosphole Compounds |
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