Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for Biomimetic Asymmetric Hydrogenation

A new and easily regenerable NAD(P)H model 9,10-dihydrophenanthridine (DHPD) has been designed for biomimetic asymmetric hydrogenation of imines and aromatic compounds. This reaction features the use of hydrogen gas as terminal reductant for the regeneration of the DHPD under the mild condition. The...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-02, Vol.134 (4), p.2442-2448
Hauptverfasser:	Chen, Qing-An, Gao, Kai, Duan, Ying, Ye, Zhi-Shi, Shi, Lei, Yang, Yan, Zhou, Yong-Gui
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemical synthesis Biomimetic Materials - chemistry Hydrocarbons, Aromatic - chemical synthesis Hydrocarbons, Aromatic - chemistry Hydrogen - chemistry Hydrogenation Imines - chemical synthesis Imines - chemistry Models, Molecular Molecular Structure NADP - chemistry Phenanthridines - chemical synthesis Phenanthridines - chemistry Stereoisomerism
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