Laser-induced breakdown spectroscopy for polymer identification
This study aims at differentiating several organic materials, particularly polymers, by laser induced breakdown spectroscopy. The goal is to apply this technique to the fields of polymer recycling and cultural heritage conservation. We worked with some usual polymers families: polyethylene (PE), pol...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2011-07, Vol.400 (10), p.3331-3340 |
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| creator | Grégoire, Sylvain Boudinet, Marjorie Pelascini, Frédéric Surma, Fabrice Detalle, Vincent Holl, Yves |
| description | This study aims at differentiating several organic materials, particularly polymers, by laser induced breakdown spectroscopy. The goal is to apply this technique to the fields of polymer recycling and cultural heritage conservation. We worked with some usual polymers families: polyethylene (PE), polypropylene (PP), polyoxymethylene, (POM), poly(vinyl chloride), polytetrafluoroethylene, polyoxyethylene (POE), and polyamide for the aliphatic ones, and poly(butylene terephthalate), acrylonitrile–butadiene–styrene, polystyrene, and polycarbonate for the aromatic ones. The fourth harmonic of a Nd:YAG laser (266 nm) in ambient air at atmospheric pressure was used. A careful analysis of the C
2
Swan system (0,0) band in polymers containing no C–C (POM), few C–C (POE), or aromatic C–C linkages led us to the conclusion that the C
2
signal might be native, i.e., the result of direct ablation from the sample. With use of these results, aliphatic and aromatic polymers could be differentiated. Further data treatments, such as properly chosen line ratios, principal component analysis, and partial least squares regression, were evaluated. It was shown that many polymers could be separated, including PE and PP, despite their similar chemical structures.
Figure
LIBS analysis for cultural heritage conservation |
| doi_str_mv | 10.1007/s00216-011-4898-2 |
| format | Article |
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2
Swan system (0,0) band in polymers containing no C–C (POM), few C–C (POE), or aromatic C–C linkages led us to the conclusion that the C
2
signal might be native, i.e., the result of direct ablation from the sample. With use of these results, aliphatic and aromatic polymers could be differentiated. Further data treatments, such as properly chosen line ratios, principal component analysis, and partial least squares regression, were evaluated. It was shown that many polymers could be separated, including PE and PP, despite their similar chemical structures.
Figure
LIBS analysis for cultural heritage conservation</description><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s00216-011-4898-2</identifier><identifier>PMID: 21465098</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Ablation ; Acetal resins ; Acrylonitrile ; Aliphatic compounds ; Analytical Chemistry ; Biochemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Chlorides ; Food Science ; Laboratory Medicine ; Monitoring/Environmental Analysis ; Original Paper ; Polyethylene ; Polyethylenes ; Polymer industry ; Polypropylenes ; Polytetrafluoroethylenes ; Recycling (Waste, etc.) ; Spectroscopy ; Spectrum analysis</subject><ispartof>Analytical and bioanalytical chemistry, 2011-07, Vol.400 (10), p.3331-3340</ispartof><rights>Springer-Verlag 2011</rights><rights>COPYRIGHT 2011 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-f60c3230aff74cb38ba590699a0f6054cf056912368a22480c02fbe9914ed8323</citedby><cites>FETCH-LOGICAL-c484t-f60c3230aff74cb38ba590699a0f6054cf056912368a22480c02fbe9914ed8323</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00216-011-4898-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00216-011-4898-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21465098$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Grégoire, Sylvain</creatorcontrib><creatorcontrib>Boudinet, Marjorie</creatorcontrib><creatorcontrib>Pelascini, Frédéric</creatorcontrib><creatorcontrib>Surma, Fabrice</creatorcontrib><creatorcontrib>Detalle, Vincent</creatorcontrib><creatorcontrib>Holl, Yves</creatorcontrib><title>Laser-induced breakdown spectroscopy for polymer identification</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><addtitle>Anal Bioanal Chem</addtitle><description>This study aims at differentiating several organic materials, particularly polymers, by laser induced breakdown spectroscopy. The goal is to apply this technique to the fields of polymer recycling and cultural heritage conservation. We worked with some usual polymers families: polyethylene (PE), polypropylene (PP), polyoxymethylene, (POM), poly(vinyl chloride), polytetrafluoroethylene, polyoxyethylene (POE), and polyamide for the aliphatic ones, and poly(butylene terephthalate), acrylonitrile–butadiene–styrene, polystyrene, and polycarbonate for the aromatic ones. The fourth harmonic of a Nd:YAG laser (266 nm) in ambient air at atmospheric pressure was used. A careful analysis of the C
2
Swan system (0,0) band in polymers containing no C–C (POM), few C–C (POE), or aromatic C–C linkages led us to the conclusion that the C
2
signal might be native, i.e., the result of direct ablation from the sample. With use of these results, aliphatic and aromatic polymers could be differentiated. Further data treatments, such as properly chosen line ratios, principal component analysis, and partial least squares regression, were evaluated. It was shown that many polymers could be separated, including PE and PP, despite their similar chemical structures.
