Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature

Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the...

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Veröffentlicht in:Colloid and polymer science 2009-03, Vol.287 (3), p.251-257
Hauptverfasser: Kobayashi, Hiroshi, Suzuki, Toyoko, Moritaka, Mineho, Miyanaga, Emi, Okubo, Masayoshi
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container_end_page 257
container_issue 3
container_start_page 251
container_title Colloid and polymer science
container_volume 287
creator Kobayashi, Hiroshi
Suzuki, Toyoko
Moritaka, Mineho
Miyanaga, Emi
Okubo, Masayoshi
description Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the formation of multihollow PS particles. An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed.
doi_str_mv 10.1007/s00396-008-1983-y
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An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. 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subjects Applied sciences
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Coalescence
Coalescing
Complex Fluids and Microfluidics
Emulsifiers
Emulsion polymerization
Exact sciences and technology
Food Science
Nanotechnology and Microengineering
Nonionic
Organic polymers
Original Contribution
Physical Chemistry
Physicochemistry of polymers
Polymer Sciences
Polymerization
Polystyrene resins
Preparation, kinetics, thermodynamics, mechanism and catalysts
Seeds
Soft and Granular Matter
title Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature
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