Rheological behavior of PAA–CnTAB complex: influence of PAA charge density and surfactant tail length in PAA semidilute aqueous solution
Interactions between anionic polyelectrolyte, poly(acrylic acid) (PAA), and cationic surfactant, alkyltrimethylammonium bromide (C n TAB), were investigated by rheological measurements in semidilute PAA solution. The dependences of the rheological behavior on the chain length of the surfactant, PAA...
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| Veröffentlicht in: | Colloid and polymer science 2009-08, Vol.287 (8), p.911-918 |
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| creator | Wu, Qiang Du, Miao Ye, Tao Shangguan, Yong-gang Zhou, Jian-ping Zheng, Qiang |
| description | Interactions between anionic polyelectrolyte, poly(acrylic acid) (PAA), and cationic surfactant, alkyltrimethylammonium bromide (C
n
TAB), were investigated by rheological measurements in semidilute PAA solution. The dependences of the rheological behavior on the chain length of the surfactant, PAA neutralization degree, and temperature were discussed. The results revealed that both dodecyl and cetyltrimethylammonium bromides (C
12
TAB and C
16
TAB) could increase the viscosity of PAA solution when the surfactant amounts surpassed a critical surfactant concentration (
C
c
), and
C
c
of C
16
TAB was lower than that of C
12
TAB at same PAA neutralization degree. The increase of viscosity is attributed to the surfactant micelles bridging of the polymer chains and confine the mobility PAA chain. On the other hand, it is found that the hydrogen bonding also played an important role in the PAA–C
n
TAB system, especially in lower neutralization degree PAA solution, which results in the viscosity increase rapidly with the added surfactant into lower neutralization degree PAA solution. |
| doi_str_mv | 10.1007/s00396-009-2045-9 |
| format | Article |
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n
TAB), were investigated by rheological measurements in semidilute PAA solution. The dependences of the rheological behavior on the chain length of the surfactant, PAA neutralization degree, and temperature were discussed. The results revealed that both dodecyl and cetyltrimethylammonium bromides (C
12
TAB and C
16
TAB) could increase the viscosity of PAA solution when the surfactant amounts surpassed a critical surfactant concentration (
C
c
), and
C
c
of C
16
TAB was lower than that of C
12
TAB at same PAA neutralization degree. The increase of viscosity is attributed to the surfactant micelles bridging of the polymer chains and confine the mobility PAA chain. On the other hand, it is found that the hydrogen bonding also played an important role in the PAA–C
n
TAB system, especially in lower neutralization degree PAA solution, which results in the viscosity increase rapidly with the added surfactant into lower neutralization degree PAA solution.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-009-2045-9</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Applied sciences ; Cationic ; Chain mobility ; Chains (polymeric) ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Exact sciences and technology ; Food Science ; Hydrogen bonding ; Nanotechnology and Microengineering ; Organic polymers ; Original Contribution ; Physical Chemistry ; Physicochemistry of polymers ; Polyelectrolytes ; Polymer Sciences ; Properties and characterization ; Rheological properties ; Soft and Granular Matter ; Solution and gel properties ; Surfactants ; Viscosity</subject><ispartof>Colloid and polymer science, 2009-08, Vol.287 (8), p.911-918</ispartof><rights>Springer-Verlag 2009</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-009-2045-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-009-2045-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21699798$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wu, Qiang</creatorcontrib><creatorcontrib>Du, Miao</creatorcontrib><creatorcontrib>Ye, Tao</creatorcontrib><creatorcontrib>Shangguan, Yong-gang</creatorcontrib><creatorcontrib>Zhou, Jian-ping</creatorcontrib><creatorcontrib>Zheng, Qiang</creatorcontrib><title>Rheological behavior of PAA–CnTAB complex: influence of PAA charge density and surfactant tail length in PAA semidilute aqueous solution</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Interactions between anionic polyelectrolyte, poly(acrylic acid) (PAA), and cationic surfactant, alkyltrimethylammonium bromide (C
n
TAB), were investigated by rheological measurements in semidilute PAA solution. The dependences of the rheological behavior on the chain length of the surfactant, PAA neutralization degree, and temperature were discussed. The results revealed that both dodecyl and cetyltrimethylammonium bromides (C
12
TAB and C
16
TAB) could increase the viscosity of PAA solution when the surfactant amounts surpassed a critical surfactant concentration (
C
c
), and
C
c
of C
16
TAB was lower than that of C
12
TAB at same PAA neutralization degree. The increase of viscosity is attributed to the surfactant micelles bridging of the polymer chains and confine the mobility PAA chain. On the other hand, it is found that the hydrogen bonding also played an important role in the PAA–C
n
