Effect of adding glycols to the micellar properties of Tween: small-angle neutron scattering and turbidity measurements

Small-angle neutron scattering (SANS) and turbidity measurements have been carried out on the nonionic surfactants Tween 20 and Tween 80, in the presence of diethyleneglycol (DEG), triethyleneglycol (TEG), ethylene glycol monoethyl ether (EGMEE), and ethyleneglycol mono butyl ether (EGMBE). SANS mea...

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Veröffentlicht in:Colloid and polymer science 2004-12, Vol.283 (2), p.164-168
Hauptverfasser: RAKESH KUMAR MAHAJAN, CHAWLA, Jyoti, MANDEEP SINGH BAKSHI, KAUR, Gurinder, VINOD KUMAR ASWAL, PREM SAGAR GOYAL
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container_end_page 168
container_issue 2
container_start_page 164
container_title Colloid and polymer science
container_volume 283
creator RAKESH KUMAR MAHAJAN
CHAWLA, Jyoti
MANDEEP SINGH BAKSHI
KAUR, Gurinder
VINOD KUMAR ASWAL
PREM SAGAR GOYAL
description Small-angle neutron scattering (SANS) and turbidity measurements have been carried out on the nonionic surfactants Tween 20 and Tween 80, in the presence of diethyleneglycol (DEG), triethyleneglycol (TEG), ethylene glycol monoethyl ether (EGMEE), and ethyleneglycol mono butyl ether (EGMBE). SANS measurements show that the shapes of the Tween 20 and Tween 80 micelles are oblate ellipsoidal, which do not change predominantly in the presence of DEG and TEG. However, the presence of EGMBE and EGMEE reduces the aggregation number of Tween. This has been attributed to the solubilization of EGMBE and EGMEE in the Tween micelles, providing them with additional hydrophobicity.[PUBLICATION ABSTRACT]
doi_str_mv 10.1007/s00396-004-1112-5
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subjects Agglomeration
Chemistry
Ethers
Exact sciences and technology
General and physical chemistry
Hydrophobicity
Micelles
Neutron scattering
Neutrons
Solubilization
Styrene acrylonitrile resins
Surface physical chemistry
Surface-active agents: properties
Turbidity
title Effect of adding glycols to the micellar properties of Tween: small-angle neutron scattering and turbidity measurements
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