Freezing transition of wetting film of tetradecane on tetradecyltrimethylammonium bromide solutions
We have performed ellipsometry and surface tensiometry at tetradecyltrimethylammonium bromide (TTAB) aqueous solution surface coexisting with tetradecane lens as a function of the molality of TTAB and the temperature under atmospheric pressure. From the theoretical analysis of the coefficient of ell...
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| Veröffentlicht in: | Colloid and polymer science 2010-08, Vol.288 (12-13), p.1333-1339 |
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| container_title | Colloid and polymer science |
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| creator | Ohtomi, Eisuke Takiue, Takanori Aratono, Makoto Matsubara, Hiroki |
| description | We have performed ellipsometry and surface tensiometry at tetradecyltrimethylammonium bromide (TTAB) aqueous solution surface coexisting with tetradecane lens as a function of the molality of TTAB and the temperature under atmospheric pressure. From the theoretical analysis of the coefficient of ellipticity, it was clarified that the liquid monolayer comprising the surfactant and alkane is formed at higher surfactant concentrations by the wetting transition of tetradecane lens on the aqueous solution, and the solid monolayer is formed by lowering temperature (freezing transition). The results of the surface tension measurement support the occurrence of wetting transition and the freezing transition. A phase diagram of the wetting film was constructed by ellipsometry and surface tensiometry, of which the mixed solid monolayer had never been reported before. From the thermodynamic analysis of the phase diagram, it is also demonstrated that the TTAB surface density decreases accompanied with the freezing transition, which agrees with surface densities of TTAB calculated from surface tension vs. concentration curves. |
| doi_str_mv | 10.1007/s00396-010-2258-y |
| format | Article |
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From the theoretical analysis of the coefficient of ellipticity, it was clarified that the liquid monolayer comprising the surfactant and alkane is formed at higher surfactant concentrations by the wetting transition of tetradecane lens on the aqueous solution, and the solid monolayer is formed by lowering temperature (freezing transition). The results of the surface tension measurement support the occurrence of wetting transition and the freezing transition. A phase diagram of the wetting film was constructed by ellipsometry and surface tensiometry, of which the mixed solid monolayer had never been reported before. 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From the theoretical analysis of the coefficient of ellipticity, it was clarified that the liquid monolayer comprising the surfactant and alkane is formed at higher surfactant concentrations by the wetting transition of tetradecane lens on the aqueous solution, and the solid monolayer is formed by lowering temperature (freezing transition). The results of the surface tension measurement support the occurrence of wetting transition and the freezing transition. A phase diagram of the wetting film was constructed by ellipsometry and surface tensiometry, of which the mixed solid monolayer had never been reported before. From the thermodynamic analysis of the phase diagram, it is also demonstrated that the TTAB surface density decreases accompanied with the freezing transition, which agrees with surface densities of TTAB calculated from surface tension vs. concentration curves.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Density</subject><subject>Ellipsometry</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Freezing</subject><subject>General and physical chemistry</subject><subject>Lenses</subject><subject>Monolayers</subject><subject>Nanotechnology and Microengineering</subject><subject>Phase diagrams</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Short Communication</subject><subject>Soft and Granular Matter</subject><subject>Solid-liquid interface</subject><subject>Surface freezing</subject><subject>Surface physical chemistry</subject><subject>Surfactant</subject><subject>Tensiometry</subject><subject>Tetradecane</subject><subject>Wetting</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1rFjEUhYMo-Fr9Aa46INLV1JvPSZZS-gUFF1pwFzJ5k7cpM5OaZCjjr2-GqSJduAo39zmHcw9CHzGcYoDuSwagSrSAoSWEy3Z5hXaYUd5iTsVrtAMKtGVAfr5F73K-BwCmhNghe5Gc-x2mQ1OSmXIoIU5N9M2jK2X99WEY17m4ut87aybXVOLPuAwlhdGVu2Uw4xinMI9Nn-IY9q7JcZhXu_wevfFmyO7D83uEbi_Of5xdtTffLq_Pvt60lglZWgWMkF5QCcp7wwmW1DEiDVfceyY6CdZKr3pm91yC6BnpjADaWbwXAkNPj9DJ5vuQ4q_Z5aLHkK0bhho6zlkrrBTrOi4r-ekFeR_nNNVwGsuOcEUYU5XCG2VTzDk5rx_qsSYtGoNeW9db67q2rtfW9VI1n5-dTbZm8LVUG_JfIaH1LOC4cmTjcl1NB5f-SfAf8-NN5E3U5pCq8e13ApgClpJSqugT9tqcgQ</recordid><startdate>20100801</startdate><enddate>20100801</enddate><creator>Ohtomi, Eisuke</creator><creator>Takiue, Takanori</creator><creator>Aratono, Makoto</creator><creator>Matsubara, Hiroki</creator><general>Berlin/Heidelberg : Springer-Verlag</general><general>Springer-Verlag</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20100801</creationdate><title>Freezing transition of wetting film of tetradecane on tetradecyltrimethylammonium bromide solutions</title><author>Ohtomi, Eisuke ; Takiue, Takanori ; Aratono, Makoto ; Matsubara, Hiroki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c468t-90422b63809ffa52183e428a595ff46780cc8f9b4cd5806b427a6037c1d6610b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Density</topic><topic>Ellipsometry</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Freezing</topic><topic>General and physical chemistry</topic><topic>Lenses</topic><topic>Monolayers</topic><topic>Nanotechnology and Microengineering</topic><topic>Phase diagrams</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Short Communication</topic><topic>Soft and Granular Matter</topic><topic>Solid-liquid interface</topic><topic>Surface freezing</topic><topic>Surface physical chemistry</topic><topic>Surfactant</topic><topic>Tensiometry</topic><topic>Tetradecane</topic><topic>Wetting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ohtomi, Eisuke</creatorcontrib><creatorcontrib>Takiue, Takanori</creatorcontrib><creatorcontrib>Aratono, Makoto</creatorcontrib><creatorcontrib>Matsubara, Hiroki</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ohtomi, Eisuke</au><au>Takiue, Takanori</au><au>Aratono, Makoto</au><au>Matsubara, Hiroki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Freezing transition of wetting film of tetradecane on tetradecyltrimethylammonium bromide solutions</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2010-08-01</date><risdate>2010</risdate><volume>288</volume><issue>12-13</issue><spage>1333</spage><epage>1339</epage><pages>1333-1339</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>We have performed ellipsometry and surface tensiometry at tetradecyltrimethylammonium bromide (TTAB) aqueous solution surface coexisting with tetradecane lens as a function of the molality of TTAB and the temperature under atmospheric pressure. From the theoretical analysis of the coefficient of ellipticity, it was clarified that the liquid monolayer comprising the surfactant and alkane is formed at higher surfactant concentrations by the wetting transition of tetradecane lens on the aqueous solution, and the solid monolayer is formed by lowering temperature (freezing transition). The results of the surface tension measurement support the occurrence of wetting transition and the freezing transition. A phase diagram of the wetting film was constructed by ellipsometry and surface tensiometry, of which the mixed solid monolayer had never been reported before. 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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Density Ellipsometry Exact sciences and technology Food Science Freezing General and physical chemistry Lenses Monolayers Nanotechnology and Microengineering Phase diagrams Physical Chemistry Polymer Sciences Short Communication Soft and Granular Matter Solid-liquid interface Surface freezing Surface physical chemistry Surfactant Tensiometry Tetradecane Wetting |
| title | Freezing transition of wetting film of tetradecane on tetradecyltrimethylammonium bromide solutions |
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