Figure
LIBS analysis for cultural heritage conservation</description><subject>Ablation</subject><subject>Acetal resins</subject><subject>Acrylonitrile</subject><subject>Aliphatic compounds</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Food Science</subject><subject>Laboratory Medicine</subject><subject>Monitoring/Environmental Analysis</subject><subject>Original Paper</subject><subject>Polyethylene</subject><subject>Polyethylenes</subject><subject>Polymer industry</subject><subject>Polypropylenes</subject><subject>Polytetrafluoroethylenes</subject><subject>Recycling (Waste, etc.)</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><issn>1618-2642</issn><issn>1618-2650</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkc1u1TAQhS0Eoj_wAGxQdrBJmXEcx16hqoKCdCU2sLYcZ1y5JHGwE6H79vVVSpcV8sKjme-MjuYw9g7hCgG6TxmAo6wBsRZKq5q_YOcosRSyhZdPteBn7CLnewBsFcrX7IyjKIRW5-zzwWZKdZiHzdFQ9Yns7yH-nau8kFtTzC4ux8rHVC1xPE6UqjDQvAYfnF1DnN-wV96Omd4-_pfs19cvP2--1Ycft99vrg-1E0qstZfgGt6A9b4Trm9Ub1sNUmsLZdQK56GVGnkjleVcKHDAfU9ao6BBFeUl-7DvXVL8s1FezRSyo3G0M8UtG41at9j-B6k6IZSUCgv58VkSC9mhRjihVzt6Z0cyYfZxTdaVN9AUXJzJh9K_boqHptO8KwLcBa7cMCfyZklhsuloEMwpPLOHZ0p45hSeOTl__-hn6ycanhT_0ioA34FcRvMdJXMftzSXuz-z9QH2m6Km</recordid><startdate>20110701</startdate><enddate>20110701</enddate><creator>Grégoire, Sylvain</creator><creator>Boudinet, Marjorie</creator><creator>Pelascini, Frédéric</creator><creator>Surma, Fabrice</creator><creator>Detalle, Vincent</creator><creator>Holl, Yves</creator><general>Springer-Verlag</general><general>Springer</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>7QH</scope><scope>7UA</scope><scope>C1K</scope></search><sort><creationdate>20110701</creationdate><title>Laser-induced breakdown spectroscopy for polymer identification</title><author>Grégoire, Sylvain ; Boudinet, Marjorie ; Pelascini, Frédéric ; Surma, Fabrice ; Detalle, Vincent ; Holl, Yves</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-f60c3230aff74cb38ba590699a0f6054cf056912368a22480c02fbe9914ed8323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Ablation</topic><topic>Acetal resins</topic><topic>Acrylonitrile</topic><topic>Aliphatic compounds</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Food Science</topic><topic>Laboratory Medicine</topic><topic>Monitoring/Environmental Analysis</topic><topic>Original Paper</topic><topic>Polyethylene</topic><topic>Polyethylenes</topic><topic>Polymer industry</topic><topic>Polypropylenes</topic><topic>Polytetrafluoroethylenes</topic><topic>Recycling (Waste, etc.)</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Grégoire, Sylvain</creatorcontrib><creatorcontrib>Boudinet, Marjorie</creatorcontrib><creatorcontrib>Pelascini, Frédéric</creatorcontrib><creatorcontrib>Surma, Fabrice</creatorcontrib><creatorcontrib>Detalle, Vincent</creatorcontrib><creatorcontrib>Holl, Yves</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><jtitle>Analytical and bioanalytical chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Grégoire, Sylvain</au><au>Boudinet, Marjorie</au><au>Pelascini, Frédéric</au><au>Surma, Fabrice</au><au>Detalle, Vincent</au><au>Holl, Yves</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laser-induced breakdown spectroscopy for polymer identification</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><stitle>Anal Bioanal Chem</stitle><addtitle>Anal Bioanal Chem</addtitle><date>2011-07-01</date><risdate>2011</risdate><volume>400</volume><issue>10</issue><spage>3331</spage><epage>3340</epage><pages>3331-3340</pages><issn>1618-2642</issn><eissn>1618-2650</eissn><abstract>This study aims at differentiating several organic materials, particularly polymers, by laser induced breakdown spectroscopy. The goal is to apply this technique to the fields of polymer recycling and cultural heritage conservation. We worked with some usual polymers families: polyethylene (PE), polypropylene (PP), polyoxymethylene, (POM), poly(vinyl chloride), polytetrafluoroethylene, polyoxyethylene (POE), and polyamide for the aliphatic ones, and poly(butylene terephthalate), acrylonitrile–butadiene–styrene, polystyrene, and polycarbonate for the aromatic ones. The fourth harmonic of a Nd:YAG laser (266 nm) in ambient air at atmospheric pressure was used. A careful analysis of the C
2
Swan system (0,0) band in polymers containing no C–C (POM), few C–C (POE), or aromatic C–C linkages led us to the conclusion that the C
2
signal might be native, i.e., the result of direct ablation from the sample. With use of these results, aliphatic and aromatic polymers could be differentiated. Further data treatments, such as properly chosen line ratios, principal component analysis, and partial least squares regression, were evaluated. It was shown that many polymers could be separated, including PE and PP, despite their similar chemical structures.
Figure
LIBS analysis for cultural heritage conservation</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><pmid>21465098</pmid><doi>10.1007/s00216-011-4898-2</doi><tpages>10</tpages></addata></record> |
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| subjects | Ablation Acetal resins Acrylonitrile Aliphatic compounds Analytical Chemistry Biochemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chlorides Food Science Laboratory Medicine Monitoring/Environmental Analysis Original Paper Polyethylene Polyethylenes Polymer industry Polypropylenes Polytetrafluoroethylenes Recycling (Waste, etc.) Spectroscopy Spectrum analysis |
| title | Laser-induced breakdown spectroscopy for polymer identification |
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