Bimolecular Electron Transfer in Ionic Liquids: Are Reaction Rates Anomalously High?

Steady-state and picosecond time-resolved emission spectroscopy are used to monitor the bimolecular electron transfer reaction between the electron acceptor 9,10-dicyanoanthracene in its S1 state and the donor N,N-dimethylaniline in a variety of ionic liquids and several conventional solvents. Detai...

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Veröffentlicht in:	The journal of physical chemistry. B 2012-02, Vol.116 (4), p.1370-1384
Hauptverfasser:	Liang, Min, Kaintz, Anne, Baker, Gary A, Maroncelli, Mark
Format:	Artikel
Sprache:	eng
Schlagworte:	B: Statistical Mechanics, Thermodynamics, Medium Effects Diffusion Diffusion rate Electron transfer Ionic liquids Mathematical models Quenching Rate constants Solvents
Online-Zugang:	Volltext
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