TAB system, especially in lower neutralization degree PAA solution, which results in the viscosity increase rapidly with the added surfactant into lower neutralization degree PAA solution.</description><subject>Applied sciences</subject><subject>Cationic</subject><subject>Chain mobility</subject><subject>Chains (polymeric)</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Hydrogen bonding</subject><subject>Nanotechnology and Microengineering</subject><subject>Organic polymers</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polyelectrolytes</subject><subject>Polymer Sciences</subject><subject>Properties and characterization</subject><subject>Rheological properties</subject><subject>Soft and Granular Matter</subject><subject>Solution and gel properties</subject><subject>Surfactants</subject><subject>Viscosity</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNotkctOAzEMRSMEEuXxAeyyQawGnMk8Gnal4iUhgRBI7KJMxtMGpUlJZhDsWLPlD_kSUtqVZfvY8vUl5IjBKQOozyIAF1UGILIcijITW2TECl5mrOTVNhkBB54VkL_skr0YXwGgEFU1It-Pc_TWz4xWljY4V-_GB-o7-jCZ_H79TN3T5IJqv1ha_DinxnV2QKdxQ1A9V2GGtEUXTf9JlWtpHEKndK9cT3tlLLXoZv08jf4PRFyY1tihR6reBvRDpNGn1Hh3QHY6ZSMebuI-eb66fJreZHf317fTyV22ZHWZ5NUltjzvqprriguBDdNNqhVtkqr0ONcNQslZoaERbVXkdfoD8rZR43HXFS3fJyfrvcvg0wmxlwsTNVqr3OoeKZgQJasZS-TxhlQx_acLymkT5TKYhQqfMmeVELUYJy5fczG13AyDfPVDcEmEZCBX_si1PzL5I1f-SMH_ANZ7hSQ</recordid><startdate>200908</startdate><enddate>200908</enddate><creator>Wu, Qiang</creator><creator>Du, Miao</creator><creator>Ye, Tao</creator><creator>Shangguan, Yong-gang</creator><creator>Zhou, Jian-ping</creator><creator>Zheng, Qiang</creator><general>Springer-Verlag</general><general>Springer</general><scope>IQODW</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200908</creationdate><title>Rheological behavior of PAA–CnTAB complex: influence of PAA charge density and surfactant tail length in PAA semidilute aqueous solution</title><author>Wu, Qiang ; Du, Miao ; Ye, Tao ; Shangguan, Yong-gang ; Zhou, Jian-ping ; Zheng, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1759-275ed32f673c6399eb1cb75e4d153ac82cbe05314c0b9d6427143e3dba88ff4d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Cationic</topic><topic>Chain mobility</topic><topic>Chains (polymeric)</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Hydrogen bonding</topic><topic>Nanotechnology and Microengineering</topic><topic>Organic polymers</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Polyelectrolytes</topic><topic>Polymer Sciences</topic><topic>Properties and characterization</topic><topic>Rheological properties</topic><topic>Soft and Granular Matter</topic><topic>Solution and gel properties</topic><topic>Surfactants</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Qiang</creatorcontrib><creatorcontrib>Du, Miao</creatorcontrib><creatorcontrib>Ye, Tao</creatorcontrib><creatorcontrib>Shangguan, Yong-gang</creatorcontrib><creatorcontrib>Zhou, Jian-ping</creatorcontrib><creatorcontrib>Zheng, Qiang</creatorcontrib><collection>Pascal-Francis</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Qiang</au><au>Du, Miao</au><au>Ye, Tao</au><au>Shangguan, Yong-gang</au><au>Zhou, Jian-ping</au><au>Zheng, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rheological behavior of PAA–CnTAB complex: influence of PAA charge density and surfactant tail length in PAA semidilute aqueous solution</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2009-08</date><risdate>2009</risdate><volume>287</volume><issue>8</issue><spage>911</spage><epage>918</epage><pages>911-918</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>Interactions between anionic polyelectrolyte, poly(acrylic acid) (PAA), and cationic surfactant, alkyltrimethylammonium bromide (C
n
TAB), were investigated by rheological measurements in semidilute PAA solution. The dependences of the rheological behavior on the chain length of the surfactant, PAA neutralization degree, and temperature were discussed. The results revealed that both dodecyl and cetyltrimethylammonium bromides (C
12
TAB and C
16
TAB) could increase the viscosity of PAA solution when the surfactant amounts surpassed a critical surfactant concentration (
C
c
), and
C
c
of C
16
TAB was lower than that of C
12
TAB at same PAA neutralization degree. The increase of viscosity is attributed to the surfactant micelles bridging of the polymer chains and confine the mobility PAA chain. On the other hand, it is found that the hydrogen bonding also played an important role in the PAA–C
n
TAB system, especially in lower neutralization degree PAA solution, which results in the viscosity increase rapidly with the added surfactant into lower neutralization degree PAA solution.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00396-009-2045-9</doi><tpages>8</tpages></addata></record> |
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| ispartof | Colloid and polymer science, 2009-08, Vol.287 (8), p.911-918 |
| issn | 0303-402X 1435-1536 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_919951711 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Applied sciences Cationic Chain mobility Chains (polymeric) Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Exact sciences and technology Food Science Hydrogen bonding Nanotechnology and Microengineering Organic polymers Original Contribution Physical Chemistry Physicochemistry of polymers Polyelectrolytes Polymer Sciences Properties and characterization Rheological properties Soft and Granular Matter Solution and gel properties Surfactants Viscosity |
| title | Rheological behavior of PAA–CnTAB complex: influence of PAA charge density and surfactant tail length in PAA semidilute aqueous solution |
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