Feasibility of fly ash-based composite coagulant for coal washing wastewater treatment

► Coal washing wastewater was analyzed. ► Several fly ash-based composite coagulants were prepared to treat coal washing wastewater. ► The effluent with the high COD and SS removal was obtained after treatment. In this study, several fly ash (FA)-based composite coagulants, leached by hydrochloric a...

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Veröffentlicht in:Journal of hazardous materials 2012-02, Vol.203, p.221-228
Hauptverfasser: Yan, Long, Wang, Yufei, Ma, Hongzhu, Han, Zhiping, Zhang, Qiang, Chen, Yashao
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creator Yan, Long
Wang, Yufei
Ma, Hongzhu
Han, Zhiping
Zhang, Qiang
Chen, Yashao
description ► Coal washing wastewater was analyzed. ► Several fly ash-based composite coagulants were prepared to treat coal washing wastewater. ► The effluent with the high COD and SS removal was obtained after treatment. In this study, several fly ash (FA)-based composite coagulants, leached by hydrochloric acid, were prepared to treat coal washing wastewater. The concentrations of Al 3+ and Fe 2+/Fe 3+ in the leachates and coagulants were analyzed, and optimal experimental conditions, including coagulant dosage and initial pH, were determined using various analytical techniques (scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), X-ray fluorescence (XRF), particle-size analysis, zeta potential, pH and conductivity measurements). A suspended solids (SS) and chemical oxygen demand (COD) removal efficiency from the effluent treated by one of the coagulants reached 99.61% and 96.48%, respectively, at dosages of 10 g l −1 (initial pH of 9, adjusted by CaO). This indicates that the coagulant was an effective agent for coal washing wastewater treatment, and that the leached Al 3+ and Fe 3+ and introduced Ca 2+ may have improved the coagulation process. Analysis of the dry sludge composition and slurry particle size distribution of the coal washing wastewater showed that charged colloidal particles and the fine particle distribution in the coal washing wastewater make the wastewater treatment a difficult process. Results from this study could provide a novel approach for the treatment of coal washing wastewater and coal fly ash utilization.
doi_str_mv 10.1016/j.jhazmat.2011.12.004
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In this study, several fly ash (FA)-based composite coagulants, leached by hydrochloric acid, were prepared to treat coal washing wastewater. The concentrations of Al 3+ and Fe 2+/Fe 3+ in the leachates and coagulants were analyzed, and optimal experimental conditions, including coagulant dosage and initial pH, were determined using various analytical techniques (scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), X-ray fluorescence (XRF), particle-size analysis, zeta potential, pH and conductivity measurements). A suspended solids (SS) and chemical oxygen demand (COD) removal efficiency from the effluent treated by one of the coagulants reached 99.61% and 96.48%, respectively, at dosages of 10 g l −1 (initial pH of 9, adjusted by CaO). This indicates that the coagulant was an effective agent for coal washing wastewater treatment, and that the leached Al 3+ and Fe 3+ and introduced Ca 2+ may have improved the coagulation process. Analysis of the dry sludge composition and slurry particle size distribution of the coal washing wastewater showed that charged colloidal particles and the fine particle distribution in the coal washing wastewater make the wastewater treatment a difficult process. Results from this study could provide a novel approach for the treatment of coal washing wastewater and coal fly ash utilization.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2011.12.004</identifier><identifier>PMID: 22197558</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>aluminum ; calcium ; calcium oxide ; chemical oxygen demand ; Coagulant ; Coagulants ; coagulation ; Coal ; Coal Ash ; coal fly ash ; Coal washing wastewater ; colloids ; energy ; Feasibility Studies ; fluorescence ; Fly ash ; hydrochloric acid ; Industrial Waste ; iron ; leachates ; Microscopy, Electron, Scanning ; Particle Size ; particle size distribution ; Particulate composites ; scanning electron microscopy ; sludge ; slurries ; Spectrometry, X-Ray Emission ; spectroscopy ; Washing ; Waste water ; wastewater ; Wastewater treatment ; Water Pollutants - chemistry ; X-radiation ; X-Ray Diffraction ; zeta potential</subject><ispartof>Journal of hazardous materials, 2012-02, Vol.203, p.221-228</ispartof><rights>2011 Elsevier B.V.</rights><rights>Copyright © 2011 Elsevier B.V. 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In this study, several fly ash (FA)-based composite coagulants, leached by hydrochloric acid, were prepared to treat coal washing wastewater. The concentrations of Al 3+ and Fe 2+/Fe 3+ in the leachates and coagulants were analyzed, and optimal experimental conditions, including coagulant dosage and initial pH, were determined using various analytical techniques (scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), X-ray fluorescence (XRF), particle-size analysis, zeta potential, pH and conductivity measurements). A suspended solids (SS) and chemical oxygen demand (COD) removal efficiency from the effluent treated by one of the coagulants reached 99.61% and 96.48%, respectively, at dosages of 10 g l −1 (initial pH of 9, adjusted by CaO). This indicates that the coagulant was an effective agent for coal washing wastewater treatment, and that the leached Al 3+ and Fe 3+ and introduced Ca 2+ may have improved the coagulation process. Analysis of the dry sludge composition and slurry particle size distribution of the coal washing wastewater showed that charged colloidal particles and the fine particle distribution in the coal washing wastewater make the wastewater treatment a difficult process. Results from this study could provide a novel approach for the treatment of coal washing wastewater and coal fly ash utilization.