Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature
Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the...
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Veröffentlicht in: | Colloid and polymer science 2009-03, Vol.287 (3), p.251-257 |
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creator | Kobayashi, Hiroshi Suzuki, Toyoko Moritaka, Mineho Miyanaga, Emi Okubo, Masayoshi |
description | Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the formation of multihollow PS particles. An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed. |
doi_str_mv | 10.1007/s00396-008-1983-y |
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An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-008-1983-y</identifier><identifier>CODEN: CPMSB6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Applied sciences ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Coalescence ; Coalescing ; Complex Fluids and Microfluidics ; Emulsifiers ; Emulsion polymerization ; Exact sciences and technology ; Food Science ; Nanotechnology and Microengineering ; Nonionic ; Organic polymers ; Original Contribution ; Physical Chemistry ; Physicochemistry of polymers ; Polymer Sciences ; Polymerization ; Polystyrene resins ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Seeds ; Soft and Granular Matter</subject><ispartof>Colloid and polymer science, 2009-03, Vol.287 (3), p.251-257</ispartof><rights>Springer-Verlag 2008</rights><rights>2009 INIST-CNRS</rights><rights>Colloid and Polymer Science is a copyright of Springer, 2009.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-fe1a92b30dd9bb94fef115b275d6c93c2e44d4a4460d7ca81b5d5d9bb03bbf613</citedby><cites>FETCH-LOGICAL-c422t-fe1a92b30dd9bb94fef115b275d6c93c2e44d4a4460d7ca81b5d5d9bb03bbf613</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-008-1983-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-008-1983-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21152718$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kobayashi, Hiroshi</creatorcontrib><creatorcontrib>Suzuki, Toyoko</creatorcontrib><creatorcontrib>Moritaka, Mineho</creatorcontrib><creatorcontrib>Miyanaga, Emi</creatorcontrib><creatorcontrib>Okubo, Masayoshi</creatorcontrib><title>Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the formation of multihollow PS particles. An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed.</description><subject>Applied sciences</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coalescence</subject><subject>Coalescing</subject><subject>Complex Fluids and Microfluidics</subject><subject>Emulsifiers</subject><subject>Emulsion polymerization</subject><subject>Exact sciences and technology</subject><subject>Food Science</subject><subject>Nanotechnology and Microengineering</subject><subject>Nonionic</subject><subject>Organic polymers</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Physicochemistry of polymers</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polystyrene resins</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Seeds</subject><subject>Soft and Granular Matter</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp10V9r1jAUBvAgDnydfgDvCiJedeZf08Y7GdMJA73YYHchTU-2jDapScqon8cPampfZAhe5SK_58kJB6E3BJ8RjNsPCWMmRY1xVxPZsXp9hg6Es6YmDRPP0QEzzGqO6e0L9DKlB4wxl0Ic0K_vEWYddXbBV8FW0zJmdx_GMTxWcxjXlNcIHqpisjMjpKpfqwQwwFBBwWnLbXCC6H7uNUty_u4PehJ7dPm-ct6EOIfyXLnzwRftzLHHOogfK7AWTN4myTDNUOQS4RU6sXpM8Pp4nqKbzxfX55f11bcvX88_XdWGU5prC0RL2jM8DLLvJbdgCWl62jaDMJIZCpwPXHMu8NAa3ZG-GZqNYtb3VhB2it7vvXMMPxZIWU0uGRhH7SEsSUkiJW8Fa4p8-498CEv0ZThFupY2klHBiyK7MjGkFMGqObpJx1URrLa1qX1tqqxNbWtTa8m8OzbrZPRoo_bGpb9BWn5EW9IVR3eXypW_g_hkgv-W_waPcK6G</recordid><startdate>20090301</startdate><enddate>20090301</enddate><creator>Kobayashi, Hiroshi</creator><creator>Suzuki, Toyoko</creator><creator>Moritaka, Mineho</creator><creator>Miyanaga, Emi</creator><creator>Okubo, Masayoshi</creator><general>Springer-Verlag</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20090301</creationdate><title>Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature</title><author>Kobayashi, Hiroshi ; Suzuki, Toyoko ; Moritaka, Mineho ; Miyanaga, Emi ; Okubo, Masayoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-fe1a92b30dd9bb94fef115b275d6c93c2e44d4a4460d7ca81b5d5d9bb03bbf613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coalescence</topic><topic>Coalescing</topic><topic>Complex Fluids and Microfluidics</topic><topic>Emulsifiers</topic><topic>Emulsion polymerization</topic><topic>Exact sciences and technology</topic><topic>Food Science</topic><topic>Nanotechnology and Microengineering</topic><topic>Nonionic</topic><topic>Organic polymers</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Physicochemistry of polymers</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polystyrene resins</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Seeds</topic><topic>Soft and Granular Matter</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kobayashi, Hiroshi</creatorcontrib><creatorcontrib>Suzuki, Toyoko</creatorcontrib><creatorcontrib>Moritaka, Mineho</creatorcontrib><creatorcontrib>Miyanaga, Emi</creatorcontrib><creatorcontrib>Okubo, Masayoshi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kobayashi, Hiroshi</au><au>Suzuki, Toyoko</au><au>Moritaka, Mineho</au><au>Miyanaga, Emi</au><au>Okubo, Masayoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2009-03-01</date><risdate>2009</risdate><volume>287</volume><issue>3</issue><spage>251</spage><epage>257</epage><pages>251-257</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><coden>CPMSB6</coden><abstract>Seeded emulsion polymerizations of styrene using polystyrene (PS) seed particles with incorporated nonionic emulsifier were carried out at 40 and 70 °C to investigate the influence of temperature during the polymerization process including the swelling step of the seed particles with monomer on the formation of multihollow PS particles. An increase in the temperature during the polymerization process caused an increase in the rate of coalescence (i.e., the degree of coalescence at any given time) of the small water domains in the inside. After the coalescence proceeded excessively, the water domains were eventually discharged from the particles to the medium, resulting in nonhollow particles. The results show that it is important for the preparation of the multihollow PS particles to control the coalescence of a lot of small water domains inside the seed particles with the incorporated nonionic emulsifier, and strongly support the formation mechanism previously proposed.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00396-008-1983-y</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Applied sciences Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Coalescence Coalescing Complex Fluids and Microfluidics Emulsifiers Emulsion polymerization Exact sciences and technology Food Science Nanotechnology and Microengineering Nonionic Organic polymers Original Contribution Physical Chemistry Physicochemistry of polymers Polymer Sciences Polymerization Polystyrene resins Preparation, kinetics, thermodynamics, mechanism and catalysts Seeds Soft and Granular Matter |
title | Preparation of multihollow polystyrene particles by seeded emulsion polymerization using seed particles with incorporated nonionic emulsifier: effect of temperature |
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