Borromean-Entanglement-Driven Assembly of Porous Molecular Architectures with Anion-Modified Pore Space

A series of metal–organic frameworks based on a flexible, highly charged Bpybc ligand, namely 1⋅Mn⊃OH−, 2⋅Mn⊃SO42−, 3⋅Mn⊃bdc2−, 4⋅Eu⊃SO42− (H2BpybcCl2=1,1′‐bis(4‐carboxybenzyl)‐4,4′‐bipyridinium dichloride, H2bdc=1,4‐benzenedicarboxylic acid) have been obtained by a self‐assembly process. Single‐cry...

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Veröffentlicht in:	Chemistry : a European journal 2012-02, Vol.18 (7), p.1924-1931
Hauptverfasser:	Sun, Jian-Ke, Yao, Qing-Xia, Tian, Yu-Yang, Wu, Lei, Zhu, Guang-Shan, Chen, Rui-Ping, Zhang, Jie
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Anions Borromean entanglement Channels Chemistry Ions Linkages metal-organic frameworks Methyl alcohol Porosity porous materials Self assembly Surface chemistry
Online-Zugang:	Volltext
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