</description><subject>aluminum</subject><subject>calcium</subject><subject>calcium oxide</subject><subject>chemical oxygen demand</subject><subject>Coagulant</subject><subject>Coagulants</subject><subject>coagulation</subject><subject>Coal</subject><subject>Coal Ash</subject><subject>coal fly ash</subject><subject>Coal washing wastewater</subject><subject>colloids</subject><subject>energy</subject><subject>Feasibility Studies</subject><subject>fluorescence</subject><subject>Fly ash</subject><subject>hydrochloric acid</subject><subject>Industrial Waste</subject><subject>iron</subject><subject>leachates</subject><subject>Microscopy, Electron, Scanning</subject><subject>Particle Size</subject><subject>particle size distribution</subject><subject>Particulate composites</subject><subject>scanning electron microscopy</subject><subject>sludge</subject><subject>slurries</subject><subject>Spectrometry, X-Ray Emission</subject><subject>spectroscopy</subject><subject>Washing</subject><subject>Waste water</subject><subject>wastewater</subject><subject>Wastewater treatment</subject><subject>Water Pollutants - chemistry</subject><subject>X-radiation</subject><subject>X-Ray Diffraction</subject><subject>zeta potential</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU2P0zAQQC0EYsvCTwByg0uCxx9xfEJoxQLSShxguVqOPem6Supiu6zKr8dVC0dWc5ix9GY89iPkJdAOKPTvNt3mzv5ebOkYBeiAdZSKR2QFg-It57x_TFaUU9HyQYsL8iznDaUUlBRPyQVjoJWUw4r8uEabwxjmUA5NnJppPjQ237WjzegbF5ddzKFgrex6P9ttaaaYjqe5ua9c2K6PueC9LZiaktCWBbflOXky2Tnji3O-JLfXH79ffW5vvn76cvXhpnUSdGmVUkz1IKVXXgxWADCOEvsRhPZcwwiDr--hDqSfhOJinJhzWo_WW8Zh5JfkzWnuLsWfe8zFLCE7nOumGPfZaEaHGoI_TELfa8V6Ucm3_yVBKcoVVaqvqDyhLsWcE05ml8Ji08EANUdNZmPOmsxRkwFmqqba9-p8xX5c0P_r-uulAq9PwGSjsesUsrn9VifIqlBLkLoS708E1u_9FTCZ7AJuHfqQ0BXjY3hgiT9nA67Z</recordid><startdate>20120215</startdate><enddate>20120215</enddate><creator>Yan, Long</creator><creator>Wang, Yufei</creator><creator>Ma, Hongzhu</creator><creator>Han, Zhiping</creator><creator>Zhang, Qiang</creator><creator>Chen, Yashao</creator><general>Elsevier B.V</general><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7SU</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>7X8</scope><scope>7ST</scope><scope>7U7</scope><scope>SOI</scope></search><sort><creationdate>20120215</creationdate><title>Feasibility of fly ash-based composite coagulant for coal washing wastewater treatment</title><author>Yan, Long ; 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In this study, several fly ash (FA)-based composite coagulants, leached by hydrochloric acid, were prepared to treat coal washing wastewater. The concentrations of Al 3+ and Fe 2+/Fe 3+ in the leachates and coagulants were analyzed, and optimal experimental conditions, including coagulant dosage and initial pH, were determined using various analytical techniques (scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction (XRD), X-ray fluorescence (XRF), particle-size analysis, zeta potential, pH and conductivity measurements). A suspended solids (SS) and chemical oxygen demand (COD) removal efficiency from the effluent treated by one of the coagulants reached 99.61% and 96.48%, respectively, at dosages of 10 g l −1 (initial pH of 9, adjusted by CaO). This indicates that the coagulant was an effective agent for coal washing wastewater treatment, and that the leached Al 3+ and Fe 3+ and introduced Ca 2+ may have improved the coagulation process. Analysis of the dry sludge composition and slurry particle size distribution of the coal washing wastewater showed that charged colloidal particles and the fine particle distribution in the coal washing wastewater make the wastewater treatment a difficult process. Results from this study could provide a novel approach for the treatment of coal washing wastewater and coal fly ash utilization.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>22197558</pmid><doi>10.1016/j.jhazmat.2011.12.004</doi><tpages>8</tpages></addata></record>
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source MEDLINE; ScienceDirect Journals (5 years ago - present)
subjects aluminum
calcium
calcium oxide
chemical oxygen demand
Coagulant
Coagulants
coagulation
Coal
Coal Ash
coal fly ash
Coal washing wastewater
colloids
energy
Feasibility Studies
fluorescence
Fly ash
hydrochloric acid
Industrial Waste
iron
leachates
Microscopy, Electron, Scanning
Particle Size
particle size distribution
Particulate composites
scanning electron microscopy
sludge
slurries
Spectrometry, X-Ray Emission
spectroscopy
Washing
Waste water
wastewater
Wastewater treatment
Water Pollutants - chemistry
X-radiation
X-Ray Diffraction
zeta potential
title Feasibility of fly ash-based composite coagulant for coal washing wastewater treatment
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