Improvement of wettability and detergency of polymeric materials by excimer UV treatment
The 172 nm ultraviolet (UV) excimer light was exposed to polyethylene (PE), polypropylene, poly(ethylene terephthalate) and nylon 6 surfaces in ambient air. Changes in the contact angle and particle deposition in liquid due to UV treatment were investigated from the viewpoints of wettability and det...
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Veröffentlicht in: | Colloid and polymer science 2005-09, Vol.283 (12), p.1356-1360 |
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description | The 172 nm ultraviolet (UV) excimer light was exposed to polyethylene (PE), polypropylene, poly(ethylene terephthalate) and nylon 6 surfaces in ambient air. Changes in the contact angle and particle deposition in liquid due to UV treatment were investigated from the viewpoints of wettability and detergency. For all polymers, the wettability and the acid-base component of the surface free energy evaluated by the contact angle measurements increased remarkably by UV treatment of 1 min. From surface analyses of the polymer surfaces by X-ray photoelectron spectroscopy and atomic force microscopy, oxygen concentration was found to increase after UV treatment, whereas little topographical change was observed. The deposition of PE and nylon 12 particles onto the polymer surface was examined, in situ, in water, water/ethanol mixture, ethanol and n-heptane. Although the number of deposited particles was largely dependent on the kinds of the particle, the substrate and the liquid, a significant decrease in the deposition due to UV treatment was confirmed in any system.[PUBLICATION ABSTRACT] |
doi_str_mv | 10.1007/s00396-005-1308-3 |
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Changes in the contact angle and particle deposition in liquid due to UV treatment were investigated from the viewpoints of wettability and detergency. For all polymers, the wettability and the acid-base component of the surface free energy evaluated by the contact angle measurements increased remarkably by UV treatment of 1 min. From surface analyses of the polymer surfaces by X-ray photoelectron spectroscopy and atomic force microscopy, oxygen concentration was found to increase after UV treatment, whereas little topographical change was observed. The deposition of PE and nylon 12 particles onto the polymer surface was examined, in situ, in water, water/ethanol mixture, ethanol and n-heptane. 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Although the number of deposited particles was largely dependent on the kinds of the particle, the substrate and the liquid, a significant decrease in the deposition due to UV treatment was confirmed in any system.[PUBLICATION ABSTRACT]</description><subject>Applied sciences</subject><subject>Coating, metallization, dyeing</subject><subject>Contact angle</subject><subject>Deposition</subject><subject>Ethanol</subject><subject>Ethyl alcohol</subject><subject>Exact sciences and technology</subject><subject>Excimers</subject><subject>Liquids</subject><subject>Machinery and processing</subject><subject>Plastics</subject><subject>Polyethylenes</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><subject>Ultraviolet radiation</subject><subject>Wettability</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdUE1r3DAQFaGBbpP8gN4EpfTkZOSxJOtYlqYJLOSShNyELI-Dgz-2kraN_31lNhDIaXjzPph5jH0VcCkA9FUEQKMKAFkIhLrAE7YRFWYkUX1iG0DAooLy6TP7EuMLAFRGqQ17uh33Yf5LI02Jzx3_Rym5ph_6tHA3tbylROGZJr-s7H4elpFC7_no8r53Q-TNwunV93nNHx55CuTSGnbOTrtM08XbPGMP17_utzfF7u737fbnrvCIMhVKqKpsa9eSgU5ro2XjnUGksjGdJNEq3TZOVCUpWWktoStr6erKYGfqjPCM_Tjm5jf-HCgmO_bR0zC4ieZDtEYYI0sUKiu_fVC-zIcw5eOsqHVZC1GiySpxVPkwxxios_vQjy4sVoBdq7bHqm2u2q5VW8ye72_JLno3dMFNvo_vRi1A11Lif-Z0fiA</recordid><startdate>20050901</startdate><enddate>20050901</enddate><creator>GOTOH, Keiko</creator><creator>KIKUCHI, Shino</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20050901</creationdate><title>Improvement of wettability and detergency of polymeric materials by excimer UV treatment</title><author>GOTOH, Keiko ; 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Changes in the contact angle and particle deposition in liquid due to UV treatment were investigated from the viewpoints of wettability and detergency. For all polymers, the wettability and the acid-base component of the surface free energy evaluated by the contact angle measurements increased remarkably by UV treatment of 1 min. From surface analyses of the polymer surfaces by X-ray photoelectron spectroscopy and atomic force microscopy, oxygen concentration was found to increase after UV treatment, whereas little topographical change was observed. The deposition of PE and nylon 12 particles onto the polymer surface was examined, in situ, in water, water/ethanol mixture, ethanol and n-heptane. Although the number of deposited particles was largely dependent on the kinds of the particle, the substrate and the liquid, a significant decrease in the deposition due to UV treatment was confirmed in any system.[PUBLICATION ABSTRACT]</abstract><cop>Berlin</cop><pub>Springer</pub><doi>10.1007/s00396-005-1308-3</doi><tpages>5</tpages></addata></record> |
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subjects | Applied sciences Coating, metallization, dyeing Contact angle Deposition Ethanol Ethyl alcohol Exact sciences and technology Excimers Liquids Machinery and processing Plastics Polyethylenes Polymer industry, paints, wood Technology of polymers Ultraviolet radiation Wettability |
title | Improvement of wettability and detergency of polymeric materials by excimer UV treatment |
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